显微组织对X100管线钢氢致开裂及氢捕获行为影响

doi:10.11902/1005.4537.2018.168

中国腐蚀与防护学报

2019, Vol. 39

Issue (6): 536-542 DOI: 10.11902/1005.4537.2018.168

研究报告

本期目录 | 过刊浏览

显微组织对X100管线钢氢致开裂及氢捕获行为影响

袁玮,黄峰(

),甘丽君,戈方宇,刘静

武汉科技大学省部共建耐火材料与冶金国家重点实验室武汉 430081

Effect of Microstructure on Hydrogen Induced Cracking and Hydrogen Trapping Behavior of X100 Pipeline Steel

YUAN Wei,HUANG Feng(

),GAN Lijun,GE Fangyu,LIU Jing

State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China

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摘要:

依据NACE TM 0284-2011标准评估了不同显微组织X100管线钢的氢致开裂 (HIC) 敏感性，采用场发射扫描电镜、氢显等手段观察了钢中HIC裂纹的萌生和扩展以及H的聚集，借助于氢渗透动力学参数分析了X100管线钢不同显微组织试样的氢捕获效率与HIC敏感性的内在关联。结果表明，具有不同显微组织的X100管线钢HIC敏感性依次为：原始铁素体-贝氏体组织试样＞炉冷处理的块状铁素体组织试样＞风冷处理的针状铁素体组织试样；钢中组织对氢的捕获效率越高，钢材对HIC敏感性越大；H原子容易在夹杂物和基体之间的界面处聚集，钢中的MnS夹杂、Ca-Al-Si-O复合夹杂和MnO夹杂均为HIC裂纹萌生源。

关键词 ： X100管线钢, 组织, HIC敏感性, 氢捕获

Abstract：

The hydrogen induced cracking (HIC) sensitivity of X100 pipeline steels with different microstructures was evaluated according to the NACE TM 0284-2011 standard. While, the initiation and propagation of HIC, and the aggregation of hydrogen atoms in the steel were characterized via field emission scanning electron microscopy (FE-SEM) and hydrogen microprint technique. The relationship between hydrogen trapping efficiency and HIC sensitivity of X100 pipeline steels with different microstructure was analyzed by using kinetic parameters of hydrogen permeation. The results show that the HIC susceptibility of X100 pipeline steels with different microstructure could be ranked as follows: original specimen with ferrite-bainite microstructure＞furnace-cooling specimen with massive ferrite microstructure＞wind-cooling specimen with acicular ferrite microstructure. The microstructure has higher trapping efficiency, the more susceptible to HIC is. Hydrogen atoms tend to aggregate at the interface between inclusion and matrix, and the HIC could initiate at MnS inclusion, Ca-Al-Si-O composite inclusion and MnO inclusion in the steels.

Key words： X100 pipeline steel microstructure HIC susceptibility hydrogen trapping

收稿日期: 2018-11-13

ZTFLH:

TG174

基金资助:国家自然科学基金(51871172)

通讯作者: 黄峰 E-mail: Huangfeng@wust.edu.cn

Corresponding author: Feng HUANG E-mail: Huangfeng@wust.edu.cn

作者简介: 袁玮，女，1988年生，博士生

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引用本文:

袁玮,黄峰,甘丽君,戈方宇,刘静. 显微组织对X100管线钢氢致开裂及氢捕获行为影响[J]. 中国腐蚀与防护学报, 2019, 39(6): 536-542.
Wei YUAN, Feng HUANG, Lijun GAN, Fangyu GE, Jing LIU. Effect of Microstructure on Hydrogen Induced Cracking and Hydrogen Trapping Behavior of X100 Pipeline Steel. Journal of Chinese Society for Corrosion and protection, 2019, 39(6): 536-542.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2018.168 或 https://www.jcscp.org/CN/Y2019/V39/I6/536

图1 电化学渗氢装置

图2 氢显实验流程

图3 热处理前后X100管线钢的显微组织

图4 HIC敏感性测试后X100管线钢表面形貌

表1 X100管线钢HIC敏感性参数

图5 X100管线钢HIC裂纹扩展形貌

图6 X100管线钢HIC裂纹中夹杂物的BSE图及EDS结果

图7 Ca-Al-Si-O夹杂物周围氢显形貌及EDS结果

图8 X100管线钢的电化学氢渗透曲线

表2 X100管线钢氢渗透动力学参数

[1]	Wan H X, Du C W, Liu Z Y, et al. The effect of hydrogen on stress corrosion behavior of X65 steel welded joint in simulated deep sea environment [J]. Ocean Eng., 2016, 114: 216
[2]	Saleh A A, Hejazi D, Gazder A A, et al. Investigation of the effect of electrolytic hydrogen charging of X70 steel: II. Microstructural and crystallographic analyses of the formation of hydrogen induced cracks and blisters [J]. Int. J. Hydrog. Energy, 2016, 41: 12424
[3]	Amin L V, Miresmaeili R, Abdollah-Zadeh A. The mutual effects of hydrogen and microstructure on hardness and impact energy of SMA welds in X65 steel [J]. Mater. Sci. Eng., 2017, A679: 87
[4]	Hejazi D, Haq A J, Yazdipour N, et al. Effect of manganese content and microstructure on the susceptibility of X70 pipeline steel to hydrogen cracking [J]. Mater. Sci. Eng., 2012, A551: 40
[5]	Qu Y M, Huang F, Liu J, et al. Influence of microstructure on hydrogen induced cracks susceptibility and hydrogen trapping efficiency for X80 pipeline steel [J]. Chin. J. Mater. Res., 2010, 24: 508
[5]	(曲炎淼, 黄峰, 刘静等. 显微组织对X80钢氢致裂纹敏感性和氢捕获效率的影响 [J]. 材料研究学报, 2010, 24: 508)
[6]	Mohtadi-Bonab M A, Szpunar J A, Razavi-Tousi S S. A comparative study of hydrogen induced cracking behavior in API 5L X60 and X70 pipeline steels [J]. Eng. Fail. Anal., 2013, 33: 163
[7]	Li J, Gao X H, Du L X, et al. Relationship between microstructure and hydrogen induced cracking behavior in a low alloy pipeline steel [J]. J. Mater. Sci. Technol., 2017, 33: 1504
[8]	Arafin M A, Szpunar J A. Effect of bainitic microstructure on the susceptibility of pipeline steels to hydrogen induced cracking [J]. Mater. Sci. Eng., 2011, A528: 4927
[9]	Peng X H, Liu J, Huang F, et al. Effect of microstructure on hydrogen-induced cracking propagation and hydrogen trapping efficiency of pipeline steel [J]. Corros. Prot., 2013, 34: 882
[9]	(彭先华, 刘静, 黄峰等. 微观组织对管线钢氢致裂纹扩展方式及氢捕获效率的影响 [J]. 腐蚀与防护, 2013, 34: 882)
[10]	Huang F, Li X G, Liu J, et al. Hydrogen-induced cracking susceptibility and hydrogen trapping efficiency of different microstructure X80 pipeline steel [J]. J. Mater. Sci., 2011, 46: 715
[11]	Dong C F, Liu Z Y, Li X G, et al. Effects of hydrogen-charging on the susceptibility of X100 pipeline steel to hydrogen-induced cracking [J]. Int. J. Hydrog. Energy, 2009, 34: 9879
[12]	Du C W, Zhao T L, Liu Z Y, et al. Corrosion behavior and characteristics of the product film of API X100 steel in acidic simulated soil solution [J]. Int. J. Miner. Metall. Mater., 2016, 23: 176
[13]	Gan L J, Huang F, Liu J Y, et al. Hydrogen trapping and hydrogen induced cracking of welded X100 pipeline steel in H2S environments [J]. Int. J. Hydrog. Energy, 2018, 43: 2293
[14]	NACE TM0284-2011. Evaluation of pipeline and pressure vessel steels for resistance to hydrogen-induced cracking [S]. 2011
[15]	Xue H B, Cheng Y F. Characterization of inclusions of X80 pipeline steel and its correlation with hydrogen-induced cracking [J]. Corros. Sci., 2011, 53: 1201
[16]	Mohtadi-Bonab M A, Eskandari M, Rahman K M M, et al. An extensive study of hydrogen-induced cracking susceptibility in an API X60 sour service pipeline steel [J]. Int. J. Hydrog. Energy, 2016, 41: 4185
[17]	Huang F, Liu S, Liu J, et al. Sulfide stress cracking resistance of the welded WDL690D HSLA steel in H2S environment [J]. Mater. Sci. Eng,, 2014, A591: 159
[18]	Wang S H, Luu W C, Ho K F, et al. Hydrogen permeation in a submerged arc weldment of TMCP steel [J]. Mater. Chem. Phys., 2002, 77: 447
[19]	Chu W Y, Qiao L J, Li J X, et al. Hydrogen Embrittlement and Stress Corrosion Cracking [M]. Beijing: Science Press, 2013: 92
[19]	(褚武杨, 乔利杰, 李金许等. 氢脆和应力腐蚀 [M]. 北京: 科学出版社, 2013: 92)
[20]	Zhang T M, Zhao W M, Deng Q S, et al. Effect of microstructure inhomogeneity on hydrogen embrittlement susceptibility of X80 welding HAZ under pressurized gaseous hydrogen [J]. Int. J. Hydrog. Energy, 2017, 42: 25102

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