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Corrosion Behavior of Steel Materials in Marine Supercritical Carbon Dioxide Environment |
ZHANG Guoqing1, YU Zhixia1, WANG Yuesong2, WANG Zhi1, JIN Zhengyu2, LIU Hongwei2( ) |
1 Offshore Oil Engineering Co., Ltd., Tianjin 300461, China 2 School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China |
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Cite this article:
ZHANG Guoqing, YU Zhixia, WANG Yuesong, WANG Zhi, JIN Zhengyu, LIU Hongwei. Corrosion Behavior of Steel Materials in Marine Supercritical Carbon Dioxide Environment. Journal of Chinese Society for Corrosion and protection, 2025, 45(4): 1061-1069.
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Abstract Maine Carbon Capture, Utilization and Storage (CCUS) is one of the effective methods to solve the problems caused by the excess emission of CO2. However, the pipelines face serious corrosion problems in the process of CO2 transport. Aiming at marine corrosion problems under supercritical CO2 conditions, this work investigated the corrosion behavior of A106 carbon steel with different water contents and temperature by mass loss, scanning electron microscope (SEM), X-ray diffractometer (XRD) and three-dimensional stereoscopic microscope. Results indicate that the corrosion rate of A106 steel increased with the increase of water content in CO2 environment at 10 MPa and 35 ℃. When the water content exceeded 2000 μL/L, the corrosion rate was significantly accelerated. A106 steel reached the maximum corrosion rate, i.e., 0.16 mm/a at the water content of 3000 μL/L. However, the localized corrosion rate of A106 steel was the highest with the value of 0.73 mm/a at the water content of 2000 μL/L. In the CO2 environment at 10 MPa, the corrosion rate of A106 steel decreased from 25 to 60 ℃ and then increased with the increase of temperature. At 60 ℃, the corrosion rate reached a minimum value, i.e., 0.025 mm/a. Therefore, temperature and water content are the key factors affecting the corrosion of steel materials in supercritical CO2 environment.
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Received: 08 October 2024
32134.14.1005.4537.2024.325
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Corresponding Authors:
LIU Hongwei, E-mail: liuhw35@mail.sysu.edu.cn
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