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Journal of Chinese Society for Corrosion and protection  2024, Vol. 44 Issue (5): 1134-1144    DOI: 10.11902/1005.4537.2023.318
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Research Progress on CO2 Corrosion and Protective Countermeasures for Oil Casing
YANG Tao1, XU Lei1(), WANG Jianchun2, ZHANG Mingcheng1, YAO Yanbo1, GAO Guogang1, XU Wenzhong2, LI Changyun1
1 Faculty of Engineering, China University of Petroleum-Beijing at Karamay, Karamay 834000, China
2 Xinjiang Defeng Yisheng Oil Anticorrosion Engineering Co., Ltd., Karamay 834000, China
Cite this article: 

YANG Tao, XU Lei, WANG Jianchun, ZHANG Mingcheng, YAO Yanbo, GAO Guogang, XU Wenzhong, LI Changyun. Research Progress on CO2 Corrosion and Protective Countermeasures for Oil Casing. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1134-1144.

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Abstract  

With the popularization and application of CO2 flooding technology in oilfields, the CO2 corrosion and corrosion-control becomes an urgent problem to be solved. CO2 corrosion can easily cause the damage and failure of oil casing, and it is of great economic value and scientific significance to study the relevant corrosion mechanism and anti-corrosion measures. In this paper, the CO2 corrosion mechanism is introduced, and the influence of temperature, medium flow rate, pH and other factors on the CO2 corrosion rate is analyzed. By taking the actual operation conditions of oilfield exploitation and the influencing factors of CO2 corrosion into consideration, the research progress of corrosion-resistant materials, corrosion inhibitors, metal plating and other measures are reviewed, and the advantages and disadvantages of these measures in the actual oilfield application are summarized. Among many measures, the amorphous alloy coating is prone to be passivated passivated in operating conditions of oilfields, which may act as an effectively barrier to protect the pipe steel substrate from corrosion attack by corrosive media, thereby enhance the service life of the pipeline. The result of comprehensive analysis shows that the anti-corrosion measures of metal coating have good economic benefits and application prospects, and the future research on anti-corrosion technology of metal coating is prospected.

Key words:  CO2 corrosion      oil casing      antiseptic measures      metal plating     
Received:  09 October 2023      32134.14.1005.4537.2023.318
ZTFLH:  TE988.2  
Fund: Science and Technology Plan of Karamay(20232023hjcxrc0008);2023 Autonomous Region Graduate Innovation Project(XJ2023G281)
Corresponding Authors:  XU Lei, E-mail: 2019592043@cupk.edu.cn

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2023.318     OR     https://www.jcscp.org/EN/Y2024/V44/I5/1134

Fig.1  Corrosion rate of P110 steel at different temperatures[11]
Fig.2  Effect of CO2 partial pressure on average corrosion rate[18]
Fig.3  Morphologies of corrosion products of 20 steel with pH values of 3 (a), 5 (b) and 7 (c)[27]
Fig.4  Surface morphologies of corrosion products of N80 carbon steel with a flow rate of 0 (a), 1 (b) and 2 (c) m/s[31]
Fig.5  Effect of temperature on TD corrosion inhibition of novel thiourea derivatives[38]
Fig.6  SEM images of corrosion inhibition effect of new thiourea derivative TD on 20# carbon steel: (a) original sample, (b) corrosion sample without corrosion inhibitor, (c) corrosion sample with 20 mg/L TD corrosion inhibitor[38]
Fig.7  Oxide film interface morphologies of Fe-Cr alloys of different compositions in CO2 at 600oC[43]: (a) 316L stainless steel, (b) 15-15Ti stainless steel, (c) 321 stainless steel, (d) T91 steel
Fig.8  Corrosion process of cathode coating: (a) plating porosity, (b) corrosion start, (c) corrosion end
Fig.9  Micromorphologies of Ni-W alloy plating under different processes[63]: (a) direct current plating process, (b) pluse plating process with a duty cycle of 50%, (c) pluse plating process with a duty cycle of 60%
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