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Journal of Chinese Society for Corrosion and protection  2024, Vol. 44 Issue (5): 1177-1188    DOI: 10.11902/1005.4537.2024.001
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Low Temperature Wear and Corrosion Resistance of Epoxy Based Polar Marine Ice Breaking Coatings
SUN Shibin1, SHI Changwei1, WANG Dongsheng2, CHANG Xueting2, LI Mingchun3()
1 School of Logistics Engineering, Shanghai Maritime University, Shanghai 201306, China
2 School of Marine Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
3 Ocean Chemical Research Institute Co., Ltd., Qingdao 266001, China
Cite this article: 

SUN Shibin, SHI Changwei, WANG Dongsheng, CHANG Xueting, LI Mingchun. Low Temperature Wear and Corrosion Resistance of Epoxy Based Polar Marine Ice Breaking Coatings. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1177-1188.

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Abstract  

A wear-resistant and corrosion-resistant composite coating designed for application in polar ship icebreaking areas was developed with modified basalt powder (BP) and mica powder as filler, while epoxy resin (EP) as the matrix, which was then applied on FH36 Marine low temperature steel plate. Considering the requirements related with the presence of ice-seawater friction-corrosion coupling effect in the ice zone navigation, tests such as coating adhesion, hardness, corrosion resistance by seawater immersion, as well as simulated low-temperature ice load friction and wear by varying ice-loads at different temperatures. The results show that as the filler content of mica powder and basalt powder increased from 10% to 20% (in mass fraction), the adhesion between the low-temperature composite coating and the substrate decreased from level 1 to level 2, whereas, its Vickers hardness increased by approximately 20%, corrosion resistance was improved accordingly, and the friction coefficient exhibited a decreasing trend, resulting in a significant improvement of wear resistance by nearly 50%, demonstrating the wear-reducing effect. Additionally, with the decrease in temperature, the wear performance of the low-temperature coating for polar ships showed a decreasing trend followed by an increasing trend.Meanwhile, the wear rate decreased successively from 0.3151 mm3/(N∙m) to 0.0962 mm3/(N∙m) and then increased to 0.1949 mm3/(N∙m). The lowest wear rate and the best wear resistance were observed at 0°C, indicating that temperature has a significant impact on the wear performance of the coating. In sum, the higher aggregate content can significantly improve the low-temperature wear resistance of the composite coating, resulting in lower wear volume.

Key words:  polar vessels      paints      epoxy resin      low temperature friction     
Received:  01 January 2024      32134.14.1005.4537.2024.001
ZTFLH:  TG172  
Fund: National Key Research and Development Program(2022YFB3705303);Technical Standard Project of Shanghai Science and Technology Commission(21DZ2205700);"Dawn" Plan of Shanghai Municipal Education Commission(19SG46);International Cooperation and Exchange Project of the Ministry of Science and Technology(CU03-29);Project of Shanghai Deep Sea Material Engineering Technology Center(19DZ2253100)
Corresponding Authors:  LI Mingchun, E-mail: limingchun0309@163.com

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2024.001     OR     https://www.jcscp.org/EN/Y2024/V44/I5/1177

IngredientBP-1/EPBP-2/EP
Epoxy resin4530
Basalt powder1020
Mica powder1020
Curing agent1510
Iron red88
Teflon powder4.04.0
Ultraviolet absorber3.53.5
Dispersant2.52.5
Defoamer1.01.0
Anti-settling agent1.01.0
Table 1  Formulations of two BP/EP coatings for polar ice breakers (mass fraction, %)
Fig.1  Surface morphologies of BP-2/EP (a, c) and BP-1/EP (b, d) coatings after scratch test
Fig.2  Vickers hardnesses of two BP/EP coatings before and after soaking
Fig.3  Equivalent circuit diagrams of electrochemical impedance spectroscopies of unsoaked (a, b) and soaked (c) BP/EP coatings
Fig.4  Nyquist plots of BP-1/EP (a) and BP-2/EP (b) coatings in 3.5%NaCl solution
Fig.5  Bode plots of BP-1/EP (a) and BP-2/EP (b) coatings in 3.5%NaCl solution
SampleTime / dRc / Ω·cm2Yof / S·sec n ·cm-2nfRct/ Ω·cm2Yodl / S·sec n ·cm-2ndl
BP-1/EP01.13 × 1071.60 × 10-70.366---
101.99 × 1053.99 × 10-100.8511.09 × 10-31.99 × 10-70.092
BP-2/EP07.91 × 1063.72 × 10-90.97641.08 × 1075.56 × 10-80.522
101.69 × 1046.86 × 10-110.9722.47 × 1061.21 × 10-70.344
Table 2  Fitting parameters of EIS of two BP/EP coatings
Fig.6  Coefficient curves of friction between BP/EP coatings and seawater (a) or sea ice (b) under different loads
Fig.7  Wear morphologies of two BP/EP coatings after friction test with seawater at 80 N (a) and 120 N (b)
Load / NSampleWidth / µmDepth / µmWear volµme / µm3Attrition rate / mm3·(N·m)-1
80BP-1/EP3217252301540.47949
BP-2/EP2777151160400.24175
120BP-1/EP3514474326140.60085
BP-2/EP3379252399740.3333
Table 3  Abrasion losses of two BP/EP coatings after friction tests under 80 and 120 N in seawater environment
Fig.8  3D morphology diagrams of grinding cracks of BP-1/EP (a) and BP-2/EP (b) coatings after wet friction test
Fig.9  Variations of friction coefficients of BP-1/EP (a, b) and BP-2/EP (c, d) coatings under 80 N (a, c) and 120 N (b, d)
Fig.10  Temperature dependences of average friction coefficients of two BP/EP coatings under 80 N (a) and 120 N (b)
Fig.11  Outlines of abrasion marks of BP-1/EP (a) and BP-2/EP (b) coatings after frictions tests from -20oC to 20oC under 80 N
Load / NSampleTemperature / oCWidth / μmDepth / μmVolµme / μm3
80BP-1/EP20315728287978
10309718190626
028231691932
-10316817118764
-20297820195014
BP-2/EP20318722151254
103358757888
02856846170
-1026681881256
-2030961393552
120BP-1/EP20355223363056
10338418231476
0320015168366
-10315618199813
-20305022261550
BP-2/EP20384910238590
1034567113954
02948482002
-10298210114762
-2030519192131
Table 4  Widths, depths and total volumes of wear marks of two BP/EP coatings under different conditions
Fig.12  3D morphologies of wear marks of BP-2/EP coating after friction tests at -20oC (a), -10oC (b), 0oC (c), 10oC (d) and 20oC (e)
Fig.13  Wear rates of two BP/EP coatings from -20oC to 20oC under 80 and 120 N
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