|
|
Corrosion Inhibition of Erigeron canadensis L.Extract for Steel in HCl Solution |
SHI Chengjie, LEI Ran, DENG Shuduan, XU Juan, SHAO Dandan, GUO Qingqing, LI Xianghong( ) |
Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China |
|
Cite this article:
SHI Chengjie, LEI Ran, DENG Shuduan, XU Juan, SHAO Dandan, GUO Qingqing, LI Xianghong. Corrosion Inhibition of Erigeron canadensis L.Extract for Steel in HCl Solution. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1189-1199.
|
Abstract The extract of invasive alien weed Erigeron canadensis L. (ECE) was prepared by ultrasound-assisted extraction. The corrosion inhibition performance of ECE as a corrosion inhibitor on steel in 1.0 mol/L HCl solution had been investigated by means of mass loss measurement, electrochemical method and metal surface characterization. The results show that ECE has good corrosion inhibition performance on steel in 1.0 mol/L HCl solution, and the corrosion inhibition rate increases with the increase of ECE concentration. Among others the corrosion inhibition rate of 300 mg·L-1 ECE at 40oC is the best, reaching 93.7%. The adsorption of ECE on steel surface is consistent with Langmuir adsorption isotherm. The standard adsorption Gibbs free energy ranges from -28.37 kJ/mol to -27.60 kJ/mol at 20-50oC, and adsorption is a mixed type of physical and chemical adsorption. The potentiodynamic polarization curves show that ECE is a mixed inhibitor corrosion inhibitor acting through "geometrical overlay effect". The Nyquist plot shows a single capacitive resistance arc, and the charge transfer resistance at the steel/acid interface increases with increasing ECE concentration, while the capacitance of the double layer decreases. Examination results of metallographic microscopy, atomic force microscopy (AFM), contact angle, FTIR and UV-Vis show that the adsorption of ECE induced the formation a corrosion inhibition film on the steel surface significantly slows down steel corrosion in HCl solution and enhances the hydrophobicity of the steel surface.
|
Received: 20 November 2023
32134.14.1005.4537.2023.364
|
|
Fund: National Natural Science Foundation of China(52161016);Research Project for Distinguished Young Scholars in Yunnan Province(202001AV070008);Joint Key Project of Agricultural Fundamental Research in Yunnan Province(202101BD070001-017);Special Project of "Top Young Talents" of Yunnan Ten Thousand Talents Plan(51900109);Open Fund Project of State Forestry and Grassland Administration Key Laboratory of Southwest Forestry Biomass Resources Efficient Utilization in Southwest Region, Southwest Forestry University(2022-KF08);Yunnan University Student Innovation and Entrepreneurship Training Program(s202310677069) |
Corresponding Authors:
LI Xianghong, E-mail: xianghong-li@163.com
|
1 |
Wu C H, Liu T, Gao S, et al. Ultrasonic vibration enhanced friction stir welding process of aluminum/steel dissimilar metals [J]. J. Mater. Eng., 2022, 50(1): 33
doi: 10.11868/j.issn.1001-4381.2021.000338
|
|
吴程浩, 刘 涛, 高 嵩 等. 铝/钢异种金属的超声振动强化搅拌摩擦焊接工艺 [J]. 材料工程, 2022, 50(1): 33
doi: 10.11868/j.issn.1001-4381.2021.000338
|
2 |
Lv Y L, Chen J X, Wang Y Q, et al. Research on corrosion inhibition performance of 1,2-Diphenyl-1H-Imidazo [4,5-f][1,10] phenanthroline as a new-type inhibitor for mild steel [J]. Mater. Prot., 2022, 55(5): 48
|
|
吕艳丽, 陈娟霞, 王艳秋 等. 1,2-二苯基-1H-咪唑[4,5-f][1,10]邻菲罗啉新型缓蚀剂对低碳钢的缓蚀性能研究 [J]. 材料保护, 2022, 55(5): 48
|
3 |
Ding J W, Feng X F. Active ingredient extraction of excess sludge and its corrosion behavior in acid pickling [J]. Environ. Sci. Technol., 2020, 43(1): 158
|
|
丁杰伟, 冯宪凤. 剩余污泥中活性成分提取及其酸洗缓蚀行为研究 [J]. 环境科学与技术, 2020, 43(1): 158
|
4 |
Zhao J P, Gao Y H, Li H H, et al. Progress in research on green corrosion inhibitor for pickling [J]. Appl. Chem. Ind., 2018, 47: 1975
|
|
赵军平, 高玉华, 李海花 等. 绿色酸洗缓蚀剂的研究进展 [J]. 应用化工, 2018, 47: 1975
|
5 |
Wang X, Ren S F, Jiang H. et al. Preparation method and research direction of plant corrosion inhibitors [J]. Surf. Technol., 2018, 47(3): 196
|
|
王 霞, 任帅飞, 蒋欢 等. 植物缓蚀剂的制备方法与研究方向 [J]. 表面技术, 2018, 47(3): 196
|
6 |
Liu Z H, Wang X P, Sheng Y Q, et al. Corrosion inhibition of extracts of holly leaves on Q235 steel in 1 mol/L hydrochloric acid medium [J]. Mater. Prot., 2019, 52(6): 45
|
|
刘子涵, 王兴平, 盛耀权 等. 冬青树叶提取液在1 mol/L盐酸介质中对Q235钢的缓蚀性能 [J]. 材料保护, 2019, 52(6): 45
|
7 |
Liu X H, Guan J X, Fu Z D, et al. Corrosion inhibition performance and mechanism of orange peel extract in H3PO4 solution [J]. Surf. Technol., 2023, 52(8): 263
|
|
柳鑫华, 关俊霞, 付占达 等. 橙子皮提取物在H3PO4溶液中的缓蚀性能及缓蚀机理研究 [J]. 表面技术, 2023, 52(8): 263
|
8 |
Chen W, Huang D X, Wei F. Inhibition effect of Brainea insignis extract against carbon steel corrosion in HCl solution [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 376
|
|
陈 文, 黄德兴, 韦 奉. 铁蕨提取物对碳钢在盐酸中的缓蚀行为研究 [J]. 中国腐蚀与防护学报, 2021, 41: 376
|
9 |
Zhang F, Li X H. Inhibition action of alternanthera philoxeroides extract on steel in sulfuric acid solution [J]. Chem. Res. Appl., 2021, 33: 1472
|
|
张 富, 李向红. 空心莲子草提取物对钢在硫酸溶液中的缓蚀性能 [J]. 化学研究与应用, 2021, 33: 1472
|
10 |
Chen S Y, Shu J X, Liu J Q, et al. Corrosion inhibition of dendrobium root extracts for Q235 steel in HCl medium [J]. Mod. Chem. Ind., 2022, 42(suppl.2) : 222
|
|
陈思屹, 舒加喜, 刘嘉奇 等. 石斛根提取物在盐酸中对Q235钢的缓蚀作用研究 [J]. 现代化工, 2022, 42(): 222
|
11 |
Liu T D, Shen C, Sun T X, et al. Research progress of plant extract corrosion inhibitors in metal anticorrosion [J]. Appl. Chem. Ind., 2022, 51: 2756
|
|
刘拓东, 沈 超, 孙天晓 等. 植物提取物缓蚀剂在金属防腐中的研究进展 [J]. 应用化工, 2022, 51: 2756
|
12 |
Gong L, Li J S, Liu X Y, et al. Analysis of invasive alien species in Chinese national nature reserves [J]. Ecol. Sci., 2017, 36(4): 210
|
|
宫 璐, 李俊生, 柳晓燕 等. 我国部分国家级自然保护区外来入侵物种的分布概况 [J]. 生态科学, 2017, 36(4): 210
|
13 |
Wu C Y, Shao S, Yan M M, et al. Research on development chemical constituents of Erigeron Canadensis L. [J]. China Pharm., 2015, 24(1): 1
|
|
吴程彦, 邵 帅, 严铭铭 等. 小飞蓬化学成分研究进展 [J]. 中国药业, 2015, 24(1): 1
|
14 |
Li X H, Xu X, Lei R, et al. Synergistic inhibition effect of walnut green husk extract complex inhibitors on steel in phosphoric acid [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 358
|
|
李向红, 徐 昕, 雷然 等. 磷酸中核桃青皮复配缓蚀剂对冷轧钢的缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2022, 42: 358
doi: 10.11902/1005.4537.2021.160
|
15 |
Kaya F, Solmaz R, Geçibesler İ H. The use of methanol extract of Rheum Ribes (Işgın) flower as a natural and promising corrosion inhibitor for mild steel protection in 1 M HCl solution [J]. J. Ind. Eng. Chem., 2023, 122: 102
|
16 |
Wang L Z, Li X H. Adsorption and inhibition behavior of imidazoline on steel surface in trichloroacetic acid solution [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 353
|
|
王丽姿, 李向红. 三氯乙酸溶液中咪唑啉在钢表面的吸附及缓蚀行为 [J]. 中国腐蚀与防护学报, 2021, 41: 353
doi: 10.11902/1005.4537.2020.096
|
17 |
Zhang X, Wen J X, Liu Y X, et al. Corrosion inhibition effect of Galium aparine Linn extracts on Q235 steel in hydrochloric acid solution [J]. Surf. Technol., 2018, 47(3): 231
|
|
张 欣, 文家新, 刘云霞 等. 猪殃殃草提取物在盐酸中对Q235钢的缓蚀作用研究 [J]. 表面技术, 2018, 47(3): 231
|
18 |
Deng Z H, Lei R, Zhang Z Y, et al. Corrosion inhibition of vetiver extract on steel in hydrochloric acid environment [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 173
|
|
邓志华, 雷 然, 张智勇 等. 香根草提取物对冷轧钢在盐酸溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2023, 43: 173
doi: 10.11902/1005.4537.2022.065
|
19 |
Lei R, Shi C J, Li X H. Corrosion inhibition of aluminum in HCl solution by Flos Sophorae Immaturus extract [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 939
|
|
雷 然, 石成杰, 李向红. 槐米提取物对Al在HCl溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2022, 42: 939
|
20 |
Lin B L, Shao J J, Zhao C, et al. Passiflora edulis Sims peel extract as a renewable corrosion inhibitor for mild steel in phosphoric acid solution [J]. J. Mol. Liq., 2023, 375: 121296
|
21 |
Aljourani J, Raeissi K, Golozar M A. Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution [J]. Corros. Sci., 2009, 51: 1836
|
22 |
Zhang K G, Yang W Z, Xu B, et al. Inhibitory effect of konjac glucomanan on pitting corrosion of AA5052 aluminium alloy in NaCl solution [J]. J. Colloid Interface Sci., 2018, 517: 52
|
23 |
Mu G N, Li X M, Li F. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid [J]. Mater. Chem. Phys., 2004, 86: 59
|
24 |
Li X H, Deng S D, Xu X. Inhibition action of cassava starch ternary graft copolymer on steel in H2SO4 solution [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 105
|
|
李向红, 邓书端, 徐 昕. 木薯淀粉三元接枝共聚物对钢在H2SO4溶液中的缓蚀性能研究 [J]. 中国腐蚀与防护学报, 2020, 40: 105
doi: 10.11902/1005.4537.2019.035
|
25 |
Lei R, Li X H, Shi C J, et al. Inhibition mechanism of Fagopyrum esculentum Moench. Extract on steel in HCl media [J]. Surf. Technol., 2023, 52(1): 162
|
|
雷 然, 李向红, 石成杰 等. 荞麦提取物对钢在HCl介质中的缓蚀机理 [J]. 表面技术, 2023, 52(1): 162
|
26 |
Ruan Y P, Tang B, Huang S H. Progress in research on adsorption properties of organic substances on metal surfaces [J]. Surf. Technol., 2009, 38(2): 70
|
|
阮宜平, 汤 兵, 黄树焕. 有机物质在金属表面的吸附研究进展 [J]. 表面技术, 2009, 38(2): 70
|
27 |
Du P F, Lei R, Li X H. Corrosion inhibition effect of Mikania micrantha Kunth extract on cold rolled steel in sulfamic acid solution [J]. Corros. Prot., 2023, 44(4): 15
|
|
杜鹏飞, 雷 然, 李向红. 薇甘菊提取物对冷轧钢在氨基磺酸溶液中的缓蚀效果 [J]. 腐蚀与防护, 2023, 44(4): 15
|
28 |
Su T J, Li K E. Inhibition behavior of N,N'-dicinnamylidene-o-phenylenediamine for mild steel in hydrochloric acid [J]. Chem. Res. Appl., 2018, 30: 62
|
|
苏铁军, 李克娥. 盐酸介质中邻苯二胺双缩肉桂醛对A3碳钢的缓蚀行为研究 [J]. 化学研究与应用, 2018, 30: 62
|
29 |
Abbout S, Chebabe D, Zouarhi M, et al. Ceratonia Siliqua L seeds extract as eco-friendly corrosion inhibitor for carbon steel in 1 M HCl: characterization, electrochemical, surface analysis, and theoretical studies [J]. J. Mol. Struct., 2021, 1240: 130611
|
30 |
Qiu L, Li X H, Lei R, et al. Inhibition performance of coconut diethanolamide on cold rolled steel in trichloroacetic acid solution [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 301
|
|
仇 莉, 李向红, 雷然 等. 椰油酸二乙醇酰胺对钢在三氯乙酸溶液中的缓蚀性能 [J]. 中国腐蚀与防护学报, 2023, 43: 301
|
31 |
Qiang Y J, Zhang S T, Yan S, et al. Three indazole derivatives as corrosion inhibitors of copper in a neutral chloride solution [J]. Corros. Sci., 2017, 126: 295
|
32 |
Gutiérrez E, Rodríguez J A, Cruz-Borbolla J, et al. Development of a predictive model for corrosion inhibition of carbon steel by imidazole and benzimidazole derivatives [J]. Corros. Sci., 2016, 108: 23
|
33 |
Han T, Guo J X, Zhao Q, et al. Molecular simulation and theoretical experiment error analysis of quaternary ammonium salt corrosion inhibitors [J]. Appl. Chem. Ind., 2022, 51: 1559
|
|
韩 曈, 郭继香, 赵 清 等. 季铵盐缓蚀剂的分子模拟与理论实验误差分析 [J]. 应用化工, 2022, 51: 1559
|
34 |
Aramaki K, Hagiwara M, Nishihara H. The synergistic effect of anions and the ammonium cation on the inhibition of iron corrosion in acid solution [J]. Corros. Sci., 1987, 27: 487
|
35 |
Bereket G, Yurt A, Türk H. Inhibition of the corrosion of low carbon steel in acidic solution by selected polyelectrolytes and polymers [J]. Anti-Corros. Methods Mater., 2003, 50: 422
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|