Corrosion Inhibition of Erigeron canadensis L.Extract for Steel in HCl Solution

doi:10.11902/1005.4537.2023.364

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (5): 1189-1199 DOI: 10.11902/1005.4537.2023.364

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Corrosion Inhibition of Erigeron canadensis L.Extract for Steel in HCl Solution

SHI Chengjie, LEI Ran, DENG Shuduan, XU Juan, SHAO Dandan, GUO Qingqing, LI Xianghong(

)

Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

Cite this article:

SHI Chengjie, LEI Ran, DENG Shuduan, XU Juan, SHAO Dandan, GUO Qingqing, LI Xianghong. Corrosion Inhibition of Erigeron canadensis L.Extract for Steel in HCl Solution. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1189-1199.

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Abstract

The extract of invasive alien weed Erigeron canadensis L. (ECE) was prepared by ultrasound-assisted extraction. The corrosion inhibition performance of ECE as a corrosion inhibitor on steel in 1.0 mol/L HCl solution had been investigated by means of mass loss measurement, electrochemical method and metal surface characterization. The results show that ECE has good corrosion inhibition performance on steel in 1.0 mol/L HCl solution, and the corrosion inhibition rate increases with the increase of ECE concentration. Among others the corrosion inhibition rate of 300 mg·L^-1 ECE at 40^oC is the best, reaching 93.7%. The adsorption of ECE on steel surface is consistent with Langmuir adsorption isotherm. The standard adsorption Gibbs free energy ranges from -28.37 kJ/mol to -27.60 kJ/mol at 20-50^oC, and adsorption is a mixed type of physical and chemical adsorption. The potentiodynamic polarization curves show that ECE is a mixed inhibitor corrosion inhibitor acting through "geometrical overlay effect". The Nyquist plot shows a single capacitive resistance arc, and the charge transfer resistance at the steel/acid interface increases with increasing ECE concentration, while the capacitance of the double layer decreases. Examination results of metallographic microscopy, atomic force microscopy (AFM), contact angle, FTIR and UV-Vis show that the adsorption of ECE induced the formation a corrosion inhibition film on the steel surface significantly slows down steel corrosion in HCl solution and enhances the hydrophobicity of the steel surface.

Key words: Erigeron canadensis L. extract corrosion inhibition steel hydrochloric acid adsorption

Received: 20 November 2023 32134.14.1005.4537.2023.364

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52161016);Research Project for Distinguished Young Scholars in Yunnan Province(202001AV070008);Joint Key Project of Agricultural Fundamental Research in Yunnan Province(202101BD070001-017);Special Project of "Top Young Talents" of Yunnan Ten Thousand Talents Plan(51900109);Open Fund Project of State Forestry and Grassland Administration Key Laboratory of Southwest Forestry Biomass Resources Efficient Utilization in Southwest Region, Southwest Forestry University(2022-KF08);Yunnan University Student Innovation and Entrepreneurship Training Program(s202310677069)

Corresponding Authors: LI Xianghong, E-mail: xianghong-li@163.com

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	SHI Chengjie
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	SHAO Dandan
	GUO Qingqing
	LI Xianghong

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.364 OR https://www.jcscp.org/EN/Y2024/V44/I5/1189

Fig.1 Curves of inhibition (η_w) and corrosion rate (v) versus ECE concentration (c) at different temperatures: (a) η_w-c, (b) v-c

Fig.2 Fitted straight lines for c/θ-c

Table 1 Linear fitting parameters of c/θ-c

Fig.3 Fitted straight line for lnK-1/T

Table 2 Thermodynamic parameters of adsorption

Fig.4 Fitted straight lines for Arrhenius (a) and transition state (b)

Fig.5 Variation curves of corrosion kinetic parameters with ECE concentration

Fig.6 Kinetic potential polarization curves of steel in 1.0 mol/L HCl medium with different ECE concentrations at 20^oC

Table 3 Parameters of kinetic potential polarization curves

Fig.7 EIS of steel in 1.0 mol/L HCl solution without and with ECE at 20^oC and equivalent circuit: (a) Nyquist plots, (b) Bode modulus, (c) Bode phase angle plots, (d) equivalent circuit

Table 4 Fitting parameters of EIS

Fig.8 Metallurgical microscopy morphologies (a1-c1) and contact angles (a2-c2) on steel surface: (a1, a2) before immersion, (b1, b2) after corrosion, (c1, c2) after corrosion inhibition

Fig.9 AFM micromorphologies of steel surface: (a) before immersion, (b) after corrosion, (c) after corrosion inhibition

Table 5 Surface roughness parameters of steel

Fig.10 UV spectra of inhibition solutions

Fig.11 FTIR spectra of EC, ECE and adsorbed layer on steel surface

Fig.12 Schematic corrosion and corrosion inhibition mechanism of steel immersed in 1.0 mol/L HCl containing ECE

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