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J Chin Soc Corr Pro  2007, Vol. 27 Issue (2): 93-96     DOI:
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ELECTROCHEMICAL BEHAVIOR OF THESIMULATED Al2Zn SEGREGATION IN 3%NaCl SOLUTION
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华中科技大学化学系
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;. ELECTROCHEMICAL BEHAVIOR OF THESIMULATED Al2Zn SEGREGATION IN 3%NaCl SOLUTION. J Chin Soc Corr Pro, 2007, 27(2): 93-96 .

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Abstract  Simulated Al2Zn segregation alloys were developed according to the average elements distribution of zinc enriched zones of Al-Zn-In alloy. Open circuit potential against time,polarization curves,and electrochemical impedance spectroscopy were employed to study the electrochemical behavior of Al-Zn-In and simulated Al2Zn alloys. The results showed that the simulated Al2Zn alloy exhibits a more electronegative open circuit potential and a lower self-corrosion rate as compared with those of Al-Zn-In alloy. However,the Al2Zn segregation in Al-Zn-In alloy can be attributed to the formation of micro-local galvanic corrosion that leads to the preferential dissolution of Al2Zn and the loss of current efficiency.
Key words:  Al-Zn-In      Al2Zn      segregation      electrochemical behavior      
Received:  14 October 2005     
ZTFLH:  TG174.41  
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[1]Reboul M C,Gimenez P H,Ramaeu J J.A proposed activationmechanism for Al anodes[J].Corrosion,1984,40(7):366-371
[2]Salinas D R,Garcia S G,Bessone J B.Influence of alloying elementsand microstructure on aluminum sacrificial anode performance:Caseof Al-Zn[J].J.Appl.Electrochem.,1999,29(9):1063-1071
[3]Munoz AG,Saidman S B,Bessone J B.Corrosion of an Al-Zn-Inalloy in chloride media[J].Corros.Sci.,2002,44(10):2171-2182
[4]Venugopal A,Angal R D,Raja V S.Effect of grain boundary corro-sion on impedance characteristics of an aluminum-zinc-indiumal-loy in 3.5%sodium chloride solution[J].Corrosion,1996,52(2):138-142
[5]Venugopal A,Raja V S.AC impedance study on the activationmechanism of aluminium by indium and zinc in 3.5%NaCl medium[J].Corros.Sci.,1997,39(12):2053-2065
[6]Ashok S R,Venkataramani A,Parthiban G T,et al.Performance ofaluminium anodes under heat treatment[J].Corrosion Prevention&Control,2002,49(2):60-63
[7]Qi G T,Guo Z H,Qu J E.Effect of magnesium on microstructureand performance of containing RE aluminum anode[J].J.Chin.Soc.Corros.Prot.,2001,21(4):220-224(齐公台,郭稚弧,屈钧娥.合金元素Mg对含RE铝阳极组织与性能的影响[J].中国腐蚀与防护学报,2001,21(4):220-224)
[8]Qi G T,Liao H X,Qu J E.Study on the electrochemical perform-ances of segregation phases in aluminum anodes containing RE[J].J.Chin.Soc.Corros.Prot.,2003,23(6):354-358(齐公台,廖海星,屈钧娥.含RE铝阳极中析出相的电化学行为研究[J].中国腐蚀与防护学报,2003,23(6):354-358)
[9]Buchheit R G.A compilation of corrosion potentials reported for in-termetallic phases in aluminum alloys[J].J.Electrochem.Soc.,1995,142(11):3994-3996
[10]Li Y,Li G G.The analysis for failure Al sacrificial anode used insea bed pipelines[J].J.Chin.Soc.Corros.Prot.,2002,22(1):60-63(李异,李光广.在役海底管线牺牲阳极失效分析[J].中国腐蚀与防护学报,2002,22(1):60-63).
[11]Bessone J B,Flamini D O,Saidman D O.Comprehensive model forthe activation mechanism of Al-Zn alloys produced by indium[J].Corros.Sci.,2005,47(1):95-105
[12]Xu G,Cao C N,Lin HC,et al.Electrochemical study of active dis-solution for aluminum in neutral NaCl solution[J].Corros.Sci.Prot.Technol.,1998,10(6):321-326(许刚,曹楚南,林海潮,等.纯铝在NaCl溶液中活化溶解时电化学行为研究[J].腐蚀科学与防护技术,1998,10(6):321-326)
[13]Venugopal A,Veluchamy P,Selvam P,et al.X-ray photoelectronspectroscopic study of the oxide film on an aluminum-tin alloy in3.5%sodium chloride solution[J].Corrosion,1997,53(10):808-812
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