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Journal of Chinese Society for Corrosion and protection  2019, Vol. 39 Issue (6): 550-556    DOI: 10.11902/1005.4537.2018.172
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Investigation on Interrelation of Field Corrosion Test and Accelerated Corrosion Test of Grounding Materials in Red Soil Environment
ZHU Yichen1,LIU Guangming1(),LIU Xin2,PEI Feng2,TIAN Xu2,SHI Chao1
1. School of Material Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
2. State Grid Jiangxi Electric Power Research Institute, Nanchang 330096, China
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Abstract  

The corrosion behavior of eight typical grounding materials in red soil environment were studied via buried test in real red soil and accelerated corrosion test, as well as weight-loss measurement, corrosion morphology and corrosion product composition analysis. And then the acceleration ratio and interrelation rate between accelerated corrosion test and field corrosion test were calculated. The results showed that different grounding materials had different corrosion acceleration ratios in the same accelerated corrosion test, and the corrosion mechanism of accelerated corrosion test is basically consistent with that of field corrosion test. However, after accelerated corrosion test and field corrosion test, the compositions of the formed corrosion products on Q235 steel and Cu grounding material were all different, because of the differences of microbial activity and CO2 solubility in soils. Correlation analysis results showed that the Pearson correlation coefficient (P) between accelerated corrosion test and field corrosion test was 0.9663, in other word, the service life of grounding materials buried in the field could be evaluated by the accelerated corrosion test.

Key words:  grounding meterial      soil corrosion      accelerated corrosion test      interrelation     
Received:  20 November 2018     
ZTFLH:  TG172.4  
Fund: Supported by National Natural Science Foundation of China(51961028);Science and Technology Project of State Grid Corporation(52182017000Y)
Corresponding Authors:  Guangming LIU     E-mail:  gemliu@126.com

Cite this article: 

ZHU Yichen,LIU Guangming,LIU Xin,PEI Feng,TIAN Xu,SHI Chao. Investigation on Interrelation of Field Corrosion Test and Accelerated Corrosion Test of Grounding Materials in Red Soil Environment. Journal of Chinese Society for Corrosion and protection, 2019, 39(6): 550-556.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2018.172     OR     https://www.jcscp.org/EN/Y2019/V39/I6/550

Fig.1  Schematic drawing of the experimental device
MaterialRust removal solutionCleaning time / minCleaning temperature / ℃
Q235 steel

500 mL HCl (relative density 1.19),

3.5 g C6H12N4, 500 mL pure water

1020~25

Galvanized steel /

zinc clad steel

100 g (NH4)2S2O8, 1000 mL pure water520~25

Copper /

copper clad steel

500 mL HCl (relative density 1.19),

500 mL pure water

320~25
Zinc-magnesium alloy and copper clad steel100 g (NH4)2S2O8, 1000 mL pure water520~25
Conductive coated steel1000 mL pure water1520~25
Stainless steel clad steel

100 mL HNO3 (relative density 1.41),

900 mL pure water

2060
Table 1  Formulation and cleaning parameters of rust removal solution
Fig.2  Corrosion rates of grounding materials during field and accelerated corrosion tests
Fig.3  Surface morphologies of grounding materials after field corrosion test for 296 d in red soil: (a) Q235 steel, (b) galvanized steel, (c) zinc clad steel, (d) zinc-magnesium alloy and copper clad steel, (e) copper, (f) copper clad steel, (g) conductive coating clad steel, (h) stainless steel clad steel
Fig.4  Surface morphologies of grounding materials after accelerated corrosion test for 30 d in red soil: (a) Q235 steel, (b) galvanized steel, (c) zinc clad steel, (d) zinc-magnesium alloy and copper clad steel, (e) copper, (f) copper clad steel, (g) conductive coating clad steel, (h) stainless steel clad steel
Fig.5  Micro-surface morphologies of grounding materials after field corrosion test for 296 d in red soil: (a) Q235 steel, (b) galvanized steel, (c) zinc clad steel, (d) zinc-magnesium alloy and copper clad steel, (e) copper, (f) copper clad steel, (g) conductive coating clad steel, (h) stainless steel clad steel
Fig.6  Micro-surface morphologies of grounding materials after accelerated corrosion test for 30 d in red soil: (a) Q235 steel, (b) galvanized steel, (c) zinc clad steel, (d) zinc-magnesium alloy and copper clad steel, (e) copper, (f) copper clad steel, (g) conductive coating clad steel, (h) stainless steel clad steel
MaterialCorrosion test methodMain components of corrosion product
Q235 steelField corrosion testFeOOH, Fe2O3, Fe3O4, FeS, SiO2
Accelerated corrosion testFeOOH, Fe2O3, Fe3O4, SiO2
Galvanized steelField corrosion testZnO, FeOOH, Fe2O3, SiO2
Accelerated corrosion testZnO, FeOOH, Fe2O3, SiO2
Zinc clad steelField corrosion testZn, ZnO, SiO2
Accelerated corrosion testZn, ZnO, SiO2
Zinc-magnesium alloy and copper clad steelField corrosion testZn, Zn(OH)2, MgCO3, SiO2
Accelerated corrosion testZn, Zn(OH)2, MgCO3, SiO2
CopperField corrosion testCu, CuO, Cu2O, Cu2(OH)2CO3
Accelerated corrosion testCu, CuO, Cu2O
Copper clad steelField corrosion testCu, CuO, Cu2O, Cu2(OH)2CO3
Accelerated corrosion testCu, CuO, Cu2O
Table 2  Result of XRD analysis of rusted samples
Fig.7  Pearson's interrelation of field corrosion test and accelerated corrosion test
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