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INVETIGATION OF THE CORROSION OF COLLECTION PIPE OF DEHYDRATED NATURAL GAS TRANSPORT |
Liewei Liu;;; |
华中科技大学化学系 |
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Abstract New processes of dehydration with triglycol are applied in the transport of natural gas in Sichuan-east Datianchi oil/gas field.Accidents of cracking and perforation still occurred in the collection pipe of natural gas transport. The spot loss-sample and corrosion product collected form the pipe were analzed with X-ray diffraction, electron probe microscopy analysis (EPMA),scanning electron microscope and thermal analysis. The analysis results show that the collection pipe of natural gas transport suffered severe hydrogen sulfide corrosion though new processes of dehydration had been introduced. The pattern of corrosion showed fron loss-sample was pitting corrosion. The composed of FeS, FeS2, Fe3S4,and Fe9S8, some ferrous oxide composition and something else.Thermal analysis of corrosion product sample shows that a strong exothernic reaction exists between 170℃ to 350℃, the enthalpy value(△H) is about -256.8J/g.
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Received: 20 September 1999
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Corresponding Authors:
Liewei Liu
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[1] Sardisco J B, Wright W B, Greco E. C. Corrosion of iron in H2S -CO2- - H2O system corrosion film properties on pure iron[J],Corrosion, 1963, 19(10): 354 - 359 [2] Ogundele G l, White W E. Some observations on corrosion of carbon steel in sour gas environments[J]. Corrosion, 1986, 42(7): 398 - 408 |
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