|
|
A STUDY ON SURFACE STATE DURING THE PRETREATMENT OFELECTROLESS NICKEL PLATING ON MAGNESIUM ALLOYS |
;; |
上海交通大学金属基复合材料国家重点实验室 |
|
|
Abstract Changes of the surface state during the pretreatmen t of electroless nickel plating (EN) on magnesium alloys were studied using weig ht loss method,scanning electron microscopy (SEM) and X-ray photoelectron spectr oscopy (XPS).The results showed that the pretreatment of electroless nickel plat ing on magnesium alloys was a process of one protective film replacing another a nd magnesium was protected all the time.Due to the formation of Mg(OH)2 and Mg F2 film on the surface,alkaline cleaning and activating made little attack to the substrate.Different etching solutions gave different etch rates and resultan t morphologies.The CrOOH- containing film,which was formed during etching,disapp eared after activation.Effects of the changes of surface state during the pretre atment on subsequent EN procedure were also discussed.
|
Received: 07 August 2000
|
|
[1] Froes F H, Eliezer D, Aghion E.The science, technology and applications of magnesium[J]. JOM, 1998,9:30 [2] Fairweather W A. Electroless nickel plating of magnesium[J]. Trans. IMF, 1997,75(3): 113 [3] Sakata Y- Electroless nickel plating directly on magnesium alloy diecastings[A]. The Proceedings of the 74th AESF Annual Technical Conference[C]. Orlando: AESF, 1987, 6 [4] ASTM B480-88, Standard Guide for Preparation of Magnesium and Magnesium Alloys for Electroplation, Annual Book of ASTM Standards 2000, Volume 02.05, PA: ASTM, 2000,188 - 190 [5] Riedel W . Electroless Nickel Plating[M]. England: Finishing Publication Ltd. , 1991 [6] Mallory G O, Hajdu J B. Electroless Plating: Fundamentals & Applications[M]. Orlando:AESF, 1990 [7] Poubaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions[M].Houston: NACE, 1974 [8] Wagner C D. Handbook of X- ray Photoelectron Spectrosropy[M].Minnesota: Perkin - Elmer Corp., 1979 [9] Wang J Q, Wu W H, Feng D M.The Introduction to Electron Spectroscopy(XPS/XAES/UPS)[M]. Beijing:National Defense Industry Press, 1992 (王建琪,吴文辉,冯大明编著.电子能谱学(XPS/XAES/UPS)引论[M].北京:国防工业出版社.1992) |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|