Alloying of Compositionally Modulated Cu/Ni Multilayer Films and Corrosion Performance of Cu-Ni Alloy Coatings

doi:10.11092/1005.4537.2013.144

Journal of Chinese Society for Corrosion and protection

2014, Vol. 34

Issue (6): 523-531 DOI: 10.11092/1005.4537.2013.144

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Alloying of Compositionally Modulated Cu/Ni Multilayer Films and Corrosion Performance of Cu-Ni Alloy Coatings

LUO Lili, FEI Jingyin(

), WANG Lei, LIN Xihua, WANG Shaolan

Faculty of Science,Northwestern Polytechnical University, Xi'an 710129, China

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Abstract

Cu/Ni multilayered films were prepared by a two step electrodeposition method. The influence of the modulation wavelength and heat treatment condition on the alloying of Cu/Ni multilayered films were studied by means of SEM and XRD. The results showed that the Cu-Ni alloy coatings with well homogeneity in microstructure and composition can be prepared by the alloying of Cu/Ni multilayered films; the alloying process would be favored with the decreasing modulation wavelength as well as the increasing temperature and time of heat-treatment. Besides, the corrosion performance of coatings of copper, nickel and Cu-Ni alloy were comparatively evaluated by immersion test in NaCl solution. The results showed that the Cu-Ni alloy coatings exhibited much positive corrosion potential, smaller polarized current density and lower corrosion rate rather than the pure copper and nickel coatings.

Key words: Cu/Ni multilayer film the alloying electrodeposition corrosion resistance

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LUO Lili, FEI Jingyin, WANG Lei, LIN Xihua, WANG Shaolan. Alloying of Compositionally Modulated Cu/Ni Multilayer Films and Corrosion Performance of Cu-Ni Alloy Coatings. Journal of Chinese Society for Corrosion and protection, 2014, 34(6): 523-531.

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https://www.jcscp.org/EN/10.11092/1005.4537.2013.144 OR https://www.jcscp.org/EN/Y2014/V34/I6/523

Table 1 Copper and nickel baths used for the deposition of Cu/Ni CMMF

Fig.1 Surface morphologies of Cu/Ni CMMF with different period thickness: (a) λ=4 μm, (b) λ=2 μm, (c) λ=1 μm

Fig.2 Cross-sectional morphologies of Cu/Ni CMMF with different modulated wavelength: (a) λ=4 μm, (b) λ=2 μm, (c) λ=1 μm

Table 2 Influencing factor and level during heat treatment of Cu/Ni CMMF

Fig.3 Table header design

Table 3 Orthogonal test program and results

Fig.4 Cross sections of Cu-Ni CMMF with different modulation wavelength after heat treatment at 700 ℃ for 3 h:

(a) λ=4 μm, (b) λ=2 μm, (c) λ=1 μm

Fig.5 Effect of modulated wavelength on alloying of Cu/Ni CMMF

Fig.6 Cross-sectional morphologies of Cu-Ni CMMF with the period thickness of 2 μm after heat treatment temperature for 3 h at 300 ℃ (a), 500 ℃ (b), 700 ℃ (c) and 900 ℃ (d)

Fig.7 Influence of temperature on alloying of Cu/Ni CMMF

Fig.8 Section morphologies of Cu-Ni CMMF with the period thickness of 2 μm after heat treatment at 700 ℃ for 1 h (a), 3 h (b) and 8 h (c)

Fig.9 Effect of heating time on alloying of Cu/Ni CMMF

Table 4 Analysis of covariance table

Fig.10 Surface (a) and cross-sectional (b) morphologies of alloyed Cu-Ni coatings

Fig.11 XRD patterns of Cu/Ni CMMF before (a) and after (b) alloying

Table 5 Dependence of corrosion potentials (E_corr) on coating configurations

Fig.12 Anodic polarization curves for copper coating on copper substrate in 3.5%NaCl solutions with different

pH values

Fig.13 Anodic polarization curves for nickel coating on copper substrate in 3.5%NaCl solutions with different pH

values

Fig.14 Anodic polarization curves for alloyed Cu-Ni coating on copper substrate in 3.5%NaCl solutions with different pH values

Table 6 Corrosion rate of Cu, Ni, Cu-Ni coatings in different conditions

[1]	Foecke T, Lashmore D S. Mechanical behavior of compositionally modulated alloys: multilayers[J]. Scr. Metall. Mater., 1992, 27: 651-656
[2]	Flevaris N K, Logothetidis S. Optical anisotropy in compositionally modulated Cu-Ni films by spectroscopic ellipsometry[J]. Appl. Phys. Lett., 1987, 50(22): 1544-1546
[3]	Yu J X, Chen Y Y, Huang Q A. Electrochemical preparation and properties measurement of nanolaminar metallic multilayers[J]. Mater. Prot., 1997, 30(7): 1-3
	(喻敬贤, 陈永言, 黄清安. 纳米金属多层膜的电化学制备与性能研究的现状[J]. 材料保护, 1997, 30(7): 1-3)
[4]	Huang Q A, Wang Y P, Zhang K, et al. Review of electrodeposition of metallic multilayers[J]. Plat. Finish., 1998, 17(1): 48-51
	(黄清安, 王银平, 张葵等. 电沉积法制备金属多层膜的述评[J]. 电镀与涂饰, 1998, 17(1): 48-51)
[5]	Stoudt M R, Cammarata R C, Ricker R E. Suppression of fatigue cracking with nanometer-scale multilayered coatings[J]. Scr. Mater., 2000, 43: 491-496
[6]	Zhang W, Xue Q J. Tribological properties of nickel-copper multilayer film on beryllium bronze substrate[J]. Thin Solid Films, 1997, 305: 292-296
[7]	Baibich M N, Broto J M, Fert A, et al. Giant magnetoresistance of (001) Fe/(001) Cr magnetic supperlatices[J]. Phys. Rev. Lett., 198861(21): 2472-2475
[8]	Gyorgy E M, McWhan D B, Dillon J F, et al. Magnetic behavior and structure of compositionally modulated Cu-Ni thin films[J]. Phys. Rev., 1982, 25B: 6739-6747
[9]	Gyorgy E M, Dillon J F, Jr McWhan D B, et al. Magnetic properties of compositionally modulated Cu-Ni thin films[J]. Phys. Rev. Lett.1980, 45: 57-60
[10]	Testardi L R, Willens R H, Krause J T, et al. Enhanced elastic moduli in Cu-Ni films with compositional modulation[J]. J. Appl. Phys., 1981, 52(1): 510-511
[11]	Cammarata R C, Schlesinger T E, Kim C, et al. Nanoindentation study of the mechanical properties of copper-nickel multilayered thin films[J]. Appl. Phys. Lett., 1990, 56(19): 1862-1864
[12]	Menezes S, Anderson D P. Wavelength-property correlation in electrodeposited ultrastructured Cu-Ni multilayers[J]. J. Electrochem. Soc., 1990, 137(2): 440-444
[13]	Tench D, White J. Enhanced tensile strength for electrodeposited nickel-copper multilayer composites[J]. Metall. Trans., 1984, 15(11)A: 2039-2040
[14]	Baral D, Ketterson J B, Hilliard J E. Mechanical properties of composition modulated Cu-Ni foils[J]. J. Appl. Phys., 1985, 57(4): 1076-1083
[15]	Gabe D R. Protective layered electrodeposits[J]. Electrochim. Acta, 1994, 39(8/9): 1115-1121
[16]	Liao Y, Gabe D R, Wilcox G D. A study of zinc-iron alloy electrodeposition using a rotating cylinder hull cell[J]. Plat. Surf. Finish., 1998, 85(3): 60-66
[17]	Watson S A. Zinc-nickel alloy electroplated steel coil and other precoated coil for the use by the automotive industry[J]. Nickel Develop. Inst. Rev., 1988, 13001: 235-258
[18]	Kirilova I, Ivanov I, Rashkov St. Anodic behaviour of composition modulated Zn-Co multilayer electrodeposited from single and dual bath[J]. Appl. Electrochem., 1998, 28: 1359-1363
[19]	Benballa M, Nils L, Sarret M, et al. Zinc-Nickel codeposition in ammonium baths[J]. Surf. Coat. Technol., 2000, 123(1): 55-61
[20]	Fei J Y, Liu J H, Liang G Z, et al. Electrodeposition of composiyionally modulated multilayer Zn-Ni alloy coatings[J]. Corros. Sci. Prot. Technol., 2006, 18(1): 24-27
	(费敬银, 刘江宏, 梁国正等. 电沉积法制备组分调解Zn-Ni合金多层镀层[J]. 腐蚀科学与防护技术, 2006, 18(1): 24-27)
[21]	Fei J Y, Wilcox G D. Electrodeposition of zinc-nickel compositionally modulated multilayer coatings and their corrosion behaviours[J]. Surf. Coat. Technol., 2006, 200(11): 3533-3539
[22]	Xu H B, Fu H T, Zhao G Y. Electrochemical study on dissolution mechanism of copper anode in the active region[J]. J. Chin. Soc. Corros. Prot., 1999, 19(1): 27-32
	(徐海波, 付洪田, 赵广宇. 铜阳极活性区溶解机制的电化学研究[J]. 中国腐蚀与防护学报, 1999, 19(1): 27-32)
[23]	Dhar H P, White R E, Burnell G, et al. Corrosion of Cu and Cu-Ni alloys in 0.5M NaCl and in synthetic seawater[J]. Corrosion, 198541(6): 317-323
[24]	Kear G, Barker B D, Stokes K, et al. Electrochemical corrosion behaviors of 90-10 Cu-Ni alloy in chloride-based electrolytes[J]. J. Appl. Electrochem., 2004, 34: 659-669

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