|
Abstract Self-assembled monolayers (SAMs) have important application in corrosion prevention of metals due to their dense, ordered, ultrathin and stable structure. In this paper SAMs of organosulfurs, fatty acids, organosilicon derivatives, diphosphates, schiff bases and imidazolines are introduced in detail. Their applications in corrosion protection of metals, such as gold, silver, copper and iron are reviewed, respectively. The development of SAMs in the field of corrosion and protection of metals is predicted.
|
Received: 14 March 2006
|
|
Corresponding Authors:
YANG Chang-jiang
E-mail: chjiyang@sina.com
|
[1]Bigelow W C,Pickett D L,Zisman W A.Oleophobic monolayersI.Films adsorbed from solution in non-polar liquids[J].J.ColloidInterface.Sci.,1946,1:513-538 [2]Nuzzo R G,Allara D L,Ralph G N,et al.Adsorption of bifunc-tional organic disulfides on gold surfaces[J].J.Am.Chem.Soc.,1983,105:4481-4483 [3]Kong Y,Zhang S Y,Li H J.Study of the effect of n-dodecanethi-ol self-assembled monolayer on the improvement of corrosion pro-tection of epoxy coating[J].Acta Chem.Sin.,2004,62(17):1612-1616(孔燕,张树永,李红娟.正十二硫醇自组装单层膜改善环氧涂层腐蚀防护性能的研究[J].化学学报,2004,62(17):1612-1616) [4]Yu T T.Structural comparison of self-assembled monolayers of n-alkanoic acids on the surfaces of silver,copper and aluminum[J].J.Am.Chem.Soc.,1993,115(10):4350-4358 [5]Hai W L,Larry J K,Hun G H,et al.Inorganic analogs of Lang-muir-Blodgett films:adsorption of ordered zirconium 1,10-de-canebisphosphonate multilayers on silicon surfaces[J].J.Am.Chem.Soc.,1988,110(2):618-620 [6]Sunder R,Bao L T,Mario B,et al.Self-assembled monolayermechanism for corrosion inhibition of iron by imidazolines[J].Langmuir,1996,12(26):6419-6428 [7]Wang Y,Gu N,Guo Z,et al.Method for assembling self-assem-bled corrosion-inhibiting nano-film on metal[P].CN 1485377 A31,2004 [8]Kim H,Zhang J,Gandour R D,et al.Method of protecting met-als from corrosion using thiol compound[P].US 2005186347 A125,2005 [9]Feng Z,Cha E.Hybrid anti-corrosion coating for magnetic headscomprising thin diamond-like carbon layer and self-assembledmonolayer[P].US 2004223256 A1 11,2004 [10]Francis P Z,Richard M C.In-situ electrochemical scanning tun-neling microscopy study of cyanide-induced corrosion of nakedand hexadecyl mercaptan-passivated Au(111)[J].Langmuir,1997,13(2):122-126 [11]Francis P Z,Richard M C.Corrosion passivation of gold by n-alkanethiol self-assembled monolayer:effect of chain length andend group[J].Langmuir,1998,14(12):3279-3286 [12]Cao Z,Gu N.Investigation on gold corrosion by in situ quartzcrystal microbalance and atomic force microscopy in self-assem-bled processes of alkanethiol monolayers[J].Mater.Lett.,2005,59(28):3687-3693 [13]Cao Z,Xiao Z L,Gu N,et al.Corrosion behaviors on polycrys-talline gold substrates in self-assembled processes of alkanethiolmonolayers[J].Anal.Lett.,2005,38(8):289-1304 [14]Magali E,Michel K,Hisasi T.The formation of sel-assemblingmembrane of hexadecane-thiol on silver to prevent the tarnishing[J].Electrochi.Acta,2004,49:1937-1943 [15]Burleigh T D,Gu Y,Donahey G,et al.Tarnish protection ofsilver using a hexadecanethiol self-assembled monolayer and de-scriptions of accelerated tarnish tests[J].Corrosion,2001,57(12):1066-1074 [16]Bernard M C,Dauvergane E,Evesque M,et al.Reduction ofsilver tarnishing and protection against subsequent corrosion[J].Corros.Sci.,2005,47:663-679 [17]Burleigh T D,Shi C,Kilic S,et al.Self-assembled monolayersof perfluoroalkyl amideethanethiols,fluoroalkylthiols,and alkylth-iols for the prevention of silver tarnish[J].Corrosion,2002,58(1):49-56 [18]Liu J H,Wang Y H,Guo Z R,et al.Self-assembled layer onsilver for protection against corrosion[J].J.Chem.Indu.Eng.,2004,55(10):1674-1677(刘金红,王怡红,郭志睿等.银表面分子自组装膜的防腐性能[J].化工学报,2004,55(10):1674-1677) [19]Hutt D A,Liu C.Oxidation protection of copper surfaces usingself-assembled monolayers of octadecanethiol[J].Appl.Surf.Sci.,2005,252(2):400-411 [20]Whelan C M,Kinsella M,Ho H M,et al.In-situ cleaning andpassivation of oxidized Cu surfaces by alkanethiols and its applica-tion to wire bonding[J].J.Electro.Mater.,2004,33(9):1005-1011 [21]Feng Y,Teo W K,Siow K S,et al.Corrosion protection of copperby a self-assembled monolayer of alkanethiol[J].J.Electrochem.Soc.,144(1):55-64 [22]Ma H Y,Yang C,Yin B S,et al.Electrochemical characteriza-tion of copper surface modified by n-alkanethiols in chloride-con-taining solution[J].Appl.Surf.Sci.,2003,218:143-153 [23]Wen D J,Feng F.Corrosion inhibition behavior of n-dodecanethi-ol on copper in acid media[J]J.Chem.Ind.Eng.,2005,56(7):1363-1367(闻荻江,冯芳.正十二烷基硫醇对铜在酸性介质中的缓蚀行为[J].化工学报,2005,56(7):1363-1367) [24]Jennings G K,Munro J C,Yong T H,et al.Effect of chain lengthon the protection of copper by n-alkanethiols[J].Langmuir,1998,14(21):6130-6139 [25]Jennings G K,Yong T H,Munro J C,et al.Structural effects onthe barrier properties of self-assembled monolayers formed long-chainω-alkoxy-n-alkanethiols on copper[J].J.Am.Chem.Soc.,2003,125(10):2950-2957 [26]Tan Y S,Srinivasan M P,Pehkonen S O,et al.Self-assembledorganic thin films on electroplated copper for prevention of corro-sion[J].J.Vac.Sci.Technol.A:Vacuum,Surfaces and Films,2004,22(4):1917-1925 [27]Wang C,Chen S,Zhao S.Inhibition effect of as-treated,mixedself-assembled film of phenylthiourea and 1-dodecanethiol oncopper corrosion[J].J.Electrochem.Soc.,2004,151(1):B11-B15 [28]Wang C T,Chen S H.A new approach for preparing effective in-hibition film on copper based on self-assembled process[J].Chin.Chem.Lett.,2003,14(3):308-311 [29]Wang C T,Chen S H,Zhao S Y,et al.Inhibition effect ofalkylthiourea and 12-dodecanethiol on copper corrosion[J].ActaChem.Sin.,2003,61(2):151-155(王春涛,陈慎豪,赵世勇等.烯丙基硫脲和十二烷基硫醇对铜的缓蚀作用[J].化学学报,2003,61(2):151-155) [30]Aramaki K.Preparation of protective films on copper by chemicalmodification of alkanethiol self-assembled monolayer[J].Zairyo toKankyo,2002,51(4):136-143 [31]Quan Z,Chen S,Cui X,et al.Factors affecting the quality andcorrosion inhibition ability of self-assembled monolayers of aSchiff base[J].Corrosion,2002,58(3):248-256 [32]Chen Y H,Wang Q F,Ding K Q,et al.Corrosion protection ofcopper by a self-assembled monolayer of B2et2B Schiff base[J].J.Hebei Normal Univ.(Natural Science Edition),2003,27(4):377-379(陈玉红,王庆飞,丁克强等.B2-et-2B自组装膜对铜的缓蚀作用[J].河北师范大学学报(自然科学版),2003,27(4):377-379) [33]Cui W Z,Ding K Q,Wang Q F,et al.Corrosion protection ofcopper by a self-assembled monolayer of Schiff base[J].J.HebeiNormal Univ.(Natural Science Edition),2002,26(4):381-383(崔维真,丁克强,王庆飞等.席夫碱自组装膜对铜的腐蚀保护[J].河北师范大学学报(自然科学版),2002,26(4):381-383) [34]Lusk A T,Jennings G K.Characterization of self-assembled mono-layers formed from sodium S-alkyl thiosulfates on copper[J].Langmuir,2001,17(25):7830-7836 [35]Telegdi J,RigóT,Kálmán E.Molecular layers of hydroxamicacids in copper corrosion inhibition[J].J.Electroanal.Chem.,2005,582(1-2):191-201 [36]Telegdi J,RigóT,Kálmán E.Nanolayer barriers for inhibition ofcopper corrosion[J].Corros.Eng.Sci.Technol.,2004,39(1):65-70 [37]Wang D Q,Chen S H,Ma H Y,et al.Protection of copper cor-rosion by carbazole and N-vinylcarbazole self-assembled films inNaCl solution[J].J.Appl.Electrochem.,2003,33(2):179-186 [38]Felhosi I,Telegdi J,Palinkas G,et al.Kinetics of self-assem-bled layer formation on iron[J].Electrochi.Acta,2002,47(13-14):2335-2340 [39]Felhosi I,Kalman E,Poczik P.Corrosion protection by self-as-sembly[J].Russ.J.Electrochem.,2002,38(3):230-237 [40]Miecznikowski K,Chojak M,Steplowska W,et al.Two-layerstructures of ultra-thin metal hexacyanoferrate films:Charge trap-ping and possibility of application to corrosion protection[J].Pol.J.Chem.,2004,78(9):1183-1193 [41]Aramaki K.Preparation of protective films on iron by chemicalmodification of self-assembled monolayers[J].Zairyo to Kankyo,2003,52(7):332-339 [42]Ohkubo H,Itoh J,Nagano H,et al.Corrosion prevention of pureiron using self-assembled monolayer coating[J].Zairyo to Kankyo,2003,52(6):316-318 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|