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EFFECT OF RARE EARTH ON CORROSION RESISTANCE OF ELECTROLESS Ni-P/PVDF PLATINGS |
DING Jie, ZHANG Benge, YAN Mingzhen, LIU Jia |
China Petroleum Pipeline Engineering Corporation, Langfang 065000 |
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Abstract Ni-P/PVDF(RE) composite platings were deposited by adding rare earth elements Y3+ and La3+ into electroless Ni-P/PVDF alloy baths. The effects of rare earth content on corrosion resistance were estimated by electrochemical polarization measurement. The results indicate that at the proper rare earth content, the surface morphology of the electroless Ni-P/PVDF(RE) plating is more uniform and denser than that of Ni-P/PVDF plating. The corrosion resistance of the coatings increases at low rare earth content, and then decreased with the increase of its content. The optimum content of rare earth in plating bath is 0.1 g/L. Under the synergetic effect of rare earth and PVDF particles, the corrosion resistance of the Ni-P/PVDF(RE) plating is enhanced.
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Received: 17 March 2011
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Corresponding Authors:
DING Jie
E-mail: cppedingjie@cnpc.com.cn
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[1] Du T. Some physicochemical application of rare earth for metal materials[J]. Acta Metall. Sin., 1997, 33 (l): 69-77 (杜挺. 稀土元素在金属材料中的一些物理化学作用[J]. 金属学报, 1997,33(l): 69-77)[2] Hu W B, Liu L, Wu Y T. Plating Difficult Substrates with Electroless [M]. Beijing: Chemical Industry Press, 2003 (胡文彬, 刘磊, 仵亚婷. 难镀基材的化学镀镍技术[M]. 北京:化学工业出版社, 2003)[3] Yan H. New Technology of Metal Surface Treatment [M].Beijing: Metallurgical Industry Press, 1996 (阎洪.金属表面处理新技术[M]. 北京: 冶金工业出版社, 1996)[4] Zhang L, Xuan T P, Huang Q H. Effect of Ce on electroless Co-Ni-P plating process[J]. Plat. Finish., 2002, 24(1): 1-4 (章磊, 宣天鹏, 黄芹华. 铈对化学镀Co-Ni-P合金工艺的影响[J].电镀与精饰, 2002, 24(1): 1-4)[5] Yan M, Zhang X X. Effect of Yb on structure and corrosion resistance of electroless Ni-P platings[J]. Chin. J. Rare Met.,2005, 29(3): 285-288 (严密, 张小星.镱对镍磷合金化学镀组织和抗腐蚀性能的影响[J]. 稀有金属, 2005, 29(3):285-288)[6] Shao G J, Qin X J, Wang H Y, et al. Influence of RE element on Ni-P coelectrodeposition process[J]. Mater. Chem. Phys.,2003, 80(3): 334-338 |
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