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ELECTROCHEMICAL ELEVATION OF CORROSION RESISTANCE OF OLIVE-GREEN FILM ON LY12 Al ALLOY PREPARED IN NaOH |
TANG Zilong1;2; LIU Zhe1 |
1.School of Materials Science and Engineering; Tianjin University; Tianjin 300072
2.Tianjin Key Laboratory of Composite and Functional Materials; Tianjin University; Tianjin 300072 |
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Abstract Corrosion performance of olive green film on LY12 Al alloy, prepared electrolytically in 0.2 mol/L NaOH at room temperature, is evaluated by electrochemical techniques including dynamical potential anodic polarization curve and polarization resistance. Good passivity of the color film in both acid and neural media and pitting resistance are demonstrated according to the results. Moreover, the color film also shows good long-term corrosion resistance in various aggressive corrosion solutions. The structure, composition and morphology of the color film are analyzed with the help of X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The color film, a little more 4 μm in thickness, is mainly composed by α-alumina based on XRD. The enrichment of O and other corrosion-resistance elements inside film benefits the corrosion performance of LY12 alloy, also helps the stabilization of film color.
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Received: 04 June 2008
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Corresponding Authors:
TANG Zilong
E-mail: zlt633@gmail.com
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[1] Wu M, Sun Y. Development of surface treatment for aluminum and its alloy [J]. Surf. Technol., 2003, 32(3): 13-15
(吴敏,孙勇. 铝及其合金表面处理的研究现状 [J]. 表面技术, 2003,32(3): 13-15)
[2] Wang H C, Peng Q, Wang X Y. Corrosion resistance of anodized aluminum oxide film [J]. Corros. Prot., 2006,27(8): 391-393
(王海潮, 彭乔, 王啸宇. 电化学法研究铝阳极氧化膜的抗腐蚀性 [J]. 腐蚀与防护,2006, 27(8): 391-393)
[3] Cheng W, Chen R Y, Zheng X, et al. Study on black coloring of aluminum alloy surface [J]. Plat. Finish., 2000,22(6): 5-7
(程蔚, 陈日耀, 郑曦等. 铝合金表面着亮黑色的研究 [J]. 电镀与精饰, 2000, 22(6): 5-7)
[4] Zhang Y G. Electrolytic coloring of anodizing aluminum film in ferrous sulfate solution [J]. Light Alloy Process. Technol., 2003, 31: 40-42
(张永光. 铝阳极氧化膜在亚铁盐溶液中的电解着色 [J]. 轻合金加工技术, 2003,31: 40-42)
[5] Ding L H, Zhang J, Zheng Y. Plasma-prepared Ni/Al2O3:preparation, characterization and toluene hydrogenation [J]. Inter.J. Chem. React. Eng., 2006, 4: 1-7
[6] Yang Z S, Jia J F, Tian J. Preparation of micro-arc discharge oxidized coating on hot-tip aluminized stainless steel sheet [J]. J. Inorg. Mater.,2004,19(6):1446-1450
(杨钟时,贾建峰,田均. 不锈钢表面Al2O3膜的微弧氧化制备 [J].无机化学学报,2004,19(6):1446-1450)
[7] Chen Y Z, Wu S, Shen L R. Study on microstructure of AlN produced by N+ implantation into pure aluminum [J]. Nuclear Technol., 2003, 26(4): 295-298
(陈勇忠, 武胜, 沈丽如. 氮离子注入铝的结构研究 [J]. 核技术, 2003,26(4): 295-298)
[8] Chen J M, Qian J F, Ma M. The development of self-healing Al2O3 insulating coating [J]. Surf. Technol., 2002, 31:32-36
(湛继明,钱家缚,马梅. 自修复三氧化二铝涂层研究 [J]. 表面技术,2002, 31: 32-36)
[9] Chik H, Xu J M. Nanometric superlattices:non-lithog raphic fabrication, materials, and prospects [J]. Mater.Sci. Eng., 2004, R43: 103-138
[10] Li G Q, Li D, Li J Q. Cerium conversion coating formed on anodized aluminum by cathodic electrolysis [J]. J. Chin. Soc. Corros. Prot., 2001, 21(3): 150-157
(李国强, 李荻, 李久青. 铝合金阳极氧化膜上阴极电解沉积的稀土铈转化膜 [J]. 中国腐蚀与防护学报, 2001, 21(3): 150-157 )
[11] Ren J J, Zuo Y. The study on morphology and growth mechanism of pits on anodized aluminum [J]. J. Chin. Soc.,Corros. Prot., 2003, 23(4):198-201
(任建军,左禹. 铝阳极氧化膜的蚀孔形貌与蚀孔生长机理研究 [J]. 中国腐蚀与防护学报, 2003, 23(4):198-201)
[12] Zhu Z F. Al Anodic Oxidation and Surface Finishing Techniques [M]. Beijing: Chemical Industry Press 2004
(朱祖芳.铝合金阳极氧化与表面处理技术 [M].化学工业出版社,北京,2004)
[13] Hou Z H, Liu J P, Xu Y. Investigation on the components, appearance and structure of high voltage anodization film on aluminum [J]. J. Chin. Soc. Corros. Prot.,2001,21(3):177-181
(侯朝辉,刘建平,许岩. 铝表面高压阳极氧化膜层结构分析 [J]. 中国腐蚀与防护学报, 2001,21(3):177-181)
[14] Wang L X, Pan A J, Yang Z Q. Structure and electrolytic coloring performance of nanometer al oxide film [J]. J. Shanghai Inst. Technol., 2003, 3: 232-235
(王莉贤, 潘安健, 杨志强. 纳米级铝氧化膜的结构与电解着色性能 [J].上海应用技术学院学报, 2003, 3: 232-235)
[15] Schofield E. Anodic routes to nanoporous materials [J].Trans. Inst. Met. Finish., 2005, 83(1): 35-42
[16] Badawy W,Al-Kharafi F M,EI-Azab A S. Electro chemical behaviour and corrosion inhibition of Al,Al-6061 and Al-Cu in natural aqueous solution [J]. Corros.Sci., 1999, 41:709-727
[17] Lenderink H J W, Linden M,Wit J H W.Corrosion of aluminum in acidic and natural solutions [J]. Electrochim. Acta,1993,38(14):1989-1992
[18] Pyun S I, Moon S M,Ahn S H. Effects of ions on anodic dissolution of pure aluminum in alkaline solution [J]. Corros. Sci., 1999,41:653-667
[19] Shaffei M F, El-Rehim S S, Shaaban N A. Electrolytic coloring of anodic aluminum for selective solar absorbing films [J]. Met.Finish., 2001, 11: 27-30
[20] Xia S J, Yue R, Rateick R G.Electrochemical studies of AC/DC anodized Mg alloy in NaCl solution [J]. J. Electrochem. Soc., 2004, 151(3): B179-B187
[21] Shuker I, Newby K R. Why functional trivalent chromium fails and hexavalent chromium is environmentally friendly[J]. Trans.Inst. Met. Finish., 2005. 83(6): 272-274
[22] Liu Z, Tang Z L. Study on coloring technique of LY12 Al alloy in NaOH solution [J]. Corros. Sci. Prot. Technol., submitted
(刘哲,唐子龙. LY12 铝合金在弱碱性介质中的着色工艺研究 [J]. 腐蚀科学与防护技术, 待发表)
[23] Wei J S, Tang Z L, Song S Z. Coloring of 304 stainless steel in NaOH by modularized potential [J]. Surf. Technol., 2007,36(5): 43-45
(魏军胜,唐子龙,宋诗哲. 碱性介质中304不锈钢交流调制电位着色工艺研究 [J]. 表面技术, 2007, 36(5): 43-45)
[24] Tang Z L, Li G D, Wei J S. Electrochemical evaluation of corrosion performance of 304 stainless steel with oxide skin cleaned electrolytically [J]. J. Chem. Ind. Eng., 2007, 58(9), 2306-2312
(唐子龙,李国栋,魏军胜. 电解清除氧化皮的304不锈钢盘条耐蚀性的电化学评价 [J]. 化工学报, 2007, 58(9), 2306-2312)
[25] Tang Z L, Song S Z. Performance evaluation techniques of film and coating on stainless steel [J]. J. Chin. Soc. Corros.Prot., 2008,28(2):121-128
(唐子龙,宋诗哲. 不锈钢耐蚀装饰膜的性能检测 [J].中国腐蚀与防护学报,2008,28(2):121-128) |
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