POTENTIOSTATIC CURRENT OSCILLATIONS OF IRON IN H_2SO_4 SOLUTION UNDER THE INFLUENCE OF Cl~- AND MAGNETIC FIELDS

J Chin Soc Corr Pro

1998, Vol. 18

Issue (1): 27-34 DOI:

Current Issue | Archive | Adv Search

POTENTIOSTATIC CURRENT OSCILLATIONS OF IRON IN H_2SO_4 SOLUTION UNDER THE INFLUENCE OF Cl~- AND MAGNETIC FIELDS

WANG Chao LEI Sheng-bin CHEN Shen-hao YU Xi-ling (Department of Chemistry; Shandong University; Jinan; 250100)

Download:

PDF(2821KB)
Export: BibTeX | EndNote (RIS)

Abstract The effects of Cl- and external magnetic fields on potentiostatic current oscillations in Fe/0.5mol·L-1 H2SO4 system were studied with electrochemical methods and holographic microphotography. The imposed magnetic field influenced the current oscillations by speeding up the mass transfer and leading to the increase in the ratio of activation time to passivation time (ta/tp). The addition of Cl- inhibited the growth of the passive film, resulting in the increase in the ta/tp, and positive shifting and narrowing down of the oscillation potential range. The existence of both the magnetic field and C- had concurrent influence on current oscillations, which might be brought about chiefly by the increase in the magnetic susceptibility of the substance formed at the iron/solution interface.

Key words: Magnetic field Cl- Iron electrode Electrochemical oscillations

Received: 25 February 1998

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors

Cite this article:

WANG Chao LEI Sheng-bin CHEN Shen-hao YU Xi-ling (Department of Chemistry; Shandong University; Jinan; 250100). POTENTIOSTATIC CURRENT OSCILLATIONS OF IRON IN H_2SO_4 SOLUTION UNDER THE INFLUENCE OF Cl~- AND MAGNETIC FIELDS. J Chin Soc Corr Pro, 1998, 18(1): 27-34.

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y1998/V18/I1/27

1 Podesta J J, Piatti R C V, Arvia A J. J. Electrochem. Soc., 1979, 126:1363
2 Pagitsas M, Sazou D, Karantonis A, Georgolios C. J. Electroanal. Chem., 1992, 327:93
3 Wang C, Chen S, Yu X. Electrochim. Acta, 1994, 39:577
4 许颂临,蔡加勒,周绍民.高等学校化学学报,1989, 10:557
5 王晨,陈俊明.中国腐蚀与防护学报,1994, 14:(2) 123
6 Wang C, Chen S, Yu X. J. Electrochem. Soc., 1996, 143:L283
7 Heusler K E. Z. Elektrochem., 1958, 62:582
8 Bockris J O'M, Drazic D, Despic A R. Electrochim. Acta, 1961, 4:325
9 Sato N, Okamoto G. In: Bockris J O'M, Conway B E, Yeager E, White R E ed. Comprehensive Treaties of Electrochemistry, Vol. 4, New York: Plenum Press, 1981, Ch. 4

[1]	WEI Xiaoyang,MORADI Masoumeh,YANG Lijing,LV Zhanpeng,ZHENG Bizhang,SONG Zhenlun. Influence of Magnetic Field on Corrosion of Pure Cu in Artificial Seawater with Multispecies Aerobic Bacteria[J]. 中国腐蚀与防护学报, 2019, 39(6): 484-494.
[2]	Guofu OU, Lulu ZHAO, Kai WANG, Kuanxin WANG, Haozhe JIN. Dew-Point Corrosion Behavior of 10^# Carbon Steel inHCl-H₂O Environment[J]. 中国腐蚀与防护学报, 2018, 38(1): 33-38.
[3]	Kangnan ZHANG,Ming WU,Fei XIE,Dan WANG,Yuxi SAN,Feng JIANG. Effect of Magnetic Field on Corrosion of X80 Pipeline Steel in Meadow Soil at Shenyang Area[J]. 中国腐蚀与防护学报, 2017, 37(2): 148-154.
[4]	Mingming ZHANG,Li XIN,Xueyong DING,Shujiang GENG,Shenglong ZHU,Fuhui WANG. Corrosion Resistance of Alternately Multilayered Coating Ti/TiAlN on Ti-alloy Ti-6Al-4V Beneath a Solid NaCl Film in Atmosphere of Water Vapor and Oxygen at 600 ℃[J]. 中国腐蚀与防护学报, 2017, 37(1): 29-35.
[5]	Yalin LV,Bijuan ZHENG,Hongwei LIU,Fuping XIONG,Hongfang LIU,Yulong HU. Effect of Static Magnetic Field on Adhesion of Sulfate Reducing Bacteria Biofilms on 304 Stainless Steel[J]. 中国腐蚀与防护学报, 2016, 36(6): 652-658.
[6]	Yanan NIE,Hao SHEN,Kunpeng GU,Chengqi WANG. Seawater Corrosion Resistance and Service Life Prediction of Glass Fiber Reinforced Plastic Composites[J]. 中国腐蚀与防护学报, 2016, 36(4): 357-362.
[7]	Qingqing SUN,Wenhui ZHOU,Yuehuang XIE,Pengxuan DONG,Kanghua CHEN,Qiyuan CHEN. Effect of Trace Chloride and Temperature on Electrochemical Corrosion Behavior of 7150-T76 Al Alloy[J]. 中国腐蚀与防护学报, 2016, 36(2): 121-129.
[8]	CHEN Bi, ZHENG Bijuan, ZHANG Fan, LIU Hongfang. Corrosion Behavior of HSn70-1 Copper Alloy in SRB Containing Medium in Atatic Magnetic Field[J]. 中国腐蚀与防护学报, 2014, 34(4): 339-345.
[9]	LI Kejuan,ZHENG Bijuan,CHEN Bi,LIU Hongfang. Effect of Magnetic Field on Microbiologically-influenced Corrosion Behavior of Q235 Steel[J]. 中国腐蚀与防护学报, 2013, 33(6): 463-469.
[10]	WANG Lihua, CHENG Congqian, YANG Fen, ZHAO Jie. LEACHING BEHAVIOR OF LEAD-FREE SOLDERS IN A NaCl-Na₂SO₄-Na₂CO₃ MIXED SOLUTION AS SIMULATED SOIL[J]. 中国腐蚀与防护学报, 2011, 31(5): 381-384.
[11]	LI Jian ZHANG Tao MENG Guozhe SHAO Yawei WANG Fuhui. STOCHASTIC ANALYSIS OF THE MAGNETIC FIELD INFLUENCE ON THE PITTING MECHANISM OF PURE MAGNESIUM[J]. 中国腐蚀与防护学报, 2009, 29(6): 405-410.
[12]	WANG Xiaohua YANG Zhanhong LI Wangxing CHEN Jianhua WANG Shengwei LI Jingwei. EFFECT OF TMA ON STRUCTURE AND CORROSION RESISTANCE OF ALUMINUM COATINGS FROM MOLTEN SALT[J]. 中国腐蚀与防护学报, 2009, 29(5): 360-364.
[13]	. INHIBITIVE EFFECT OF TG500 IN THE SOLUTIONWITH HIGH CONTENT CO2 AND Cl-[J]. 中国腐蚀与防护学报, 2007, 27(1): 23-26 .
[14]	Lixia Yang; Xiaogang Li; Hongda Deng; Sanping Zhang; An Lin. Diffusing Behavior of Water and Chloride Ion Through Acrylic Polyurethane Coating[J]. 中国腐蚀与防护学报, 2006, 26(1): 6-10 .
[15]	;. EROSION RESISTANCE OF HA177-2A IN COMPARISON WITH HSn70-1A[J]. 中国腐蚀与防护学报, 2005, 25(3): 179-182 .

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed