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Journal of Chinese Society for Corrosion and protection  2023, Vol. 43 Issue (1): 186-190    DOI: 10.11902/1005.4537.2022.042
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Corrosion Resistance of Q690 High Strength Steel in Simulated Corrosive Environment of Ocean Splash Zone
WEI Huanhuan1,2(), ZHENG Dongdong2, CHEN Chen2,3(), ZHANG Dawei2, WANG Kaili4
1.School of Architectural Engineering, Yangling Vocational & Technical College, Xianyang 712100, China
2.State Key Laboratory of Eco-hydraulics in Northwest Arid Region, Xi'an University of Technology, Xi'an 710048, China
3.School of Civil Engineering, Xi'an University of Architecture and Technology, Xi'an 710054, China
4.China Railway the First Survey and Design Institute Group Co. Ltd., Xi'an 710043, China
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Abstract  

The surface of steel structural components exposed to extremely harsh environments is prone to rust, as a result, their normal service life is reduced, whilst the durability problem is increasingly prominent. Thus, the corrosion behavior and characteristics of surface morphology of Q690 high strength steel was assessed via alternative cyclic tests: immersion in artificial sea water, drying by indoor ventilation air and drying in atmosphere of 95% (±3%) relative humidity at 35 ℃, aiming to simulate the corrosive environment of ocean splash zone. Then, the variation of surface morphology with the progress of corrosion process and the corresponding surface coordinate parameters were collected by laser confocal microscope (LSCM). The results show that in the initial stage of corrosion, a small number of needle-like pits occurred on the surface, and the metallic luster was gradually lost. With the progress of corrosion process, the initial needle-like pits gradually developed toward large pits. At the later stage of corrosion, there exist a large number of lamellar corrosion products, and on which, exfoliations in some local areas could be observed. In addition, according to the microscopic scanning analysis, it could be seen that the cumulated corrosion products exhibited a good protective effect on the steel substrate, the corrosion process rapidly extended to the periphery and finally corrosion products completely covered the whole surface of steel specimen. When the corrosion period was 100 d, the volume loss rate and surface corrosion height were 1.38% and 840 μm, respectively.

Key words:  high strength steel      splash zone      damp-heat cycle      micro morphology      corrosion damage      volume loss rate     
Received:  17 February 2022      32134.14.1005.4537.2022.042
ZTFLH:  TG174  
Fund: National Natural Science Foundation of China(51978571);Yangling Vocational and Technical College 2021 Natural Science Foundation(ZK21-28);Research Project of the State Key Laboratory of Eco-hydraulics in Northwest Arid Region of China(2017ZZKT-8)

Cite this article: 

WEI Huanhuan, ZHENG Dongdong, CHEN Chen, ZHANG Dawei, WANG Kaili. Corrosion Resistance of Q690 High Strength Steel in Simulated Corrosive Environment of Ocean Splash Zone. Journal of Chinese Society for Corrosion and protection, 2023, 43(1): 186-190.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2022.042     OR     https://www.jcscp.org/EN/Y2023/V43/I1/186

Fig.1  Macromorphology after different corrosion periods: (a) CT0, (b) CT20, (c) CT40, (d) CT60, (e) CT80, (f) CT100
Fig.2  Scanning micro-topography after different corrosion periods (a) CT20; (b) CT40; (c) CT60; (d) CT80; (e) CT100
Specimen codeCorrosion time / dS / mm2S0 / mm2V / mm3ηv / %
CT2020125.75149.905.190.26
CT4040235.45262.9010.040.49
CT6060300.70331.2519.981.00
CT8080323.80340.0022.361.12
CT100100366.60407.5527.561.38
Table 1  Corrosion parameter statistics of scanning area
Specimen codeCorrosion time / dηs%dμmwμmd / wζmm·a-1
CT20201.23127.1471227.6950.0532.320
CT40403.03161.9253516.2980.0511.478
CT60604.05154.6535636.5030.0390.941
CT80806.18173.3148472.8560.0220.791
CT1001007.21214.6789494.5830.0230.784
Table 2  Statistics of pit size in scanning area
Fig.3  Fitting relationship between corrosion area and corrosion time
Fig.4  Relationship between pit size and corrosion time (a) d-t relationship; (b) w-t relationship; (c) d/w-t relationship
Fig.5  t-ηv-ηs relationship surface of Q690 steel
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