EFFECTS OF LOW CATHODIC POTENTIAL ON ELECTRODEPOSITED SILANE FILMS ON ALUMINUM ALLOY

J Chin Soc Corr Pro

2009, Vol. 29

Issue (3): 220-224 DOI:

技术报告

Current Issue | Archive | Adv Search

EFFECTS OF LOW CATHODIC POTENTIAL ON ELECTRODEPOSITED SILANE FILMS ON ALUMINUM ALLOY

XU Yibing; HE Deliang; ZHOU Zhou; ZHONG Jianfang; XU Chao; CUI Zhengdan; ZENG Liping

College of Chemistry and Chemical Engineering; Hunan University; Changsha 410082

Download:

PDF(1219KB)
Export: BibTeX | EndNote (RIS)

Abstract

Bis-1,2-[triethoxysilylpropyl]tetrasulfide (BTSPS) films have been successfully deposited at low cathodic potential in silane solution modified by surfactant, and a new critical cathodic potential (NCCP) (-1.6 V) has been found. The study indicated the surface morphology of silane films prepared at low cathodic potential were more compact and thicker than those prepared at conventional critical cathodic potential (-0.8 V),and BTSPS films prepared at low cathodic potentials in modified silane solution exhibited obviously higher corrosion resistances in comparison with silane films prepared by conventional electrodeposition method. Hydrogen evolution could be decreased as well as the electrodeposition of silane could be improved while adding the surfactant. Anti-corrosion of films is better as well as a negative shift of the critical cathodic potential.

Key words: aluminum silane film low cathodic potential surfactant bis-1,2-[triethoxysilylpropyl]tetrasulfide

Received: 11 September 2007

ZTFLH:

TG178

Corresponding Authors: HE Deliang E-mail: delianghe@163.com

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	HE De-Liang
	XU Si-Bing
	ZHOU Zhou
	ZHONG Jian-Fang
	XU Tiao
	CUI Zheng-Dan

Cite this article:

XU Yibing HE Deliang ZHOU Zhou ZHONG Jianfang XU Chao CUI Zhengdan ZENG Li. EFFECTS OF LOW CATHODIC POTENTIAL ON ELECTRODEPOSITED SILANE FILMS ON ALUMINUM ALLOY. J Chin Soc Corr Pro, 2009, 29(3): 220-224.

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2009/V29/I3/220

[1] Subramanian V, Van Ooij W J. Effect of amine functional group on corrosion rate of iron coated with films of organofunctional silanes[J]. Corrosion, 1998, 54(3): 204-215
[2] Zhu D, Van Ooij W J. Enhanced corrosion resistance of AA 2024-T3 and hot-dip galvanized steel using a mixture of bis-[triethoxysilylpropyl]tetrasulfide and bis-[trimethoxysilylpropyl]-amine[J]. Electrochim.Acta, 2004, 49: 1113-1125
[3] Woo H, Reucroft P J, Jacob R J.Electrodeposition of organofunctional silanes and its influence on structural adhesive bonding[J]. J. Adhes. Sci.Technol., 1993, 7(7): 681-697
[4] Zhu D, Van Ooij W J. Corrosion protection of metals by water-based silane mixtures of bis-[trimethoxysilylpropyl] amine and vinyltriacetoxysilane[J]. Prog. Org. Coat., 2004, 49: 42-53
[5] Montemor M F, Cabral A M, Zheludkevich M L, et al. The corrosion resistance of hot dip galvanized steel pretreated with bis-functional silanes modified with microsilica[J]. Surf. Coat. Technol., 2006, 200: 2875-2885
[6] Palanivel V, Huang Y, Van Ooij W J. Effects of addition of corrosion inhibitors to silane films on the performance of AA2024-T3 in a 0.5M NaCl solution[J]. Prog. Org. Coat., 2005, 53: 153-168
[7] Shacham R, Avnir D, Mandler D. Electrodeposition of methylated sol-gel films on conducting surfaces[J]. Adv. Mater., 1999, 11: 384-388
[8] Sheffer M, Groysman A, Mandler D. Electrodeposition of sol-gel films on Al for corrosion protection[J]. Corros. Sci., 2003, 45: 2893-2904
[9] Gandhi J S, Van Ooij W J. Improved corrosion protection of aluminum alloys by electrodeposited silanes[J]. J. Mater. Eng.Perform, 2004, 13(4): 475-480
[10] Hu J M , Liu L , Zhang J Q, et al.Electrodeposition of silane films on aluminum alloys for corrosion protection[J]. Prog. Org. Coat., 2007, 58: 265-271
[11] Hu J M, Liu L, Zhang J Q, et al. Effects of electrodeposition potential on the corrosion properties of bis-1, 2-[triethoxysilyl]ethane films on aluminum alloy[J]. Electrochim. Acta, 2006, 51: 3944-3949

[1]	ZHENG Li, WANG Meiting, YU Baoyi. Research Progress of Cold Spraying Coating Technology for Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 22-28.
[2]	HU Lulu, ZHAO Xuyang, LIU Pan, WU Fangfang, ZHANG Jianqing, LENG Wenhua, CAO Fahe. Effect of AC Electric Field and Thickness of Electrolyte Film on Corrosion Behavior of A6082-T6 Al Alloy[J]. 中国腐蚀与防护学报, 2020, 40(4): 342-350.
[3]	CAO Jingyi, FANG Zhigang, CHEN Jinhui, CHEN Zhixiong, YIN Wenchang, YANG Yange, ZHANG Wei. Preparation and Properties of Micro-arc Oxide Film with Single Dense Layer on Surface of 5083 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[4]	WANG Yingjun, LIU Honglei, WANG Guojun, DONG Kaihui, SONG Yingwei, NI Dingrui. Investigation of Anodic Film on a Novel RE-containing Al-Alloy Al-Zn-Mg-Cu-Sc[J]. 中国腐蚀与防护学报, 2020, 40(2): 131-138.
[5]	REN Jianping,SONG Renguo. Effect of Two-stage Ageing on Mechanical Properties and Sensitivity to Hydrogen Embrittlement of 7050 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2019, 39(4): 359-366.
[6]	Gaohong CHEN,Yuansen HU,Mei YU,Jianhua LIU,Guoai LI. Effect of Sulfuric Acid Anodizing on Mechanical Properties of 2E12 Al-alloy[J]. 中国腐蚀与防护学报, 2018, 38(6): 579-586.
[7]	Zheng LIU, Haiying LI, Hao WANG, Yong ZHAO, Siwei XIE, Shufen ZHANG. Molecular Dynamics Simulation of Adsorption Behavior of Schiff Base Surfactants on Zn Surface in Aqueous Solution[J]. 中国腐蚀与防护学报, 2018, 38(4): 381-390.
[8]	Chao SUN, Xiao YANG, Yuhua WEN. Effect of High-Al Austenitic Stainless Alloy Coatings Prepared by Magnetron Sputtering on High Temperature Oxidation Resistance of 316 Stainless Steel[J]. 中国腐蚀与防护学报, 2017, 37(6): 590-596.
[9]	Weihang ZHAO, Haowei WANG, Guangyi CAI, Zehua DONG. Localized Corrosion and Corrosion Inhibitor of Al-alloy AA6061 Beneath Electrolyte Layers[J]. 中国腐蚀与防护学报, 2017, 37(4): 366-374.
[10]	Herong ZHOU,Bihua HU,Wang YAO,Xinpei HONG,Shupeng SONG. Atmospheric Corrosion of Anodized Pure Al 1060, Al-alloys 2A12 and 7A04 Exposed to Polluted Atmospheric Environment at Jiangjin Region[J]. 中国腐蚀与防护学报, 2017, 37(3): 273-278.
[11]	Yun DAI,Shengdan LIU,Yunlai DENG,Xinming ZHANG. Pitting Corrosion of 7020 Aluminum Alloy in 3.5%NaCl Solution[J]. 中国腐蚀与防护学报, 2017, 37(3): 279-286.
[12]	Fengxuan SONG,Qizhong ZHAO,Feilong LI,Yuelu REN,Kui HUANG,Xinming ZHANG. Effect of Aging Treatment on Corrosion Rate of 7050 Al-alloy Plate[J]. 中国腐蚀与防护学报, 2017, 37(3): 287-292.
[13]	Shuangqing SUN,Qifei ZHENG,Chunling LI,Xiumin WANG,Songqing HU. Effect of Corrosion Products on Long-term Atmospheric Corrosion of Pure Aluminum 8A06[J]. 中国腐蚀与防护学报, 2017, 37(2): 110-116.
[14]	Ziheng BAI,Yunhua HUANG,Xiaogang LI,Lang YANG,Chaofang DONG,Lidan YAN,Kui XIAO. Environmental Corrosion in Industrial-marine Atmosphere at Qingdao of 7050 Al-alloy Anodized in Boric- and Sulfuric-acid Electrolyte[J]. 中国腐蚀与防护学报, 2016, 36(6): 580-586.
[15]	Jingling MA,Fengzhang REN,Guangxin WANG,Yi XIONG,Jiuba WEN. Electrochemical Performance of Al-Mg-Sn-Ga Aluminum Anode Alloy[J]. 中国腐蚀与防护学报, 2016, 36(5): 421-426.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed