Please wait a minute...
J Chin Soc Corr Pro  2008, Vol. 28 Issue (6期): 341-344    DOI:
研究报告 Current Issue | Archive | Adv Search |
SEMICONDUCTING BEHAVIOR OF 304 STAINLESS STEEL IN ELECTROLYTE SOLUTION
ZHONG Qingdong1;2;WANG Chao1;LU Xionggang1;M.Rohwerder3;ZHOU Guozhi1
1.School of Materials Science and Engineering; Shanghai University; Shanghai 200072
2.Department of Environmental Engineering; Shanghai University of Electric Power; Shanghai 200090
3.Max-Planck-Institut für Eisenforschung; Düsseldorf; 40237 Germany
Download:  PDF(775KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The semiconducting behavior of 304 stainless steel in acid and base solution was studied by utilizing potential-capacitance and Mott-Schottky analysis. It was pointed out that conducting behaviour of 304 stainless steel in different solution was different. The stainless steel showed double layer of space charge layer in 5‰ sulfuric acid, below 0 VSCE, the steel electrode showed p-type semiconducting behaviour, above 0 VSCE, the steel electrode showed n-type semiconducting behaviour. However, in 5% sodium hydroxide, the electrode showed p-type semiconducting behaviour.With increasing immersion time, the density of charge carriers in different solution changed slightly.

Key words:  304 stainless steel      conducting mechanism      p-type semiconductor      n-type semiconductor     
Received:  05 February 2007     
ZTFLH: 

TG174.48

 
Corresponding Authors:  ZHONG Qingdong   

Cite this article: 

. SEMICONDUCTING BEHAVIOR OF 304 STAINLESS STEEL IN ELECTROLYTE SOLUTION. J Chin Soc Corr Pro, 2008, 28(6期): 341-344.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2008/V28/I6期/341

[1]Uhlig H.Passivity of metals[A].In:Frankenthal R P,Kruger J.eds.,The Corrosion Monograph Series[C].Princeton,NJ:The Electrochemistry Society,1978,1
[2]Schmuki P,Bohni H.Metastable pitting and semiconductive prop-erties of passive films[J].J.Electrochem.Soc.,1992,139(7):1908-1913
[3]Simoes A M P,Ferreira M G S,Rondot B,et al.Study of passive films formed on AISI304stainless steel by impedance measure-ments and photoelectrochemistry[J].J.Electrochem.Soc.,1990,137(1):82-87
[4]Paola A D,Shukla D,Stimming U.Photoelectrochemical study of passive on stainless steel in neutral solutions[J].Electrochim.Acta,1991,36(2):345-352
[5]Paola A D.Semiconducting properties of passive films on stainless steels[J].Electrochim.Acta,1989,34(2):203-210
[6]Burleigh T D,Latanision R M.The use of photocurrents to char-acterize anodic films on Ti,Zr,Cu,and304stainless steel[J].J.Electrochem.Soc.,1987,134(1):135-141
[7]Harrison J A,Williams D E.How does the electrochemical behav-ior of stainless steel reflect that of its constituent elements?[J].Electrochim.Acta,1986,31(8):1063-1072
[8]Bartels C,Danzfuss B,Schultze J W,In:Froment M,ed.,Pas-sivity of metals and semiconductors[M].Amsterdam:Elsevier,1983
[9]Schultze J W,Elfenthal L,Leitner K,et al.Electrochemical studies of titanium dioxide films with various palladium implanta-tion profiles[J].Mater.Sci.Eng.,1987,90:253-262
[10]Leiva E,Meyer P,Schmickler W.A simulation of percolation process in electrochemical systems[J].J.Electrochem.Soc.,1988,135(12):1993-1996
[11]Leiva E,Meyer P,Schmickler W.Electron transfer through pas-sive films:role of localized electronic states[J].Corros.Sci.,1989,29(2):225-236
[12]Doblhofer K,N lte D,Ulstrup J.Polymer-film covered elec-trodes of stable electrochemical performance[J].Ber.Bunsenges.Phys.Chem.,1978,82(4):403-408
[13]AmbegaokarV,Halperin B I,Langer J S.Hopping conductivity in disordered systems[J].Phys.Rev.,1971,4B:2612-2620
[14]Lu Y C,Clayton C R.Evidence for a bipolar mechanism of pas-sivity in Mo bearing stainless steels[J].J.Electrochem.Soc.,1985,132(10):2517-2518
[15]Zhong Q D,Zheng J,Xu N X,et al.Semi-conductive behavior during degradation of a rust preventive oil film on304stainless steel in3%NaCl solution[J].Corros.Sci.Prot.Technol.,2004,16(2):83-86(钟庆东,郑金,徐乃欣等.防锈油膜失效过程中的导电行为转变[J].腐蚀科学与防护技术,2004,16(2):83-86)
[16]Zhong Q D,Zheng J,Xu N X,et al.Semi-conductive behavior of rust preventive oil coating in5%Na2SO4solution during its degradation[J].Corros.Sci.Prot.Technol.,2004,16(5):276-279(钟庆东,郑金,徐乃欣等.防锈油膜在5%Na2SO4溶液中的半导体导电行为[J].腐蚀科学与防护技术,2004,16(5):276-279)
[17]Zhong Q D,Rohwerder M,Zhang Z,et al.semiconducting be-havior of temporarily protective oil coating on the surface of AISI304stainless steel in5%Na2SO4solution during its degradation[J].J.Electrochem.Soc.,2004,151(7):B446-B452
[18]Zhong Q D,Rohwerder M,Shi L Y.The effect of ionic penetra-tion on semiconducting behaviour of temporarily protective oil coating on the surface of AISI304stainless steel[J].Mater.Cor-ros.,2005,56(9):597-605
[19]Paola A D,Quarto F D,Sunseri C.A photoelectrochemical char-acterization of passive films on stainless steels[J].Corros.Sci.,1986,26(11):935-948
[1] ZHANG Hao, DU Nan, ZHOU Wenjie, WANG Shuaixing, ZHAO Qing. Effect of Fe3+ on Pitting Corrosion of Stainless Steel in Simulated Seawater[J]. 中国腐蚀与防护学报, 2020, 40(6): 517-522.
[2] LUO Hong,GAO Shujun,XIAO Kui,DONG Chaofang,LI Xiaogang. Effect of Magnetron Sputtering Process Parameters on CrN Films on 304 Stainless Steel and TheirCorrosion Behavior[J]. 中国腐蚀与防护学报, 2019, 39(5): 423-430.
[3] Wenshan PENG,Jian HOU,Kangkang DING,Weimin GUO,Ri QIU,Likun XU. Corrosion Behavior of 304 Stainless Steel in Deep Sea Environment[J]. 中国腐蚀与防护学报, 2019, 39(2): 145-151.
[4] Tong LIAO,Zheng MA,Leilei LI,Xiumin MA,Xiutong WANG,Baorong HOU. Light-generated Cathodic Protection Properties of Fe2O3/TiO2 Nanocomposites for 304 Stainless Steel[J]. 中国腐蚀与防护学报, 2019, 39(1): 36-42.
[5] Hui LIU,Wei QIU,Bin LENG,Guojun YU. Corrosion Behavior of 304 and 316H Stainless Steels in Molten LiF-NaF-KF[J]. 中国腐蚀与防护学报, 2019, 39(1): 51-58.
[6] Siqi ZHANG,Nan DU,Meifeng WANG,Shuaixing WANG,Qing ZHAO. Effect of Cathode Area on Stable Pitting Growth Rate of 304 Stainless Steel in 3.5%NaCl Solution[J]. 中国腐蚀与防护学报, 2018, 38(6): 551-557.
[7] Yingjun AI,Nan DU,Qing ZHAO,Shixin HUANG,Liqiang WANG,Qingjie WEN. Effect of Temperature on Initiation of Metastable Pits and Geometric Features of Stable Pits for 304 Stainless Steel[J]. 中国腐蚀与防护学报, 2017, 37(2): 135-141.
[8] Yurong FANG,Chaoyang FU. Corrosion and Corrosion Inhibition of 304 Stainless Steel in Acidic FeCl3 Solution with Applied Inhibitor K2Cr2O7 and Ultrasonic Vibration[J]. 中国腐蚀与防护学报, 2015, 35(4): 305-310.
[9] YE Chao, DU Nan, TIAN Wenming, ZHAO Qing, ZHU Li. Effect of pH on Pitting Corrosion Process of 304 Stainless Steel in 3.5%NaCl Solution[J]. 中国腐蚀与防护学报, 2015, 35(1): 38-42.
[10] XU Hongmei, LIU Wei, CAO Lixin, SU Ge, GAO Rongjie. Preparation of ZnO/TiO2 Composite Film on 304 Stainless Steel and Its Photo-cathodic Protection Properties[J]. 中国腐蚀与防护学报, 2014, 34(6): 507-514.
[11] TIAN Wenming, DU Nan, ZHAO Qing. ELECTRONIC SPECKLE PATTERN INTERFEROMETRY MEASUREMENT OF 304 STAINLESS STEEL PITTING POTENTIAL[J]. 中国腐蚀与防护学报, 2012, 32(5): 431-436.
[12] LI Ji, ZHAO Lin, LI Bowen,ZHENG Liqun, HAN En-Hou. ELECTROCHEMICAL NOISE ANALYSIS OF 304 STAINLESS STEEL PITTING CORROSION IN FERRIC CHLORIDE SOLUTION[J]. 中国腐蚀与防护学报, 2012, 32(3): 235-240.
[13] WANG Hongfen, WANG Zhiqi, HONG Haixia, CHEN Shougang,YIN Yansheng. CORROSION RESISTANCE BEHAVIOR OF CERIUM-DOPED TiO2 FILM IN THE PRESENCE OF MARINE BACTERIUM SULFATE-REDUCING BACTERIA[J]. 中国腐蚀与防护学报, 2010, 30(6): 481-486.
[14] HUANG Wenjing; HUANG Hualiang; QIU Yubing; CHEN Zhenyu; GUO Xingpeng. EFFECT OF SIZE ON CORROSION BEHAVIOR OF MICRO-ELECTRODES[J]. 中国腐蚀与防护学报, 2010, 30(2): 141-144.
[15] . CORROSION BEHAVIOR OF NANOCRYSTALLIZED BULK 304 STAINLESS STEELI. THE RESEARCH ON ANTI-CHLORIDE ION ATTACK OF THE PASSIVE FILM[J]. 中国腐蚀与防护学报, 2007, 27(2): 80-83 .
No Suggested Reading articles found!