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ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY OF Al ALLOYS DURING EXFOLIATION CORROSION |
Jinfeng Li;Ziqiao Zheng;Zhao Zhang;Jianqing Zhang |
中南大学材料科学与工程学院 |
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Abstract The exfoliation development of 8090 Al - Li alloy and 7050 Al alloy was studied.The electrochemical impedance spectroscopy(EIS) of these alloys in EXCO solution was measured and simulated .At the beginning of immersion, the EIS is comprised by a capacitive arc at high - mediate frequency and an inductive arc at mediate - low frequency. Once exfoliation occurs, two capacitive arcs appear at high - mediate frequency and mediate - low frequency respectively.Some information about exfoliation, such as exfoliation development rate and exfoliation morphology, can be obtained through the simulated EIS data.
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Received: 07 July 2003
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Corresponding Authors:
Jinfeng Li
E-mail: jfli2000@163.net
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