|
|
FEATURES OF ECN OF LOCALIZED CORROSION FOR 16Mn STEEL |
Zehua Dong;Xingpeng Guo;Jiashen Zheng |
武汉华中科技大学化学系 |
|
|
Abstract The change of electrochemical noise(ECN)patterns wi th time of 16Mn steel in 0.1 mol/L Cl-+0.5 mol/L NaHCO3 solution was inv es tigated.The experimental result showed,during metastable pit initiation period,t he pitting initiation rate λ was less than 0.002 s-1,and the average life time of current transient coupled in ECN was about 3~5 s.However,the average li fetime of potential transient was 200 s.During the transition from metastable to stable pitting,λ increased rapidly,with an increase of the lifetime of current transient and a decrease of potential transient.Then,during the stable developm ent of pitting corrosion,the lifetime of current and potential transient become almost identical,and a large-scaled fluctuation in ECN as well as a decrease of λ was observed.In addition,during the transition from metastable to stable pitt ing,noise resistance Rn decreased fast,and Rn get stable once the st abilization of pitting corrosion.
|
Received: 05 March 2001
|
|
Corresponding Authors:
Zehua Dong
|
[1]HashimotoM ,MiyajimaS ,MurataT .Anexperimentalstudyofpotentialfluctuationduringpassivefilmbreakdownandrepaironiron[J].Corros.Sci.,1992,33(6):905 [2]CaoChu′nan,ChangXiaoyuan,LinHaicao.Featuresofelectrochemicalnoisesduringpittingcorrosion[J].JChineseSocietyforCorrosionandProtection,1989,9(1):21-27(曹楚南,常晓元,林海潮.孔蚀过程中的电化学噪声特征[J].中国腐蚀与防护学报,1989,9(1):21-27) [3]UruchurtuJC ,DawsonJL .Noiseanalysisofpurealuminumunderdiffer entpittingconditions[J].Corrosion,1987,43(1):19-26 [4]BertocciU ,FrydmanJ,GabrielliC ,HuetF ,KeddamM .Analysisofelec trochemicalnoisebypowerspectraldensityappliedtocorrosionstudies[J].J.Electrochem.Soc.,1998,145(8):2780-2785 [5]EdenDA .Electrochemicalnoise-thefirsttwooctaves[A].Corrosion98,NACE[C].1998,386. [6]BertocciU ,GabrielliC ,HuetF .Noiseresistanceappliedtocorrosionmeasurements.I.theoreticalanalysis[J].JofElectrochem.Soc.,1997,144(1):31-37. [7]MansfeldF ,SunZ ,HsuCH ,NagiubA .Concerningtrendremovalinelectrochemicalnoisemeasurements[J].Corros.Sci.,2001,43(3):341-352 [8]ChengYF ,WilmottM ,LuoJL .Analysisoftheroleofelectrodecapaci tanceontheinitiationofpitsforA516carbonsteelbyelectrochemicalnoisemeasurements[J].Corros.Sci.,1999,41(6):1245-1256 [9]ChengYF ,WilmottM ,LuoJL .Theroleofchlorideionsinpittingofcarbonsteelstudiedbythestatisticalanalysisofelectrochemicalnoise[J].AppliedSurfaceSci.,1999.152(1):161-168 |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|