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Journal of Chinese Society for Corrosion and protection  2015, Vol. 35 Issue (3): 251-256    DOI: 10.11902/1005.4537.2014.033
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Simulation of Carbon Steel Corrosion in Oil-gas Field Produced Waters Containing Hydrogen Sulfide
Fengping WANG(),Lan LIU,Yanwei DING,Suijun HU,Zhaobin LIU,Dan LIU,Li ZHANG
Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China
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Abstract  

In order to simulate the carbon steel corrosion in oil-gas field produced water containing H2S, a proper artificial water was poured into an autoclave and then into which H2S gas was introduced respectively in two different ways: directly inducing H2S from a pressed H2S gas cylinder and generating H2S gas in-situ during the corrosion process through chemical reaction of desired reagents pre-set in the water. The corrosion rates of 20# steel were comparatively studied for two different ways of introducing H2S gas, while the other parameters kept the same, by weight loss technique, electrochemical measurement and scanning electron microscopy with energy dispersive spectrometer. It has been found that the 20# steel in the water with in-situ generating H2S exhibits a corrosion rate 0.1077 mm/a and a coarse and porous corrosion product film. Whereas, those by inducing H2S from gas cylinder are a corrosion rate 0.0518 mm/a and a uniform and compact corrosion product film respectively. It is also noted that the results of the former one are better accorded with those observed in oil/gas fields practice. Therefore, the way of directly inducing H2S from gas cylinder into the waters should be suitable to simulate the relevant corrosion performance of metallic materials in oil-gas field produced waters.

Key words:  oil/gas field      H2S corrosion      experimental method      20# steel     

Cite this article: 

Fengping WANG,Lan LIU,Yanwei DING,Suijun HU,Zhaobin LIU,Dan LIU,Li ZHANG. Simulation of Carbon Steel Corrosion in Oil-gas Field Produced Waters Containing Hydrogen Sulfide. Journal of Chinese Society for Corrosion and protection, 2015, 35(3): 251-256.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2014.033     OR     https://www.jcscp.org/EN/Y2015/V35/I3/251

Fig.1  Schematic of reactor system for testing corrosion rate of 20# steel by potentiodynamic technique
Introducing method of H2S νcorr / mma-1 Concentration of inhibitor / mgL-1 pH
Direct method (compressed gas) 0.0518 0 6.0
0.0400 150
Indirect method (reaction of Na2S and HAc) 0.1077 0 5.5
0.0695 150
Table 1  Corrosion rate of 20# steel in oilfield media containing H2S introduced by two different methods (PTotal=3 MPa, T=60 ℃)
Fig.2  Polarization curves of 20# steel in oilfield media containing H2S without (a) and with (b) inhibitor at 60 ℃
Introducing method of H2S OCP V (Ag-AgCl) Inhibitor mgL-1 Corrosion rate mAcm-2 Tafel slope-bc mVdec-1
Direct method (compressed gas) -0.59 0 4.2×10-2 800
-0.60 150 1.9×10-2 853
Indirect method (reaction of Na2S and HAc) -0.59 0 6.2×10-2 685
-0.61 150 2.8×10-2 805
Table 2  Electrochemical parameters of 20# steel in oilfield media containing H2S introduced by two different methods (PTotal=3 MPa, T=60 ℃)
Fig.3  SEM surface images of 20# steel after corrosion in simulated solutions containing H2S induced directly (a) and indirectly (b)
Fig.4  EDS results of corrosion products of 20# steel after corrosion in simulated solutions containing H2S induced directly (a) and indirectly (b)
Element Direct method Indirect method
Mass fraction / % Atomic fraction / % Mass fraction / % Atomic fraction / %
Fe K 71.74 57.16 89.35 75.25
S K 24.68 34.25 2.47 3.62
O K 2.68 7.46 6.37 18.73
Cl K 0.89 1.12 1.82 2.41
Total 100.00 100.00
Table 3  Element compositions of corrosion products of 20# steel after corrosion in simulated solutions containing H2S induced by two different methods
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