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Simulation of Carbon Steel Corrosion in Oil-gas Field Produced Waters Containing Hydrogen Sulfide |
Fengping WANG( ),Lan LIU,Yanwei DING,Suijun HU,Zhaobin LIU,Dan LIU,Li ZHANG |
Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, China |
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Abstract In order to simulate the carbon steel corrosion in oil-gas field produced water containing H2S, a proper artificial water was poured into an autoclave and then into which H2S gas was introduced respectively in two different ways: directly inducing H2S from a pressed H2S gas cylinder and generating H2S gas in-situ during the corrosion process through chemical reaction of desired reagents pre-set in the water. The corrosion rates of 20# steel were comparatively studied for two different ways of introducing H2S gas, while the other parameters kept the same, by weight loss technique, electrochemical measurement and scanning electron microscopy with energy dispersive spectrometer. It has been found that the 20# steel in the water with in-situ generating H2S exhibits a corrosion rate 0.1077 mm/a and a coarse and porous corrosion product film. Whereas, those by inducing H2S from gas cylinder are a corrosion rate 0.0518 mm/a and a uniform and compact corrosion product film respectively. It is also noted that the results of the former one are better accorded with those observed in oil/gas fields practice. Therefore, the way of directly inducing H2S from gas cylinder into the waters should be suitable to simulate the relevant corrosion performance of metallic materials in oil-gas field produced waters.
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