压水堆二回路碱化剂与材料的相容性研究进展

doi:10.11902/1005.4537.2023.090

中国腐蚀与防护学报

2024, Vol. 44

Issue (2): 267-277 CSTR: 32134.14.1005.4537.2023.090 DOI: 10.11902/1005.4537.2023.090

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压水堆二回路碱化剂与材料的相容性研究进展

冀跃飞¹^,², 郝龙¹^,²(

), 王俭秋¹^,²^,³, 李庆华⁴, 郑跃⁴, 于沛⁴, 柯伟¹^,³

^1.中国科学院金属研究所中国科学院核用材料与安全评价重点实验室沈阳 110016
^2.中国科学技术大学材料科学与工程学院沈阳 110016
^3.广东腐蚀科学与技术创新研究院广州 510700
^4.中国核电工程有限公司北京 100083

Research Progress on Compatibility Between Alkalizing Agents and Materials in PWR Secondary Circuit

JI Yuefei¹^,², HAO Long¹^,²(

), WANG Jianqiu¹^,²^,³, LI Qinghua⁴, ZHENG Yue⁴, YU Pei⁴, KE Wei¹^,³

^1.Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^2.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
^3.Institute of Corrosion Science and Technology, Guangzhou 510700, China
^4.China Nuclear Power Engineering Co., Ltd., Beijing 100083, China

引用本文:

冀跃飞, 郝龙, 王俭秋, 李庆华, 郑跃, 于沛, 柯伟. 压水堆二回路碱化剂与材料的相容性研究进展[J]. 中国腐蚀与防护学报, 2024, 44(2): 267-277.
Yuefei JI, Long HAO, Jianqiu WANG, Qinghua LI, Yue ZHENG, Pei YU, Wei KE. Research Progress on Compatibility Between Alkalizing Agents and Materials in PWR Secondary Circuit[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(2): 267-277.

全文: PDF(3835 KB) HTML

摘要:

综述了国内外压水堆二回路碱化剂的应用情况及其与二回路结构材料相容性的研究进展。首先介绍了碱化剂的国内外发展历程；其次，从材料类型、水化学、碱化剂物理化学性质等3个角度讨论了碱化剂与材料的相容性；最后，论述了碱化剂调节pH的原理，并详细介绍了有机胺分子与材料表面氧化膜间的作用机制。

关键词 ：二回路, 碱化剂, 水化学, 乙醇胺, 结构材料

Abstract：

Impurities such as pipeline corrosion products and dissolved oxygen etc. in the secondary circuit of pressurized water reactor (PWR) can enter the steam generator through the water supply system and deposit at different positions, resulting in the decrease of heat transfer capacity and the instability of thermal and hydraulic system. The water chemistry control in secondary circuit of PWR is of great significance for a safe operation of system equipment and core components. The purpose of this work is to summarize the application of pH control agents at home and abroad, and the research progress in the compatibility between employed alkalizing agents and structural materials. Firstly, the development process in alkalizing agent for PWR secondary circuit and its application at home and abroad are detailed. Secondly, the factors influencing the compatibility between the employed alkalizing agents and structural materials are discussed from three aspects: structural materials, hydrochemistry and the physicochemical properties of alkalizing agents. Finally, the working mechanism of alkalizing agent in adjusting pH is discussed, especially the mechanism of interactions between amine molecules and the oxide scales formed on the surface of structural materials.

Key words： secondary circuit alkalizing agent water chemistry ethanolamine structural material

收稿日期: 2023-03-27 32134.14.1005.4537.2023.090

ZTFLH:

TG174

基金资助:中核集团领创科研项目

通讯作者: 郝龙，E-mail：lhao@imr.ac.cn, chinahaolong@126.com，研究方向为高温水化学控制用添加剂与安全评估

Corresponding author: HAO Long, E-mail: lhao@imr.ac.cn, chinahaolong@126.com

作者简介: 冀跃飞，男，1997年生，博士生

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图1 压水堆核电站二回路水化学演变示意图

图2 秦山核电厂在不同水化学控制下二回路各系统的pH[27]

表1 压水堆核电站二回路中采用的典型金属结构材料及其成分组成

图3 蒸汽发生器管板支撑(TSP)缝隙内杂质示意图[3]

图4 300℃时Fe、Ni、Cr氧化物溶解度与pH的关系示意图[3]

图5 260℃时Fe-H2O、Cr-H2O、Ni-H2O体系的电位与pH关系示意图

图6 690TT合金管上磁铁矿沉积行为[72]

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