单相和双相不锈钢纳米涂层的电化学腐蚀行为

中国腐蚀与防护学报

2008, Vol. 28

Issue (3): 129-134

研究报告

本期目录 | 过刊浏览

单相和双相不锈钢纳米涂层的电化学腐蚀行为

叶威; 李瑛; 王福会

中科院金属研究所

Electrochemical corrosion behavior of nano-crystalline stainless steel coating with different phase composition

中科院金属研究所

全文: PDF(1415 KB)

摘要: 用磁控溅射技术在玻璃基体上制备由两种相组成(单相和双相)的不锈钢纳米涂层,利用动电位极化､交流阻抗技术及扫描电子显微镜研究两种不锈钢纳米涂层在0.25 mol/L Na2SO4 + 0.05 mol/L H2SO4 和 0.5 mol/L NaCl + 0.05 mol/L H2SO4溶液中的电化学腐蚀行为,观察相组成对纳米不锈钢涂层耐蚀性能的影响｡结果表明,与不锈钢单相涂层相比,不锈钢双相纳米涂层具有较差的抗局部腐蚀能力,其钝化膜的载流子密度远远大于不锈钢单相钝化膜的载流子密度,使得钝化膜的离子传输能力大大增强,从而降低了钝化膜的稳定性｡

关键词 ：纳米涂层, 相组成, 局部腐蚀, 钝化膜

Abstract：The single-phase (α) and duplex-phase (α+γ) nano-crystalline coatings have been fabricated on glass substrate by DC magnetron sputtering. The electrochemical corrosion behavior of the two NC coatings in solutions of 0.25M Na2SO4 + 0.05M H2SO4 and 0.5M NaCl + 0.05M H2SO4 was investigated by using potentiodynamic polarization, EIS and SEM. The results showed that there was a large difference in the corrosion behavior between the single-phase (α) and the duplex-phase (α+γ) nano-crystalline coatings. The duplex-phased coating is shown to have exhibited a lower localized corrosion resistance and possessed a less stable passive film than the single-phase coating. A similar two-layer semiconductor passive film was formed on both coatings; however, a great increase in carrier densities could be responsible for the low stability of the passive film on the duplex-phase coating.

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收稿日期: 2006-09-26

通讯作者: 叶威 E-mail: weiye@imr.ac.cn

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叶威; 李瑛; 王福会 . 单相和双相不锈钢纳米涂层的电化学腐蚀行为[J]. 中国腐蚀与防护学报, 2008, 28(3): 129-134 .

链接本文:

https://www.jcscp.org/CN/Y2008/V28/I3/129

[1]Inturi RB,Szklarska-Smialowska Z.Localized corrosion of nanocrys-talline 304 type stainless steel films[J].Corrosion,1992,48:398-403
[2]Ryan M P,Laycock N J,Issaacs H S,et al.Corrosion pits in thin films of stainless steel[J].J.Electrochem.Soc.,1999,146:91-97
[3]Wang X Y,Li DY.Mechanical and electrochemical behavior of nanocrystalline surface of 304 stainless steel[J].Electrochim.Acta,2002,47:3939-3947
[4]Fujimoto S,Hayashida H,Shibata T.Extremely high corrosion re-sistance of thin film stainless steels deposited by ion beam sputter-ing[J].Mater.Sci.Eng.,1999,267:314-318
[5]Liu D,Wang F,Cao C.The pitting corrosion resistance of micro-crystalline coatings of sputtered 321 stainless steel[J].Corrosion,1990,46:975-977
[6]Ye W,Li Y,Wang F.Effects of nanocrystallization on the corro-sion behavior of 309 stainless steel[J].Electrochim.Acta,2006,51:4426-4432
[7]Ningshen S,Kamachi Mudali U,Amarendra G,et al.Hydrogen effects on the passive film formation and pitting susceptibility ofnitrogen containing type 316L stainless steels[J].Corros.Sci.,2006,48:1106-1112
[8]Park C J,Kwon H S,Lohrengel M M.Micro-electrochemical po-larization study on 25%Cr duplex stainless steel[J].Mater.Sci.Eng.,2004,A372:180-185
[9]Lo I H,Fu Y,Lin C J,et al.Effect of electrolyte composition on the active-to-passive transition behavior of 2205 duplex stainlesssteel in H2SO4/HCl solutions[J].Corros.Sci.,2006,48:696-709
[10]Olsson C O A.The influence of nitrogen and molybdenum on pas-sive films formed on the austenoferritic stainless steel 2205 stud-ied by AES and XPS[J].Corros.Sci.,1995,37:467-479
[11]Sato N.Toward a more fundamental understanding corrosion pro-cesses[J].Corrosion,1989,45:354-368
[12]Cheng Y F,Luo J L.A comparison of the pitting susceptibility and semiconducting properties of the passive films on carbon steelin chromate and bicarbonate solutions[J].Appl.Surf.Sci.,2000,167:113-121
[13]Hakiki N E,Boudin S,Rondot B.The electronic structure of passive films formed on stainless steels[J].Corros.Sci.,1995,37:1809-1822

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