<strong>Mg-Gd-Y-Zr</strong>合金在模拟沿海贮存环境下的腐蚀行为与机理研究

doi:10.11902/1005.4537.2024.206

中国腐蚀与防护学报

2025, Vol. 45

Issue (3): 731-738 CSTR: 32134.14.1005.4537.2024.206 DOI: 10.11902/1005.4537.2024.206

研究报告

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Mg-Gd-Y-Zr合金在模拟沿海贮存环境下的腐蚀行为与机理研究

张超¹, 陈俊航², 邹士文¹, 张欢¹, 李曌亮¹, 肖葵²(

)

^1.航天材料及工艺研究所北京 100076
^2.北京科技大学新材料技术研究院北京 100083

Corrosion Behavior of Mg-Gd-Y-Zr Alloy in Simulated Coastal Storage Environment

ZHANG Chao¹, CHEN Junhang², ZOU Shiwen¹, ZHANG Huan¹, LI Zhaoliang¹, XIAO Kui²(

)

^1.Aerospace Research Institute of Materials & Processing Technology, Beijing 100076, China
^2.Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China

引用本文:

张超, 陈俊航, 邹士文, 张欢, 李曌亮, 肖葵. Mg-Gd-Y-Zr合金在模拟沿海贮存环境下的腐蚀行为与机理研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 731-738.
Chao ZHANG, Junhang CHEN, Shiwen ZOU, Huan ZHANG, Zhaoliang LI, Kui XIAO. Corrosion Behavior of Mg-Gd-Y-Zr Alloy in Simulated Coastal Storage Environment[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(3): 731-738.

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摘要:

针对航空航天用铸造Mg-Gd-Y-Zr合金，为了评估其在沿海贮存环境下的腐蚀行为演变规律，基于我国南部沿海城市的环境参数设计了模拟临海贮存环境的加速环境谱试验方法。通过腐蚀动力学、扫描电子显微镜、X射线衍射分析和电化学测试等技术研究了铸造Mg-Gd-Y-Zr合金在模拟临海贮存环境中的腐蚀行为。结果表明，Mg-Gd-Y-Zr合金在模拟沿海贮存环境中生成较多的腐蚀产物，锈层电阻R_f不断提高，试样的腐蚀速率呈下降趋势。XRD结果表明，腐蚀产物主要为Mg(OH)₂、MgCl₂·6H₂O、MgO、Gd₂O₃以及少量的ZrO₂。随着试验的进行，试样的腐蚀产物逐渐分为两层，外层较为疏松，内层较为致密。

关键词 ：铸造镁合金, 贮存环境, 腐蚀产物

Abstract：

In order to evaluate the corrosion behavior evolution of aerospace cast Mg-Gd-Y-Zr alloy in coastal storage environments, herein, an accelerated environmental spectrum test method was designed to simulate coastal storage environments based on environmental parameters of several typical southern coastal cities of our country. The corrosion behavior of Mg-Gd-Y-Zr alloy in the simulated coastal storage environment was studied by means of corrosion kinetics, scanning electron microscopy, X-ray diffraction analysis, and electrochemical testing. The results showed that with the progress of corrosion process, corrosion products formed on Mg-Gd-Y-Zr alloy increased gradually, and the resistance R_f of the rust layer continued to increase, while the alloy showed continually a decreasing trend in corrosion rate. The XRD results indicate that the corrosion products are composited mainly of Mg(OH)₂, MgCl₂·6H₂O, MgO, Gd₂O₃, and a small amount of ZrO₂. Correspondingly, the scale of corrosion products on the alloy was gradually divided into two layers, with the outer layer being relatively loose and the inner layer being relatively dense.

Key words： casting Mg-alloy storage environment corrosion product

收稿日期: 2024-07-09 32134.14.1005.4537.2024.206

ZTFLH:

TG172

通讯作者: 肖葵，E-mail：xiaokui@ustb.edu.cn，研究方向为金属材料大气腐蚀行为与机理研究、材料服役环境损伤机理和环境腐蚀

Corresponding author: XIAO Kui, E-mail: xiaokui@ustb.edu.cn

作者简介: 张超，男，1993年生，博士，工程师

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https://www.jcscp.org/CN/10.11902/1005.4537.2024.206 或 https://www.jcscp.org/CN/Y2025/V45/I3/731

图1 模拟沿海贮存环境的加速试验方法

图2 Mg-Gd-Y-Zr合金的微观形貌及物相组成

图3 Mg-Gd-Y-Zr合金在模拟沿海贮存环境实验后的腐蚀失重曲线

图4 Mg-Gd-Y-Zr合金在模拟沿海贮存环境实验不同时间后的表面腐蚀产物形貌

表1 表面腐蚀产物的EDS能谱 (mass fraction / %)

图5 Mg-Gd-Y-Zr合金在模拟沿海贮存环境实验后的截面锈层形貌

图6 模拟沿海贮存环境实验不同时间后腐蚀产物的XRD谱

图7 Mg-Gd-Y-Zr合金在模拟沿海贮存环境实验后的极化曲线及拟合参数

图8 Mg-Gd-Y-Zr合金在模拟沿海贮存环境实验后的电化学阻抗谱

表2 电化学阻抗谱图的拟合参数

[1]	Liu Z S, Li Y D, Zhao J W, et al. Research on aluminum alloy materials and application technology for automobile lightweight [J]. Mater. China, 2022, 41: 786
[1]	刘贞山, 李英东, 赵经纬等. 汽车轻量化用铝合金材料及应用技术的研究 [J]. 中国材料进展, 2022, 41: 786
[2]	Wu G R, Chen X H. Research on material lightweight and shape design of automobile wheel hub [J]. Mater. Rep., 2021, 35: 19181
[2]	吴国荣, 陈旭辉. 汽车轮毂材料轻量化与造型设计研究 [J]. 材料导报, 2021, 35: 19181
[3]	Huang Z F, Yong Q W, Fang R, et al. Superhydrophobic and corrosion-resistant nickel-based composite coating on magnesium alloy [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 755
[3]	黄志凤, 雍奇文, 房蕊等. AZ31镁合金表面超疏水耐腐蚀镍基复合涂层 [J]. 中国腐蚀与防护学报, 2023, 43: 755 doi: 10.11902/1005.4537.2023.143
[4]	Wang H, Liu Y Y. Research progress in the preparation of anti-corrosion superhydrophobic coatings on magnesium alloys [J]. Surf. Technol., 2023, 52(11): 1
[4]	王华, 刘艳艳. 镁合金表面防腐蚀超疏水涂层制备研究进展 [J]. 表面技术, 2023, 52(11): 1
[5]	Zhang Y, Liu W, Liu Y, et al. Research progress on microstructure and mechanical properties of medical rare-earth magnesium alloys [J]. Rare Met. Mater. Eng., 2023, 52: 3065
[6]	Gu D D, Han B J, Xu Z. Effect of rare earth La on microstructure and corrosion resistance of AZ91D magnesium alloy [J]. Corros. Prot., 2016, 37: 313
[6]	古东懂, 韩宝军, 徐洲. 稀土镧对AZ91D镁合金组织及耐蚀性的影响 [J]. 腐蚀与防护, 2016, 37: 313
[7]	Deng B, Li Q F, Wu Y Z, et al. Effect of the second phase on the corrosion behavior of Mg-Zn-Zr alloy [J]. Mater. Prot., 2021, 54(9): 48
[7]	邓彬, 李庆芬, 吴远志等. 第二相对Mg-Zn-Zr合金腐蚀行为的影响 [J]. 材料保护, 2021, 54(9): 48
[8]	Liu X F, Du W B, Fu J J, et al. Effect of Gd on microstructure and corrosion behavior of Mg-xGd-1Er-1Zn-0.6Zr alloys [J]. J. Mater. Eng., 2022, 50(9): 159
[8]	刘雄飞, 杜文博, 付军健等. Gd对Mg-xGd-1Er-1Zn-0.6Zr合金显微组织和腐蚀行为的影响 [J]. 材料工程, 2022, 50(9): 159 doi: 10.11868/j.issn.1001-4381.2020.001140
[9]	Cao F Y, Zhang J, Li K K, et al. Influence of heat treatment on corrosion behavior of hot rolled Mg5Gd alloys [J]. Trans. Nonferrous Met. Soc. China, 2021, 31: 939
[10]	Cui Z Y, Xiao K, Dong C F, et al. Long-term corrosion behavior of AZ31 magnesium alloy in Xisha marine atmosphere [J]. Chin. J. Eng., 2014, 36: 339
[10]	崔中雨, 肖葵, 董超芳等. 西沙严酷海洋大气环境下AZ31镁合金的长周期腐蚀行为 [J]. 北京科技大学学报, 2014, 36: 339
[11]	Sun S, Dai J M, Song Y W, et al. Corrosion behavior of extruded EW75 Mg-alloy in Shenyang industrial atmosphere [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 141
[11]	孙硕, 代珈铭, 宋影伟等. 挤压态EW75稀土镁合金在沈阳工业大气环境中的腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2024, 44: 141
[12]	Zhou J, Xue W, Zhou K N. Research on the impact of storage environment on missile reliability [J]. China Plant Eng., 2024, (2): 221
[12]	周军, 薛伟, 周康宁. 贮存环境对导弹可靠性影响研究 [J]. 中国设备工程, 2024, (2): 221
[13]	Yang Q X, Xuan Z L, Li T P, et al. Analysis for carrier-based aerial ammunition storage environment [J]. J. Ordnance Equip. Eng., 2021, 42(10): 137
[13]	杨清熙, 宣兆龙, 李天鹏等. 舰载航空弹药贮存环境分析 [J]. 兵器装备工程学报, 2021, 42(10): 137
[14]	Tang Y, Meng Q L, Ren P. Spatial distribution and concentrations of salt fogs in a coastal urban environment: a case study in Zhuhai city [J]. Build. Environ., 2023, 234: 110156
[15]	Li J S, Chen J H, Song J L, et al. Research on corrosion behavior of truck body steel in chlorine-containing sulfuric acid environment [J]. J. Mater. Res. Technol., 2022, 21: 1878
[16]	Song Y W, Shan D Y, Han E H. Pitting corrosion of a rare earth Mg alloy GW93 [J]. J. Mater. Sci. Technol., 2017, 33: 954 doi: 10.1016/j.jmst.2017.01.014
[17]	Cui Z Y, Li X G, Xiao K, et al. Atmospheric corrosion of field-exposed AZ31 magnesium in a tropical marine environment [J]. Corros. Sci., 2013, 76: 243
[18]	Liu M, Schmutz P, Uggowitzer P J, et al. The influence of yttrium (Y) on the corrosion of Mg-Y binary alloys [J]. Corros. Sci., 2010, 52: 3687
[19]	Liu J N, Bian D, Zheng Y F, et al. Comparative in vitro study on binary Mg-RE (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) alloy systems [J]. Acta Biomater., 2020, 102: 508 doi: S1742-7061(19)30753-6 pmid: 31722254

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