粒径和温度对20号钢冲刷腐蚀协同作用的影响

doi:10.11902/1005.4537.2020.140

中国腐蚀与防护学报

2021, Vol. 41

Issue (4): 508-516 DOI: 10.11902/1005.4537.2020.140

研究报告

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粒径和温度对20号钢冲刷腐蚀协同作用的影响

任莹¹, 赵会军¹(

), 周昊¹, 张建伟¹, 刘雯¹, 杨足膺², 王磊³

^1.江苏省油气储运技术重点实验室常州 213016
^2.常州大学商学院常州 213016
^3.西南油气田公司输气管理处成都 610000

Effect of Sand Size and Temperature on Synergistic Effect of Erosion-corrosion for 20 Steel in Simulated Oilfield Produced Fluid with Sand

REN Ying¹, ZHAO Huijun¹(

), ZHOU Hao¹, ZHANG Jianwei¹, LIU Wen¹, YANG Zuying², WANG Lei³

^1.Jiangsu Key Laboratory of Oil-Gas Storage and Transportation Technology, Changzhou 213016, China
^2.Business School Changzhou University, Changzhou 213016, China
^3.Petrochina Southwest Oil and Gas Field Company Gas Transportation Management Department, Chengdu 610000, China

全文: PDF(14226 KB) HTML

摘要:

利用旋转圆柱电极实验装置，在模拟油田采出液中，通过腐蚀失重、形貌观测和电化学分析等方法量化20号钢在不同砂粒粒径和温度下的冲刷腐蚀协同作用。结果表明，砂粒粒径增大对20号钢的冲刷磨损有明显的促进作用，这与形貌观测较符合。随砂粒粒径增大，腐蚀促进冲刷的作用和冲刷促进腐蚀的作用均先增加后减小。在砂粒粒径为40~70 μm到120~200 μm时，材料冲刷腐蚀以冲刷-电化学混合控制为主；砂粒粒径为200~300 μm时，以冲刷磨损为主导。在不同的温度下，20号钢的冲刷腐蚀均以冲刷-电化学为主要控制；温度越高，腐蚀对冲刷的促进作用越显著。

关键词 ： 20号钢, 冲刷腐蚀, 砂粒粒径, 温度, 协同作用

Abstract：

The erosion-corrosion behavior of 20 steel in simulated oilfield produced fluid with different sand particle sizes and at different temperatures was studied via a rotating cylindrical electrode experimental device, as well as other methods such as corrosion mass loss measurement, morphological observation and electrochemical techniques. The results show that the increase of sand particle size can obviously promote the erosion wear of 20 steel, which is consistent with the morphology observation. With the increase of sand particle size, both the effect of corrosion promoting erosion and the effect of erosion promoting corrosion firstly increase and then decrease. When the sand particle size is in the range of 40~70 μm to 120~200 μm, the erosion-corrosion mode of the steel may mainly be ascribed to the mixed control of erosion and electrochemical corrosion. When the particle size of the sand is 200~300 μm, the erosion wear is dominant. The erosion-corrosion of 20 steel at different temperatures is mainly controlled by erosion and electrochemical corrosion. The higher the temperature, the much obvious the promotion effect of corrosion on erosion.

Key words： 20 steel erosion corrosion sand particle size temperature synergism effect

收稿日期: 2020-08-03

ZTFLH:

TG174

基金资助:国家自然科学基金(41801194);江苏省油气储运重点实验室开放课题(CDYQCY202004);2019年度常州大学大学生创新创业基金(2019-04-C-36)

通讯作者: 赵会军 E-mail: zhj@cczu.edu.cn

Corresponding author: ZHAO Huijun E-mail: zhj@cczu.edu.cn

作者简介: 任莹，女，1996年生，硕士生

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引用本文:

任莹, 赵会军, 周昊, 张建伟, 刘雯, 杨足膺, 王磊. 粒径和温度对20号钢冲刷腐蚀协同作用的影响[J]. 中国腐蚀与防护学报, 2021, 41(4): 508-516.
Ying REN, Huijun ZHAO, Hao ZHOU, Jianwei ZHANG, Wen LIU, Zuying YANG, Lei WANG. Effect of Sand Size and Temperature on Synergistic Effect of Erosion-corrosion for 20 Steel in Simulated Oilfield Produced Fluid with Sand. Journal of Chinese Society for Corrosion and protection, 2021, 41(4): 508-516.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.140 或 https://www.jcscp.org/CN/Y2021/V41/I4/508

图1 20号钢在不同砂粒粒径下冲刷腐蚀极化曲线

表1 不同粒径下20号钢冲刷腐蚀极化曲线拟合数据

图2 不同粒径下20号钢冲刷腐蚀电化学阻抗谱

图3 不同粒径下20号钢的电化学阻抗谱拟合等效电路图

表2 不同粒径下20号钢的电化学阻抗谱拟合数据

图4 不同粒径下20号钢的质量损失速率

表3 不同粒径条件下冲刷腐蚀各分量定量分析结果

表4 冲刷腐蚀过程中主导因素判定表

图5 不同粒径下20号钢的冲刷腐蚀形貌

图6 不同温度下20号钢的冲刷腐蚀极化曲线

表5 20号钢在不同温度下冲刷腐蚀极化曲线拟合数据

图7 各温度下20号钢纯腐蚀电化学阻抗谱

图8 各温度下20号钢冲刷腐蚀电化学阻抗谱

图9 不同温度下20号钢的拟合等效电路图

表6 不同温度下20号钢的电化学阻抗谱拟合数据

图10 不同温度下20号钢的质量损失速率

表7 不同温度下的腐蚀数据分析

图11 不同温度下20号钢冲刷腐蚀形貌

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