阳极电沉积制备CeO<sub>2</sub>薄膜

中国腐蚀与防护学报

2012, Vol. 32

Issue (1): 34-38

研究报告

本期目录 | 过刊浏览

阳极电沉积制备CeO₂薄膜

杨青松^1,2,李纯²,王杰²,杨仲年³,张昭2,张鉴清^2,4

1. 湛江腐蚀与防护研究中心湛江 524000
2. 浙江大学化学系杭州 310027
3. 滨州学院化学与化工系滨州 256603
4. 中国科学院金属研究所金属腐蚀与防护国家重点实验室沈阳 110016

PREPARATION OF CERIA THIN FILMS BY ANODIC ELECTRODEPOSITION

YANG Qingsong^1,2, LI Chun², WANG Jie², YANG Zhongnian³, ZHANG Zhao², ZHANG Jianqing^2,4

1. Zhanjiang Corrosion and Protection Center, Zhanjiang 524000
2. Department of Chemistry, Zhejiang University, Hangzhou 310027
3. Department of Chemistry and Chemical Engineering, Binzhou University, Binzhou 256603
4. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016

全文: PDF(1119 KB)

摘要: 用阳极电沉积技术在304不锈钢基体上制备CeO₂薄膜，用扫描电子显微镜（SEM）和X射线衍射（XRD）等手段探讨不同配体阳离子种类、配体浓度和O₂对镀层表面结构的影响规律。结果表明，CH₃COONH₄配体中的铵离子（NH₄⁺）对CeO₂薄膜晶粒的细化具有重要作用，镀液中高CH₃COONH₄配体浓度及镀液的脱氧作用有利于阳极电沉积CeO₂薄膜的致密化；在镀液组成为0.1 mol/L Ce(NO₃)₃和0.2 mol/LCH₃COONH₄、且镀液脱氧的实验条件下，获得了平整致密的纳米晶CeO₂薄膜，其晶粒粒径范围为5~10 nm。

关键词 ：纳米晶, CeO₂薄膜, 阳极电沉积

Abstract：Cerium oxide thin films were anodically electrodeposited onto 304 stainless steel substrates. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) were used to investigate the effects of different deposition conditions, including different concentration of ligand and different kinds of ligand-cations and O₂, on the surface structure of the anodically obtained CeO₂ film. The results showed that NH₄⁺ can refine the crystallites of CeO₂ film, high concentration of CH₃COONH₄ ligand and the deaerating process of electroplating solutions can make the obtained CeO₂ film compact. Under the deaerating conditions, nanocrystalline anodic CeO₂ film with the micro-crystallite diameter between 5~10 nm has been successfully obtained from the solution containing 0.1 mol/L Ce(NO₃)₃ and 0.2 mol/L CH₃COONH₄.

Key words： nanocrystalline cerium oxide film anodic electrodeposit

收稿日期: 2010-08-09

ZTFLH:

TG174.44

基金资助:

国家自然科学基金项目（21073162，51131005），嘉兴市精英引领计划项目和山东省优秀中青年科学家科研奖励基金项目（2008BS04030）资助

通讯作者: 李纯 E-mail: eaglezzy@zjuem.zju.edu.cn

Corresponding author: LI Chun E-mail: eaglezzy@zjuem.zju.edu.cn

作者简介: 杨青松，男，1970年生，工程师，研究方向为金属腐蚀与防护

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引用本文:

杨青松,李纯,王杰,杨仲年,张昭,张鉴清. 阳极电沉积制备CeO₂薄膜[J]. 中国腐蚀与防护学报, 2012, 32(1): 34-38.
LI Quan, YU Jie, CHEN Yu, ZHANG Zhao, ZHANG Jian-Qing. PREPARATION OF CERIA THIN FILMS BY ANODIC ELECTRODEPOSITION. J Chin Soc Corr Pro, 2012, 32(1): 34-38.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2012/V32/I1/34

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