铝合金在NaHSO<sub>3</sub>溶液中干湿周浸腐蚀行为

中国腐蚀与防护学报

2008, Vol. 28

Issue (6期): 345-350

研究报告

本期目录 | 过刊浏览

铝合金在NaHSO₃溶液中干湿周浸腐蚀行为

周和荣^1;3;李晓刚^1;2;董超芳¹;马坚³;陆启凯³;冯皓³

1.北京科技大学材料学院腐蚀与防护中心北京 100083
2.北京科技大学北京市腐蚀、磨蚀与表面技术重点实验室北京 100083
3.中国电器科学研究院工业产品环境适应性国家重点实验室广州 510063

CORROSION BEHAVIOR OF ALUMINIUM ALLOYS AFTER CYCLIC WET-DRY IMMERSION TEST IN 0.02 mol/L NaHSO₃SOLUTION

ZHOU Herong^1;3;LI Xiaogang^1;2;DONG Chaofang¹;MA Jian³;LU Qikai³;FENG Hao³

1.Corrosion and Protection Center;University of Science and Technology Beijing; Beijing 100083
2.Beijing Key Laboratory for Corrosion; Erosion and Surface Technology; University of Science and Technology Beijing; Beijing 100083
3.State Key Laboratory of Environmental Adaption for Industrial Products; China National Electric Apparatus Research Institute; Guangzhou 510063

全文: PDF(1324 KB)

摘要:

采用干湿周浸实验、失重法和电化学阻抗谱研究了铝合金1060、2A12和7A04在0.02 mol/L NaHSO₃溶液中的腐蚀行为与规律，用扫描电镜（SEM）观察腐蚀产物形貌，并用能谱仪（EDX）和光电子能谱仪（XPS）分析其组成，并测试力学性能。研究表明，随腐蚀时间的延长，铝合金表面的腐蚀产物不断增多，失重增加，力学性能下降；腐蚀产物形貌以团状为主，并不断向外延伸，呈现不均匀的凹凸形貌；腐蚀产物主要为A1₂O₃和A1的硫酸盐水合物；电化学阻抗谱拟合结果显示,腐蚀速率先增加后降低，腐蚀时间为360 h时腐蚀速率达到最大值；耐蚀性能由强至弱依次为1060，2A12，7A04铝合金。

关键词 ：铝合金, 干湿周浸, 失重法, 电化学阻抗谱

Abstract：

The corrosion behaviors of aluminium alloys 1060，2A12 and 7A04 under cyclic wet-dry immersion conditions have been investigated in 0.02 mol/L sodium sulfite solution by the mass loss method and electrochemical impedance spectroscopy （EIS）. Scanning electron microscopy （SEM） was used to observe the surface morphology； energy dispersive X-ray detector （EDX） and X-ray photoelectron spectroscopy （XPS） were employed to analyze the corrosion products. We also tested the mechanical capability of experimental materials. The results showed that corrosion product was increasing with testing hours prolonging, mass loss adding, strength and elongation percentage declining. Surface observation revealed that corrosion product was agglomerated and accidented, extending forth. The main corrosion product is alumina and aluminium sulfate hydrate. The results of EIS indicated that corrosion rate is highest in 360 hour. Corrosion resistance of aluminium 1060 was best in 0.02 mol/L sodium sulfite solution, but that of aluminium alloy 7A04 was worst.

Key words： aluminium alloys cyclic wet－dry immersion test mass loss method EIS

收稿日期: 2007-03-28

ZTFLH:

TG172

基金资助:

国家自然科学基金项目(50499331)

通讯作者: 周和荣 zhouhr_9@163.com

Corresponding author: ZHOU Herong

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	周和荣
44.8K

引用本文:

周和荣李晓刚董超芳马坚陆启凯冯皓. 铝合金在NaHSO₃溶液中干湿周浸腐蚀行为[J]. 中国腐蚀与防护学报, 2008, 28(6期): 345-350.
ZHOU He-Rong. CORROSION BEHAVIOR OF ALUMINIUM ALLOYS AFTER CYCLIC WET-DRY IMMERSION TEST IN 0.02 mol/L NaHSO₃SOLUTION. J Chin Soc Corr Pro, 2008, 28(6期): 345-350.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2008/V28/I6期/345

[1]Zhang X Y,An B G,Han E H,et al.Runoff and corrosion of material due to acid rain[J].Corros.Sci.Prot.Technol.,2002,14(3):157-160(张学元,安百刚,韩恩厚等.酸雨对材料的腐蚀/冲刷研究现状[J].腐蚀科学与防护技术,2002,14(3):157-160)
[2]Wang Z Y,Ma T,Han W,et al.Corrosion behavior of aluminium alloys LC4in simulated polluted atmospheric environment[J].J.Chin.Soc.Corros.Prot.,2005,25(6):321-326(王振尧,马腾,韩薇等.LC4铝合金在模拟污染大气环境中的腐蚀行为[J].中国腐蚀与防护学报,2005,25(6):321-326)
[3]Gonzalez J A,Morcillo M,Lopez V,et al.Atmospheric corrosion of bare and anodized aluminium in a wide range of environmental conditions,Part I:Visual observations and gravimetric results[J].Surf.Coat.Technol.,2002,153:225-234
[4]Mendoza A R,Corvo F.Outdoor and indoor atmospheric corrosion of nonferrous metals[J].Corros.Sci.,2000,42:1123-1147
[5]Gamal A EL-Mahdy,Kwang B Kim.AC impedance study on the atmospheric corrosion of aluminium under periodic wet-dry conditions[J].Electrochim.Acta,2004,49:1937-1948
[6]Cheng Y L,Zhang Z,Cao F H,et al.A study of the corrosion of aluminium alloy2024-T3under thin electrolyte layers[J].Corros.Sci.,2004,46(7):1649-1667
[7]Oesch S,Faller M.Environmental effects on materials:the effect of the air pollutants SO2,NO2,NO and O3on the corrosion of copper,zinc and aluminium,A short literature survey and results of laboratoryexposures[J].Corros.Sci.,1997,39(9):1505-1530
[8]CaiJP,LiuM,LuoZH,etal.Studyonacceleratedtestsforatmospheric corrosion of aeronautical aluminium alloy[J].J.Chin.Soc.Corros.Prot.,2005,25(5):262-266(蔡健平,刘明,罗振华等.航空铝合金大气腐蚀加速试验研究[J].中国腐蚀与防护学报,2005,25(5):262-266)
[9]Wang Z Y,Yu G C,Han W.Atmospheric corrosion law of three non-ferrous metals in Shenyang area[J].Chin.J.Nonferrous.Met.,2003,13(2):367-372(王振尧,于国才,韩薇.3种有色金属在沈阳地区的大气腐蚀规律[J].中国有色金属学报,2003,13(2):367-372)
[10]Li J F,Zheng Z Q,Ren W D.Function mechanism of secondary phase on localized corrosion of Al alloy[J].Mater.Rev.,2005,19(2):81-83(李劲风,郑子樵,任文达.第二相在铝合金局部腐蚀中的作用机制[J].材料导报,2005,19(2):81-83)
[11]Han W,Wang Z Y,Yu G C,et al.Corrosion of aluminium in wet/dry environment containing SO2[J].Chin.J.Nonferrous.Met.,2003,13:631-634(韩薇,王振尧,于国才等.铝在含SO2湿润/干燥环境中的腐蚀规律[J].中国有色金属学报,2003,13(2):631-634)
[12]Graedel T E.Corrosion mechanisms for aluminium exposed to the heat atmosphere[J].J.Electrochem.Soc.,1989,136(4):204c-212c
[13]An B G,Zhang X Y,Song S Z,et al.A study of electrochemical impedance spectrum for corrosion behavior of LY12aluminium alloy in simulated acid rain[J].J.Chin.Soc.Corros.Prot.,2003,23(3):167-170(安百刚,张学元,宋诗哲等.LY12铝合金在模拟酸雨溶液中的阻抗谱研究[J].中国腐蚀与防护学报,2003,23(3):167-170)
[14]Buchheit R G,Grant R P,Hlavaa P F,et al.Local dissolution phenomena associated with S phase(Al2CuMg)particles in aluminium alloy2024-T3[J].J Electrochem.Soc.,1997,144(8):2621-2628
[15]Buchheit R G,Martinez M A,Montes L P.Evidence for Cu ion formation by dissolution and dealloying the Al2CuMg intermetallic compound in rotating ring-dish collection experiments[J].J.Electro-chem.Soc.,2000,147:119-128
[16]Liao C M,Olive J M,Gao M et al.In situ monitoring of pitting corrosion in aluminium alloy2024[J].Corrosion,1998,54:451-458x

[1]	张雨轩, 陈翠颖, 刘宏伟, 李伟华. 铝合金霉菌腐蚀研究进展[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[2]	于宏飞, 邵博, 张悦, 杨延格. 2A12铝合金锆基转化膜的制备及性能研究[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[3]	胡露露, 赵旭阳, 刘盼, 吴芳芳, 张鉴清, 冷文华, 曹发和. 交流电场与液膜厚度对A6082-T6铝合金腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2020, 40(4): 342-350.
[4]	曹京宜, 方志刚, 陈晋辉, 陈志雄, 殷文昌, 杨延格, 张伟. 5083铝合金表面单致密微弧氧化膜的制备及其性能研究[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[5]	王英君, 刘洪雷, 王国军, 董凯辉, 宋影伟, 倪丁瑞. 新型高强稀土Al-Zn-Mg-Cu-Sc铝合金的阳极氧化及其抗腐蚀性能研究[J]. 中国腐蚀与防护学报, 2020, 40(2): 131-138.
[6]	任建平,宋仁国. 双级时效对7050铝合金力学性能及氢脆敏感性的影响[J]. 中国腐蚀与防护学报, 2019, 39(4): 359-366.
[7]	王霞,任帅飞,张代雄,蒋欢,古月. 豆粕提取物在盐酸中对Q235钢的缓蚀性能[J]. 中国腐蚀与防护学报, 2019, 39(3): 267-273.
[8]	达波,余红发,麻海燕,吴彰钰. 等效电路拟合珊瑚混凝土中钢筋锈蚀行为的电化学阻抗谱研究[J]. 中国腐蚀与防护学报, 2019, 39(3): 260-266.
[9]	夏俊捷,牛红志,刘敏,曹华珍,郑国渠,伍廉奎. 基于卤素效应的阳极氧化技术提高Ti48Al5Nb合金抗高温氧化性能[J]. 中国腐蚀与防护学报, 2019, 39(2): 96-105.
[10]	达波,余红发,麻海燕,吴彰钰. 阻锈剂的掺入方式对全珊瑚海水混凝土中钢筋锈蚀的影响[J]. 中国腐蚀与防护学报, 2019, 39(2): 152-159.
[11]	刘建国,高歌,徐亚洲,李自力,季菀然. 咪唑啉类衍生物缓蚀性能研究[J]. 中国腐蚀与防护学报, 2018, 38(6): 523-532.
[12]	陈高红,胡远森,于美,刘建华,李国爱. 硫酸阳极化对2E12铝合金力学性能的影响[J]. 中国腐蚀与防护学报, 2018, 38(6): 579-586.
[13]	邓培昌, 刘泉兵, 李子运, 王贵, 胡杰珍, 王勰. X70管线钢在热带海水-海泥跃变区的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 415-423.
[14]	曹敏, 刘莉, 余钟芬, 李瑛, 王福会. 2A02铝合金在模拟海洋大气环境中的剥蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 502-510.
[15]	马景灵, 通帅, 任凤章, 王广欣, 李亚琼, 文九巴. L-半胱氨酸/ZnO缓蚀剂对3102铝合金在碱性溶液中电化学性能的影响[J]. 中国腐蚀与防护学报, 2018, 38(4): 351-357.

Viewed

Full text

Abstract

Cited

Shared

Discussed