碳钢在含硫化氢及高压二氧化碳饱合的NaCl溶液中的腐蚀行为

中国腐蚀与防护学报

2000, Vol. 20

Issue (4): 204-210

研究报告

本期目录 | 过刊浏览

碳钢在含硫化氢及高压二氧化碳饱合的NaCl溶液中的腐蚀行为

李国敏;刘烈伟;郑家shen

华中理工大学化学系

CORROSION BEHAVIOR OF CARBON STEEL IN HIGH PRESSURE CARBON DIOXIDE SATURATED NaCl SOLUTIONS CONTAINING HYDROGEN SULFIDE

Guomin Li;Liewei Liu;

华中理工大学化学系

全文: PDF(202 KB)

摘要: 利用自制的高温、高压腐蚀试验及电化学测试装置，通过失重法、电化学极化曲线法及电子探针微观分析等方法，研究了温度、硫化氢浓度对碳钢在高压二氧化碳饱和的3%NaCl溶液中腐蚀的影响。结果表明：较低温度（80℃）下，升高温度及增大硫化氢浓均加速腐蚀反应的阴、阳极过程，失重腐蚀速率增大；高浓度的硫化氢抑制了腐蚀反应的阴极过程；120℃时碳钢CO2腐蚀产物膜对金属基体起很好的保护作用，失重腐蚀速率减少了3—4倍，随硫化氢浓度的增大，失重腐蚀速率缓慢增长，腐蚀产物FeCO3膜逐渐转变为以硫铁化合物为主的腐蚀产物膜。

关键词 ：二氧化碳, 硫化氢, 腐蚀产物, 表面膜

Abstract：Using a self-made autoclave for corrosion testing and electrochemical measurements under high pressure conditions, the effects of temperature and hydrogen sulfide concentration on the corosion of varbon steel in high pressure CO2 saturated 3% NaCl solutions were studied by weight-loss method, electrochemical polarization technique, electron probe microscopy analysis (EPMA). Experimental results showed that temperature and hydrogen sulfide concentration had obvious effects on the corrosion rate, configuration and character of corrosion scales. The adhesivity and protectivity of corrosion scale formed at lower temperature (80℃) were poor. The rising of temperature accelerated cathodic and anodic process of corrosion reaction and at the same time increased corrosion rate. Dense iron carbonate filn was formed on steel surface at 120℃, which exhibited good adhesivity and protectivity. The corrosion rate of steel at 120℃ was only one fourth of that at 80℃. Electrochemical polarization indicated that at 120℃ cathodic process of corrosion reaction was accelerated, while the anodic process was restrained.At the lower temperature (80℃),both cathodic and anodic process of corrosion reaction were accelerated and the corrosion rate increased with increasing the concentration of hydrogen sulfide. The cathodic process of corrosion reaction is restrained at the higher concentration of hydrogen sulfide.At the higher temperature (120℃),with increasing the concentration of hydrogen sulfide the corosion scale gradually changed from iron carbonate film to corrosion scale mainly made up of sulfur/iron compound.Electrochemical polarization indicated that cathodic process of corrosion reaction was acelerated but the anodic process was restrained.

Key words： carbon dioxide hydrogen sulfide corrosion product scale

收稿日期: 1999-07-05

ZTFLH:

TG174.9

通讯作者: 李国敏

Corresponding author: Guomin Li

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引用本文:

李国敏; 刘烈伟; 郑家shen . 碳钢在含硫化氢及高压二氧化碳饱合的NaCl溶液中的腐蚀行为[J]. 中国腐蚀与防护学报, 2000, 20(4): 204-210 .
Guomin Li, Liewei Liu. CORROSION BEHAVIOR OF CARBON STEEL IN HIGH PRESSURE CARBON DIOXIDE SATURATED NaCl SOLUTIONS CONTAINING HYDROGEN SULFIDE. J Chin Soc Corr Pro, 2000, 20(4): 204-210 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2000/V20/I4/204

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