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中国腐蚀与防护学报  2026, Vol. 46 Issue (5): 1549-1559     CSTR: 32134.14.1005.4537.2025.374      DOI: 10.11902/1005.4537.2025.374
  研究报告 本期目录 | 过刊浏览 |
添加Y、Hf对AlCoCrFeNi高熵合金涂层在NaCl溶液中的腐蚀行为的影响
赵先锐1(), 戴中国1, 李战江2, 徐育烺2, 张会霞1, 李旺1
1.江苏海洋大学海洋工程学院 连云港 222005
2.江苏海事职业技术学院船舶与智能制造学院 南京 211170
Effect of Adding Y and Hf on Corrosion Behavior of AlCoCrFeNi High-entropy Alloy Coatings in NaCl Solution
ZHAO Xianrui1(), DAI Zhongguo1, LI Zhanjiang2, XU Yulang2, ZHANG Huixia1, LI Wang1
1.School of Ocean Engineering, Jiangsu Ocean University, Lianyungang 222005, China
2.School of Naval Architecture & Intelligent Manufacturing, Jiangsu Maritime Institute, Nanjing 211170, China
引用本文:

赵先锐, 戴中国, 李战江, 徐育烺, 张会霞, 李旺. 添加Y、Hf对AlCoCrFeNi高熵合金涂层在NaCl溶液中的腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2026, 46(5): 1549-1559.
Xianrui ZHAO, Zhongguo DAI, Zhanjiang LI, Yulang XU, Huixia ZHANG, Wang LI. Effect of Adding Y and Hf on Corrosion Behavior of AlCoCrFeNi High-entropy Alloy Coatings in NaCl Solution[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(5): 1549-1559.

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摘要: 

为应对海洋工程装备在宽温域海洋腐蚀环境下的服役需求,本文采用激光熔覆在AH40船用钢上制备AlCoCrFeNi与AlCoCrFeNiY0.5Hf0.4涂层,研究其在0~60 ℃区间下3.5% (质量分数) NaCl溶液中的腐蚀行为。通过动电位极化(LSV)、电化学阻抗谱(EIS)、扫描电子显微镜(SEM)和X射线光电子能谱(XPS)等技术手段表征电化学特性、钝化膜与腐蚀形貌。结果表明,添加Y、Hf的AlCoCrFeNi涂层在0和20 ℃具有更高电荷转移阻抗与稳定钝化,耐蚀性优于AlCoCrFeNi涂层。温度升高导致腐蚀电流升高、钝化膜不稳并出现点蚀;但Y、Hf促进致密钝化膜形成,使其在高温下仍具有高的抗点蚀性能。本研究可为多工况海洋防腐涂层设计提供依据。

关键词 : 高熵合金涂层,  腐蚀行为,  温度效应,  激光熔覆,  钝化膜,  AlCoCrFeNi系    
Abstract:

To meet the service requirements of ocean engineering equipment in complex conditions of temperature fluctuations and harsh corrosive environments, herein, high entropy alloy (HEA) coatings of AlCoCrFeNi and AlCoCrFeNiY0.5Hf0.4 were prepared on AH40 marine steel. The corrosion behavior of these coatings in 3.5% (mass fraction) NaCl solution over the temperature range of 0-60 ℃ was systematically investigated by means of potentiodynamic polarization, electrochemical impedance spectroscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy, in terms of the electrochemical characteristics, passivation film structure, corrosion morphology, and corrosion products of the coatings. The results indicate that at lower temperatures, the AlCoCrFeNiY0.5Hf0.4 coating exhibits excellent corrosion resistance, especially at 0 and 20 ℃, with high charge transfer impedance and stable passivation behavior. As the temperature increases, the corrosion resistance of the coating significantly deteriorates, as evidenced by an increase in corrosion current density, unstable passivation film, and the formation of local corrosion pits. The corrosion resistance of AlCoCrFeNiY0.5Hf0.4 coating at higher temperatures is significantly better than that of AlCoCrFeNi coating, which is related to the promotion effect of Y and Hf on the formation a more stable and dense passivation film on the coating surface. The increase in temperature has a profound impact on the electrochemical stability and corrosion mechanism of coatings, especially at high temperatures, which challenges the stability of passivation films and accelerates the corrosion rate. The results provide a meaningful reference for the design and optimization of new adaptive marine anti-corrosion coatings, and have important application prospects.

Key words: high entropy alloy coating    corrosion behavior    temperature effect    laser cladding    passivation film    AlCoCrFeNi series
收稿日期: 2025-12-11      32134.14.1005.4537.2025.374
ZTFLH:  TG174.3  
基金资助:博士研究基金(2024BSKY21);博士研究基金(2024BSKY22);江苏省高等学校基础科学研究面上项目(25KJB430007)
通讯作者: 赵先锐,E-mail:2595102150@qq.com,研究方向为高性能耐蚀涂层开发
Corresponding author: ZHAO Xianrui, E-mail: 2595102150@qq.com
作者简介: 赵先锐,男,1978年生,博士,教授
图1  高熵合金粉末的SEM形貌
图2  熔覆层表面的XRD图谱
图3  熔覆层的SEM形貌和EDS元素分析结果
图4  熔覆层的SEM形貌和EDS元素分析结果
图5  温度梯度下熔覆层动电位极化曲线对比
Cladding layerTemperature/ ℃

Ecorr

/ V

Icorr

/ A·cm-2

AlCoCrFeNi0-0.4691.802 × 10-6
20-0.4833.523 × 10-6
40-0.5016.546 × 10-6
60-0.5481.056 × 10-5
AlCoCrFeNiY0.5Hf0.40-0.3378.046 × 10-7
20-0.3531.277 × 10-6
40-0.3772.598 × 10-6
60-0.4066.212 × 10-6
AH400-0.5051.202 × 10-5
20-0.5452.463 × 10-5
40-0.5855.112 × 10-5
60-0.6251.058 × 10-5
表1  熔覆层在不同温度下的电化学腐蚀参数
图6  温度梯度下熔覆层的电化学阻抗谱
Cladding layerTemperatureRsRfRctCPE1CPE2
/ ℃/ Ω·cm2/ Ω·cm2/ Ω·cm2Y / Ω-1cm-2s-nnY / Ω-1cm-2s-nn
AlCoCrFeNi09.916210824144416.17 × 10-50.8871.69 × 10-130.866
206.25271329112026.29 × 10-50.8328.57 × 10-130.798
403.974989611335.17 × 10-50.8062.20 × 10-120.797
602.86623514021.92 × 10-40.7682.50 × 10-110.736
AlCoCrFeNiY0.5Hf0.4012.802626166368404.27 × 10-50.8905.56 × 10-130.884
206.59728992251084.91 × 10-50.8442.42 × 10-120.863
404.3453892494766.38 × 10-50.8104.34 × 10-30.797
603.4659314821911.41 × 10-40.8079.27 × 10-30.719
AH4008.97610401132492.27 × 10-50.8014.46 × 10-130.799
205.42399698773.58 × 10-50.7967.89 × 10-130.742
402.34679612585.56 × 10-40.7435.23 × 10-120.714
601.8972565866.33 × 10-40.7223.69 × 10-110.706
表2  熔覆层在不同温度下的等效电路拟合参数
图7  熔覆层在3.5%NaCl溶液中的等效电路图
图8  熔覆层电化学腐蚀后的SEM形貌
图9  AlCoCrFeNiY0.5Hf0.4 HEAs涂层在0 ℃下电化学腐蚀后钝化膜形成的XPS图谱
图10  AlCoCrFeNiY0.5Hf0.4 HEAs涂层在20 ℃下电化学腐蚀后钝化膜形成的XPS图谱
图11  AlCoCrFeNiY0.5Hf0.4 HEAs涂层在40 ℃下电化学腐蚀后钝化膜形成的XPS图谱
图12  AlCoCrFeNiY0.5Hf0.4 HEAs涂层在60 ℃下电化学腐蚀后钝化膜形成的XPS图谱
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