Please wait a minute...
中国腐蚀与防护学报    DOI: 10.11902/1005.4537.2025.237
  本期目录 | 过刊浏览 |
混凝土配重层对近海海底钢质管道阴极保护效果的影响
王萌萌1,曹国民2,孟繁兴1,李天亮3,宋沁峰3,单太航3,董亮3
1. 国家管网集团东部储运公司 科技研发中心
2. 国家管网集团东部原油储运有限公司
3. 常州大学
The influence of Concrete counterweight layer on cathodic protection effect of nearshore submarine steel pipes
引用本文:

王萌萌 曹国民 孟繁兴 李天亮 宋沁峰 单太航 董亮. 混凝土配重层对近海海底钢质管道阴极保护效果的影响[J]. 中国腐蚀与防护学报, 10.11902/1005.4537.2025.237.

全文: PDF(3509 KB)  
摘要: 为探究混凝土配重层对近海海洋环境中的海底管道阴极保护效果的影响,采用稳态恒电位极化、电化学阻抗谱(EIS)和数值模拟计算方法,系统研究了X60裸钢和带混凝土配重层的X60钢在不同盐度(盐度5‰、16.8‰、26.7‰)静态海水和海泥以及2m/s流动海水的阴极极化行为,并测试了混凝土配重层电阻率,获得了混凝土配重层影响下的管道阴极保护电位分布和牺牲阳极输出电流。结果表明,在5‰、16.8‰、26.7‰盐度的静态海水和海泥中达到-0.85V(CSE)极化电位时,X60裸钢所需的阴极极化电流密度约为带混凝土配重层的X60钢所需的3.5~8倍。在2m/s流动海水中,对应电位下带混凝土配重层的X60钢所需的阴极极化电流密度与在静态海水中差异相对较小,流速会明显提升X60裸钢所需的阴极极化电流密度,这与流速增大氧的扩散和破坏钙质沉积层有关,而混凝土配重层阻碍了流速的这种影响。电化学阻抗谱测得的极化电阻的变化与极化电流密度的变化规律一致,同时获得的海水中混凝土配重层电阻率约为对应海水电阻率的70倍,海泥中混凝土配重层电阻率约为对应海泥电阻率的37倍。数值模拟结果显示,混凝土配重层降低阴极极化电流密度使得阴极保护电位负移明显且电位衰减小,混凝土配重层电阻率降低了牺牲阳极的输出电流而使得阴极保护电位稍正移。混凝土配重层对于改善海底管道阴极保护效果作用明显。
关键词 X60钢混凝土配重层阴极极化电化学阻抗谱近海海洋环境数值模拟    
Abstract:To investigate the effect of concrete weighted layer on cathodic protection of submarine pipes in nearshore marine environments, steady-state constant potential polarization, electrochemical impedance spectroscopy (EIS), and numerical simulation methods were used to systematically study the cathodic polarization behavior of bare X60 steel and concrete weighted X60 steel in static seawater at different salinities (5 ‰, 16.8 ‰, 26.7 ‰) and mud, as well as 2m/s flowing seawater. The resistivity of the concrete weighted layer was also tested, and the cathodic protection potential distribution and sacrificial anode output current of the pipe under the influence of the concrete weighted layer were obtained. The results showed that when the polarization potential of -0.85V (CSE) was reached in static seawater with salinities of 5 ‰, 16.8 ‰, and 26.7 ‰ and mud, the cathodic polarization current density required for bare X60 steel was about 3.5-8 times that of X60 steel with a concrete weight layer. In 2m/s flowing seawater, the difference in cathodic polarization current density required for X60 steel with concrete weight layer under corresponding potential is relatively small compared to static seawater. The flow velocity will significantly increase the cathodic polarization current density required for bare X60 steel, which is related to the diffusion of oxygen and the destruction of calcium deposition layer due to the increase in flow velocity. However, the concrete weight layer hinders this effect of flow velocity. The change in polarization resistance measured by electrochemical impedance spectroscopy is consistent with the change in polarization current density. At the same time, the resistivity of the concrete weight layer in seawater is about 70 times that of the corresponding seawater resistivity, and the resistivity of the concrete weight layer in marine mud is about 37 times that of the corresponding marine mud resistivity. The numerical simulation results show that the concrete weight layer reduces the cathodic polarization current density, resulting in a significant negative shift and small potential attenuation of the cathodic protection potential. The concrete weight layer reduces the output current of the sacrificial anode, resulting in a slightly positive shift of the cathodic protection potential. The concrete weighted layer has a significant effect on improving the cathodic protection effect of submarine pipes.
Key wordsX60 steel    concrete counterweight layer    cathodic polarization    electrochemical impedance spectroscopy    nearshore marine environment    numerical simulation
收稿日期: 2025-07-28     
ZTFLH:  TG172  
基金资助:海底管道状态检测与安全评估技术研究
[1] 王得, 张璠, 王兴奇, 张贺新, 赵成志, 杨延格. 单组分氟碳改性环氧涂层对碳钢和铝合金长期防腐性能的对比研究[J]. 中国腐蚀与防护学报, 2025, 45(6): 1549-1562.
[2] 许诗源, 孟鑫, 杨亚璋, 刘辰, 张昭, 方晓祖. 腐蚀形貌对镁合金电化学阻抗谱特征的影响研究[J]. 中国腐蚀与防护学报, 2025, 45(6): 1589-1598.
[3] 项琦峰, 赵阳, 张涛, 王福会. 模拟浅海及深海环境中阴极极化对10CrNi5MoV钢氢脆敏感性的影响[J]. 中国腐蚀与防护学报, 2025, 45(6): 1599-1609.
[4] 郭玉杰, 李艳辉, 夏大海, 胡文彬. 腐蚀电化学阻抗谱的数据解析与物理模型研究进展[J]. 中国腐蚀与防护学报, 2025, 45(5): 1143-1160.
[5] 夏大海, 潘成成, 郭玉杰, 胡文彬, TRIBOLLET Bernard. EIS研究7050铝合金在NaCl溶液空蚀作用下的界面状态与腐蚀机制[J]. 中国腐蚀与防护学报, 2025, 45(5): 1196-1204.
[6] 何武豪, 刘阳, 杨思懿, 张韶栋, 吴伟, 张俊喜. 敏化处理对传统和增材制造316L不锈钢电化学和晶间腐蚀的影响[J]. 中国腐蚀与防护学报, 2025, 45(5): 1331-1340.
[7] 郭姿含, 樊建春, 杨云朋, 张军, 代四维. 动载作用下高压三通管汇的冲蚀特性研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 698-708.
[8] 肖琦琨, 马军, 郭凯, 熊新, 袁浩然. 基于DDPM-RSM的浆体管道冲蚀磨损数值模拟研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 709-719.
[9] 李丽, 李善文, 史洪微, 梁国平, 李春霖, 孙禹, 秦晋, 王伟, 韩恩厚. 高速列车用铝合金环氧底漆的腐蚀行为和湿热老化机理研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 757-764.
[10] 汤熠鑫, 张飞, 崔中雨, 崔洪芝, 李燚周. 氢对2205双相不锈钢在3.5%NaCl溶液中缝隙腐蚀行为影响[J]. 中国腐蚀与防护学报, 2025, 45(2): 431-437.
[11] 王天丛, 赵东杨, 向雪云, 吴航, 王文. 一种环氧耐蚀涂层在NaCl溶液中的劣化行为研究[J]. 中国腐蚀与防护学报, 2024, 44(5): 1361-1369.
[12] 刘喆, 邓成满, 魏军胜, 夏大海. 涂覆有机涂层的镀锡薄钢板耐蒸煮性能电化学快速检测技术研究[J]. 中国腐蚀与防护学报, 2024, 44(4): 883-890.
[13] 傅江悦, 郭建喜, 杨延格, 冷哲, 王文. 单相流冲刷条件下一种低合金高强钢的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2024, 44(3): 585-600.
[14] 李卓玄, 曹艳辉, 李崇杰, 李辉, 张小明, 雍兴跃. 耦接件涂层失效程度与其力学损伤之间的关系[J]. 中国腐蚀与防护学报, 2024, 44(3): 679-690.
[15] 裴莹莹, 管方, 董续成, 张瑞永, 段继周, 侯保荣. Desulfovibrio Bizertensis SY-1在阴极极化条件下对X70 管线钢的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2024, 44(2): 345-354.