氟碳涂料在防腐领域的研发现状和发展趋势

doi:10.11902/1005.4537.2015.033

中国腐蚀与防护学报

2016, Vol. 36

Issue (2): 97-106 DOI: 10.11902/1005.4537.2015.033

本期目录 | 过刊浏览

氟碳涂料在防腐领域的研发现状和发展趋势

房亚楠^1,²,秦立光¹,赵文杰¹(

),白琴²,张昕¹,乌学东¹

1. 中国科学院海洋新材料与应用技术实验室浙江省海洋材料与防护技术重点实验室中国科学院宁波材料技术与工程研究所宁波 315201
2. 上海大学材料科学与工程学院上海 200072

Research Progress and Development Trend on Corrosion Resistant Fluorocarbon Paint

Yanan FANG^1,²,Liguang QIN¹,Wenjie ZHAO¹(

),Qin BAI²,Xin ZHANG¹,Xuedong WU¹

1. Key Laboratory of Marine Materials and Related Technologies, Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
2. Faculty of Materials Science and Engineering, Shanghai University, Shanghai 200072, China

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摘要:

概述了氟碳涂料的发展过程,并对不同类型的氟碳涂料在防腐蚀领域的应用作了归纳介绍。总结了化学改性、物理共混、填料改性等方法对氟碳涂料防腐性能的影响。最后指出了氟碳涂料的发展趋势。

关键词 ：氟碳涂料, 防腐, 化学改性, 物理共混, 填料改性

Abstract：

Corrosion is a very common and serious problem which has a harmful impact on the economy development of the country. Among others the application of organic paints is the most economical and efficient way to protect engineering structures from corrosion. Fluorocarbon paint is one of the most widely used resins for anticorrosion application due to its excellent corrosion resistance, chemical resistance,and weatherability. However, fluorocarbon paint also has some disadvantages restricting its application in some fields, so it is necessary to modify the fluorocarbon paint. In this article,the development history and application of the fluorocarbon paint were systematically summarized. Then various modification methods including chemical modification, physical blending, and filler modification used for enhancing the anti-corrosion performance of fluorocarbon paint were introduced. Finally, the development trend of fluorocarbon paint was forecasted.

Key words： fluorocarbon paint anti-corrosion chemical modification physical blending fillermodification

基金资助:浙江省公益计划项目 (2014C31154),浙江省自然科学基金项目 (LY13E090009),宁波市自然科学基金项目 (2014A610132)和浙江省科技创新团队 (2011R50006) 资助

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房亚楠,秦立光,赵文杰,白琴,张昕,乌学东. 氟碳涂料在防腐领域的研发现状和发展趋势[J]. 中国腐蚀与防护学报, 2016, 36(2): 97-106.
Yanan FANG, Liguang QIN, Wenjie ZHAO, Qin BAI, Xin ZHANG, Xuedong WU. Research Progress and Development Trend on Corrosion Resistant Fluorocarbon Paint. Journal of Chinese Society for Corrosion and protection, 2016, 36(2): 97-106.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2015.033 或 https://www.jcscp.org/CN/Y2016/V36/I2/97

图1 PVF的分子结构

图2 PVDF分子的结构

图3 PTFE的分子结构

图4 氟碳涂料交联固化反应式

图5 FEVE氟碳树脂的分子结构图

图6 5种常温固化氟碳涂层体系的耐盐雾性能[44]

图7 涂层经过Cl-电迁移快速实验（RCM）后表面变化情况[42]

表1 环氧改性氟碳涂料的性能[68]

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