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Journal of Chinese Society for Corrosion and protection  2025, Vol. 45 Issue (5): 1253-1264    DOI: 10.11902/1005.4537.2024.408
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Effect of Surface Roughness, Concentration and Temperature of NaOH Solution on Corrosion Behavior of a Zr-based Metallic Glass
WANG Taotao1, XUE Rongjie1(), MA Xiaowei1, WAN Haofeng1, WANG Dongpeng2, LIU Zhenguang2
1 School of Materials Engineering, Jiangsu Institute of Technology, Changzhou 213001, China
2 School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212100, China
Cite this article: 

WANG Taotao, XUE Rongjie, MA Xiaowei, WAN Haofeng, WANG Dongpeng, LIU Zhenguang. Effect of Surface Roughness, Concentration and Temperature of NaOH Solution on Corrosion Behavior of a Zr-based Metallic Glass. Journal of Chinese Society for Corrosion and protection, 2025, 45(5): 1253-1264.

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Abstract  

The effect of temperature and concentration of NaOH solution, as well as the roughness of material on the electrochemical properties of a Zr-based metallic glass in NaOH solution were studied by means of mass loss measurement, electrochemical technology and scanning electron microscopy (SEM/EDS). The free corrosion rate of Zr-based metallic glass in 0.1 mol/L NaOH is 1.22 times that in 0.01 mol/L NaOH solution. With the increase of temperature, concentration and roughness, the Icorr of Zr-based metallic glass increases, the impedance and the corrosion resistance decrease. The corrosion products on the surface of Zr-based metallic glass increased, and the product corroded area increased. ZrO2, TiO2, NiO, CuO substrate oxides and Be(OH)2 corrosion products were formed on the surface of Vit1 after corrosion. As the temperature increases, the mobility of molecules and ions increases, making chemical reactions more likely to occur, and accelerating the dissolution and corrosion of metallic glasses. The increase of NaOH concentration and the acceleration of corrosion rate may be due to the fact that hydroxide ions (OH-) in highly concentrated alkaline solutions can react more effectively with the surface of metallic glasses, thereby accelerating corrosion. With the increase of roughness, the effective area of surface exposure involved in the corrosion reaction increases, and the corrosion reaction rate accelerates. After immersion, corrosion fluids accumulate on the surface of the alloy, resulting in an increase in local concentration differences, which lead to non-uniform corrosion and corrosion scarring.
Key words:  Zr-based metallic glass      electrochemistry      NaOH solution      corrosion property     
Received:  25 December 2024      32134.14.1005.4537.2024.408
ZTFLH:  TG172.5  
Fund: National Natural Science Foundation of China(51801083);Jiangsu Province University Innovation Training Program(202411463092Y)
Corresponding Authors:  XUE Rongjie, E-mail: xuerongjie@jsut.edu.cn
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WANG Taotao
XUE Rongjie
MA Xiaowei
WAN Haofeng
WANG Dongpeng
LIU Zhenguang

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.408     OR     https://www.jcscp.org/EN/Y2025/V45/I5/1253

Fig.1  Mass loss rates and corrosion rates of Vit1 during immersion for 648 h in 0.01 and 0.1 mol/L NaOH solutions
Fig.2  Potentiodynamic polarization curves of Vit1 samples with different surface roughness after immersion in NaOH solutions under different conditions of concentration and temperature: (a) immersion treatment, (b) roughness
Experiment conditionsIcorr / A·cm-2Ecorr / mVRs / kΩ·cm2Rct / kΩ·cm2CPE / μF·cm2α
1: 0.01 mol/L-25 ℃2.6 × 10-9-3740.4025322.704.02280.91285
2: 0.01 mol/L-35 ℃3.6 × 10-9-3330.7885154.703.93630.90021
3: 0.1 mol/L-25 ℃9.3 × 10-9-3070.0402132.706.68470.90352
4: 0.1 mol/L-35 ℃1.13 × 10-8-1460.033517.727.17760.89177
5: IC 0.01 mol/L-25 ℃6.2 × 10-9-3710.220365.549.66450.90692
6: IC 0.01 mol/L-35 ℃8.1 × 10-9-1250.170211.8011.0130.91269
7: IC 0.1 mol/L-25 ℃8.35 × 10-8-2230.027201.1810.540.93691
8: IC 0.1 mol/L-35 ℃9.12 × 10-8-2300.031142.476.80360.93684
9: 0.01 mol/L-180#3.16 × 10-7-6020.263417.157.00380.87587
10: 0.01 mol/L-400#2.76 × 10-7-4710.008454.496.16130.94270
11: 0.01 mol/L-1200#1.54 × 10-7-4300.272494.228.58450.89133
12: 0.01 mol/L-3000#5.93 × 10-8-2710.060525.494.16020.93659
13: 0.01 mol/L-5000#3.29 × 10-8-4730.060647.695.18290.86688
14: 0.1 mol/L-180#4.05 × 10-7-4630.054222.779.18760.91008
15: 0.1 mol/L-400#3.00 × 10-7-4300.484256.695.85580.93849
16: 0.1 mol/L-1200#2.05 × 10-7-3400.051291.745.05110.92293
17: 0.1 mol/L-3000#1.27 × 10-7-4090.008358.466.13160.90838
18: 0.1 mol/L-5000#4.43 × 10-8-6040.016390.806.70740.94493
Table 1  Fitting electrochemical parameters of potentiodynamic polarization curves in Fig.2 and EIS in Fig.3
Fig.3  Nyquist (a-c), Bode (d-f) and phase (g-i) diagrams of Vit1 samples with different surface roughnesses after immersion in NaOH solutions under different conditions of concentration and temperature, the inset in Fig.3a shows correspon-ding equivalent circuit model
Fig.4  SEM surface images of Vit1 samples with different surface roughness after immersion in NaOH solutions under different conditions of concentration and temperature. 0.01 mol/L at 25 and 35 ℃ (a, b); 0.01 mol/L and 0.1 mol/L (c, h); 0.01 mol/L at 25 and 35 ℃ (d, e); 0.1 mol/L at 25 and 35 ℃ (f, g); 0.1 mol/L at 25 and 35 ℃ (i, j); roughness of 180#, 400#, 1200#, 3000#, 5000# in 0.01mol/L (k-o); roughness of 180#, 400#, 1200#, 3000#, 5000# in 0.1 mol/L (p-t)
Fig.5  SEM (a) and spectral dispersion (b) of a Vit1 sample which was immersed in 0.1 mol/L NaOH solution and then electrochemical experiment was carried out in 0.1 mol/L-35 ℃ NaOH solution; atomic percentage (c-f) graphs of substrate and corrosion product of Vit1 samples with different surface roughness after immersion in NaOH solutions under different conditions of concentration and temperature
Fig.6  XPS full spectrum (a) and fine spectra (b-f) of Zr, Be, Ti, Ni and Cu elements of Vit1 after electrochemical experiment in NaOH solution at 0.1 mol/L and 25 ℃
Fig.7  Schematic illustration of corrosion mechanism
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