Corrosion Behavior of Welded Partitions of 3003 Al-alloy Used for Radiators of High-speed Train

doi:10.11902/1005.4537.2023.268

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (4): 1081-1088 DOI: 10.11902/1005.4537.2023.268

Current Issue | Archive | Adv Search

Corrosion Behavior of Welded Partitions of 3003 Al-alloy Used for Radiators of High-speed Train

WU Hailiang¹, CHEN Yuqiang¹(

), HUANG Liang², GU Hongyu², SUN Hongbo¹, LIU Jiajun¹, WANG Naiguang³, SONG Yufeng¹

1. Hunan Engineering Research Center of Forming Technology and Damage Resistance Evaluation for High Efficiency Light Alloy Components, Hunan University of Science and Technology, Xiangtan 411201, China
2. Zhuzhou Times Metal Manufacturing Co., Ltd., Zhuzhou 412200, China
3. School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China

Cite this article:

WU Hailiang, CHEN Yuqiang, HUANG Liang, GU Hongyu, SUN Hongbo, LIU Jiajun, WANG Naiguang, SONG Yufeng. Corrosion Behavior of Welded Partitions of 3003 Al-alloy Used for Radiators of High-speed Train. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 1081-1088.

Download:

HTML

PDF(10829KB)
Export: BibTeX | EndNote (RIS)

Abstract

The corrosion behavior of welded partitions of 3003 Al-alloy, used for radiators of high-speed train, in artificial solution of settling dust, which aims to simulate the synergistic ation of the settling dusts and rains on the partitions in the real service, was studied by means of immersion test, polarization curve measurement, X-ray fluorescence (XRF), scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS). Meanwhile, the relevant prediction model for the corrosion depth of welded partitions was established. The results show that, the pitting corrosion is dominant at the initial stage of corrosion, and then gradually evolves into intergranular corrosion. The main corrosion products of welded partitions are Al(OH)₃ and AlCl₃. In comparison with those of the as received ones, the corrosion potential of welded partitions after immersion for 180 d decreases by 24.5% and the corrosion current density increases by 156.7%. A prediction model for the maximum corrosion depth of welded partitions was established based on data of the immersion test results and the measured corrosion depth of the very welded partitions after 8 a of live vehicle service.

Key words: 3003 Al-alloy corrosion-resistance corrosion behavior corrosion model corrosion depth prediction model

Received: 25 August 2023 32134.14.1005.4537.2023.268

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52075166);National Natural Science Foundation of China(U21A20130);Hunan Science and Technology Innovation Program(2021GK4048);Hunan Science and Technology Innovation Program(2023RC1068)

Corresponding Authors: CHEN Yuqiang, E-mail: yqchen1984@163.com

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	WU Hailiang
	CHEN Yuqiang
	HUANG Liang
	GU Hongyu
	SUN Hongbo
	LIU Jiajun
	WANG Naiguang
	SONG Yufeng

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2023.268 OR https://www.jcscp.org/EN/Y2024/V44/I4/1081

Fig.1 SEM images (a-f) of 3003 Al-alloy welded partitions immersed in dust solution for 0 d (a), 3 d (b), 7 d (c), 15 d (d), 30 d (e) and 180 d (f), and EDS results (g-i)

Fig.2 Optical images of 3003 Al-alloy welded partition sections immersed in dust solution for 3 d (a),15 d (b),30 d (c) and 180 d (d)

Fig.3 XPS survey spectrum (a) and Al 2p fine spectrum (b) of 3003 Al-alloy welded partitions soaked in dust solution for 7 d

Fig.4 Polarization curves of 3003 Al-alloy welded partitions immersed in dust solution for different time

Table 1 Fitting electrochemical parameters of polarization curves of 3003 Al-alloy welded partitions soaked in dust solution for different time

Fig.5 Nyquist plots of 3003 Al-alloy welded partitions immersed in dust solution for different time (a) and corresponding equivalent electrical circuit (b)

Table 2 Fitting parameters of EIS of 3003 aluminium alloy welded partitions soaked in dust solution for different time

Fig.6 Profile metallography image (a) and SEM image (b) and EDS result (c) of 3003 Al-alloy welded partitions after actual exposure for 8 a

Fig.7 Corrosion models of 3003 Al-alloy welded partitions at the initial stage (a)，pitting stage (b)，expansion stage (c) and shedding stage (d)

Fig.8 Prediction curves of maximum corrosion depth of 3003 Al-alloy welded partitions

[1]	Yang H J, Gao Y M, Qin W C, et al. Microstructure and corrosion behavior of electroless Ni-P on sprayed Al-Ce coating of 3003 aluminum alloy [J]. Surf. Coat. Technol., 2015, 281: 176
[2]	Li X Q, Xiao Q, Li L, et al. Microstructure and mechanical property of 3003 aluminum alloy joint brazed with Al-Si-Cu-Zn filler metal [J]. J. Mater. Eng., 2016, 44(9): 32 doi: 10.11868/j.issn.1001-4381.2016.09.005
	李小强, 肖晴, 李力等. Al-Si-Cu-Zn钎料钎焊3003铝合金的接头组织及力学性能 [J]. 材料工程, 2016, 44(9): 32 doi: 10.11868/j.issn.1001-4381.2016.09.005
[3]	Pandya A, Saha D, Singh J K, et al. Effect of environmental pollution on corrosion characteristics of 3003 Aluminium alloy exposed in different parts of India [J]. Trans. Indian Inst. Met., 2017, 70: 1607
[4]	Chen X, Tian W M, Li S M, et al. Effect of temperature on corrosion behavior of 3003 aluminum alloy in ethylene glycol–water solution [J]. Chin. J. Aeronaut., 2016, 29: 1142
[5]	Yang H J, Gao Y M, Qin W C. Corrosion inhibition of 3003 aluminum alloy by cerium chloride-sodium nitrite blend in flue gas condensate [J]. Mater. Corros., 2017, 68: 1246
[6]	Liu Q B, Liu Z D, Guo S Y, et al. Galvanic corrosion behavior of 5083 Al-alloy and 30CrMnSiA steel in NaCl solutions [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 883
	刘泉兵, 刘宗德, 郭胜洋等. 5083铝合金与30CrMnSiA钢在不同Cl^-浓度中电偶腐蚀行为的研究 [J]. 中国腐蚀与防护学报, 2021, 41: 883 doi: 10.11902/1005.4537.2020.184
[7]	Cui Z Y, Ge F, Wang X. Corrosion mechanism of materials in three typical harsh marine atmospheric environments [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 403
	崔中雨, 葛峰, 王昕. 几种苛刻海洋大气环境下的海工材料腐蚀机制 [J]. 中国腐蚀与防护学报, 2022, 42: 403 doi: 10.11902/1005.4537.2021.165
[8]	Wang S N, Gu Y H, Geng Y L, et al. Investigating local corrosion behavior and mechanism of MAO coated 7075 aluminum alloy [J]. J. Alloy. Compd., 2020, 826: 153976
[9]	Chen C Y, Yang J, Li J Q, et al. Effect of chloride ion concentration on corrosion behavior of 3003 aluminum alloy in simulated marine atmospheric environment [J]. Surf. Technol., 2015, 44(3): 116
	陈朝轶, 杨京, 李军旗等. 模拟海洋大气环境下Cl^-质量分数对3003铝合金腐蚀行为的影响 [J]. 表面技术, 2015, 44(3): 116
[10]	Yang H J, Gao Y M, Qin W C, et al. Investigation of corrosion behavior of 3003 aluminum alloy in flue gas condensate [J]. Mater. Corros., 2017, 68: 664
[11]	Iwao S, Yoshino M, Edo M, et al. Corrosion behavior of alloy A3003 after brazing in HCl, CH₃COOH, and mixed solutions [J]. Corrosion, 2015, 71: 598
[12]	Yang X K, Zhang L W, Zhang S Y, et al. Properties degradation and atmospheric corrosion mechanism of 6061 aluminum alloy in industrial and marine atmosphere environments [J]. Mater. Corros., 2017, 68: 529
[13]	Yin M Y, Ma L Q, Wang J, et al. Effect of homogenizing treatment on the corrosion resistance of 3003 aluminum alloy ingot [J]. Spec. Cast. Nonferrous Alloys, 2012, 32: 775
	尹明勇, 马立群, 王娟等. 均匀化处理对3003铝合金铸锭耐蚀性的影响 [J]. 特种铸造及有色合金, 2012, 32: 775
[14]	Li Z, Zhang Z, Chen X G. Microstructure, elevated-temperature mechanical properties and creep resistance of dispersoid-strengthened Al-Mn-Mg 3xxx alloys with varying Mg and Si contents [J]. Mater. Sci. Eng., 2017, 708A: 383
[15]	Wang N G, Wang R C, Feng Y, et al. Discharge and corrosion behaviour of Mg-Li-Al-Ce-Y-Zn alloy as the anode for Mg-air battery [J]. Corros. Sci., 2016, 112: 13
[16]	Xie Y M, Meng X C, Wang F F, et al. Insight on corrosion behavior of friction stir welded AA2219/AA2195 joints in astronautical engineering [J]. Corros. Sci., 2021, 192: 109800
[17]	Wang N G, Huang Y X, Liu J J, et al. AZ31 magnesium alloy with ultrafine grains as the anode for Mg-air battery [J]. Electrochim. Acta, 2021, 378: 138135
[18]	Cao Y X, Zou C J, Wang C J, et al. Effect of TiO₂ nanoparticles and SDBS on corrosion behavior of 3003 aluminum alloy in aqueous ethylene glycol containing chloride ions at high temperature [J]. J. Alloy. Compd., 2021, 873: 159820
[19]	Zhang Y G, Chen Y L, Bian G X, et al. Electrochemical behavior and corrosion mechanism of anodized 7B04 aluminum alloy in acid NaCl environments [J]. J. Alloy. Compd., 2021, 886: 161231
[20]	Wang Z B, Hu H X, Zheng Y G. Synergistic effects of fluoride and chloride on general corrosion behavior of AISI 316 stainless steel and pure titanium in H₂SO₄ solutions [J]. Corros. Sci., 2018, 130: 203
[21]	Zhan D D, Wang C, Qian J Y, et al. Effect of trace Cl^- and Cu²⁺ ions on corrosion behavior of 3A21 Al-alloy in ethylene glycol coolant [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 383
	战栋栋, 王成, 钱吉裕等. 痕量Cl^-和Cu²⁺对3A21铝合金在乙二醇冷却液中腐蚀行为的影响 [J]. 中国腐蚀与防护学报, 2021, 41: 383 doi: 10.11902/1005.4537.2020.082
[22]	Romanoff M. Underground Corrosion [M]. Washington: U.S. Government Printing Office, 1957
[23]	Gu Y F, Ma M M, Li J, et al. Effect of annealing on corrosion property of aluminum/steel dissimilar metal fusion-brazed joint [J]. Trans. China Weld. Inst., 2017, 38(12): 46
	顾玉芬, 马敏敏, 李杰等. 焊后退火对铝/钢异种金属熔钎焊接头腐蚀性能的影响 [J]. 焊接学报, 2017, 38(12): 46
[24]	Zhang B. Research on the adaptability of weathering prevention technology in earthen sites under different climatic conditions [D]. Lanzhou: Lanzhou University, 2021
	张博. 不同气候环境下土遗址防风化技术适应性研究 [D]. 兰州: 兰州大学, 2021

[1]	YANG Haiyun, LIU Chunquan, XIONG Fen, CHEN Minna, XIE Yuelin, PENG Longsheng, SUN Sheng, LIU Haizhou. Research Progress on Preparation of Corrosion-resistant Coatings by Extreme High-speed Laser Material Deposition[J]. 中国腐蚀与防护学报, 2024, 44(4): 847-862.
[2]	WANG Yuxue, ZHU Aohong, WANG Liwei, CUI Zhongyu. Comparative Study on Corrosion Behavior of Two Novel Ni-Cr-Mo-V Steels in Simulated Seawater Environment[J]. 中国腐蚀与防护学报, 2024, 44(4): 918-926.
[3]	HE Jiaxuan, ZHANG Yutong, GUAN Xudong, TANG Jianhua, HUANG Hai, ZHAO Xuhui, TANG Yuming, ZUO Yu. Present Status and Progress of Corrosion Protection for Microchannel Heat Exchangers of Al-alloy[J]. 中国腐蚀与防护学报, 2024, 44(4): 993-1000.
[4]	ZHANG Chenglong, ZHANG Bin, ZHU Min, YUAN Yongfeng, GUO Shaoyi, YIN Simin. Corrosion Behavior of Medium Entropy CoCrNi-alloy in NH₄Cl Solutions[J]. 中国腐蚀与防护学报, 2024, 44(3): 725-734.
[5]	DENG Zhibin, HU Xiao, LIU Yingyan, YUE Hang, ZHANG Qian, TANG Haiping, LU Rui. Effect of Magnetic Field on Corrosion Behavior of L360 Pipeline Steel and Welded Joints in 3.5%NaCl Solution[J]. 中国腐蚀与防护学报, 2024, 44(2): 471-479.
[6]	XIONG Yiming, MEI Wan, WANG Zehua, YU Rui, XU Shiyao, WU Lei, ZHANG Xin. Corrosion Behavior of 5083 Al-alloy under Magnetic Field[J]. 中国腐蚀与防护学报, 2024, 44(1): 229-236.
[7]	SONG Dongdong, WAN Hongxia, XU Dong, ZHOU Qian. Influence of Rolling on Corrosion Behavior of ZM5 Mg-alloy[J]. 中国腐蚀与防护学报, 2024, 44(1): 213-220.
[8]	ZHU Yesen, CAI Kun, HU Baowen, XIA Yunqiu, HU Taoyong, HUANG Yi. Research Progress on Characteristics and Prediction Models of Carbon Dioxide Induced Corrosion for Submarine Pipelines[J]. 中国腐蚀与防护学报, 2023, 43(6): 1225-1236.
[9]	QU Weiwei, CHEN Zehao, PEI Yanling, LI Shusuo, WANG Fuhui. Spreading and Corrosion Behavior of CMAS Melt on Different Materials for Thermal Barrier Coating[J]. 中国腐蚀与防护学报, 2023, 43(6): 1407-1412.
[10]	ZHONG Jiaxin, GUAN Lei, LI Yu, HUANG Jiayong, SHI Lei. Effect of Second Phase on Corrosion Behavior of Friction-stir-welded Joints of 2xxx Series Al-alloy[J]. 中国腐蚀与防护学报, 2023, 43(6): 1247-1254.
[11]	LIU Hao, GUO Xiaokai, WANG Wei, WU Liankui, CAO Fahe, SUN Qingqing. Effect of Ultrasonic Shot Peening on Microstructure and Properties of a 7075 Al-alloy Rod[J]. 中国腐蚀与防护学报, 2023, 43(6): 1293-1302.
[12]	HE Jing, YU Hang, FU Ziying, YUE Penghui. Effect of Water-soluble Corrosion Inhibitor on Corrosion Behavior of Q235 Pipeline Steel for Construction[J]. 中国腐蚀与防护学报, 2023, 43(5): 1041-1048.
[13]	WANG Yang, LIU Yuanhai, MU Xianlian, LIU Miaoran, WANG Jun, LI Qiuping, CHEN Chuan. Effect of Environmental Factors on Material Transfer in Thin Liquid Film During Atmospheric Corrosion Process in Marine Environment[J]. 中国腐蚀与防护学报, 2023, 43(5): 1015-1021.
[14]	REN Huangwei, LIAO Bokai, CUI Linjing, XIANG Tengfei. Effect of Liquid Film Thickness on Corrosion Behavior of Solid Slippery Surface under Thin Liquid Film[J]. 中国腐蚀与防护学报, 2023, 43(4): 862-870.
[15]	WANG Honglun, YANG Hua, CAI Hui, LI Bowen. Corrosion Behavior of Q235 Steel by Outdoor Exposure and under Shelter in Atmosphere of Hainan Coastal[J]. 中国腐蚀与防护学报, 2023, 43(3): 677-682.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed