Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900oC

doi:10.11902/1005.4537.2023.037

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 100-106 DOI: 10.11902/1005.4537.2023.037

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Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900^oC

FENG Kangkang, REN Yanjie(

), LV Yunlei, ZHOU Mengni, CHEN Jian, NIU Yan(

)

Department of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410076, China

Cite this article:

FENG Kangkang, REN Yanjie, LV Yunlei, ZHOU Mengni, CHEN Jian, NIU Yan. Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900^oC. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 100-106.

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Abstract

The oxidation behavior of Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, mass fraction, %) alloys were studied in 1 atm O₂ at 900^oC for 24 h. After oxidation, Fe-20Ni-20Cr alloy without Si addition formed a complex oxide scale on the surface with poor protectiveness. When the Si content increased from 1% to 3%, a transition from internal to external oxidation of Si occurred. Therefore, additions of Si can significantly improve the oxidation resistance of the austenitic Fe-20Ni-20Cr alloy. Both Fe-20Ni-20Cr-3Si and Fe-20Ni-20Cr-5Si formed an amorphous SiO₂ layer on the Cr₂O₃/alloy interface, and this continuous amorphous SiO₂ layer provided an effective barrier to prevent the outward diffusion of Fe, Ni and Cr, as well as the inward migration of oxygen. A comparison of the oxidation behavior of alloys with different Si contents indicated that Fe-20Ni-20Cr-3Si has the most excellent oxidation resistance properties.

Key words: Fe-Ni-Cr-Si alloy silicon high temperature oxidation oxidation kinetics

Received: 19 February 2023 32134.14.1005.4537.2023.037

ZTFLH:

TG172

Fund: National Natural Science Foundation of China(52171066)

Corresponding Authors: REN Yanjie, E-mail: yjren@csust.edu.cn
NIU Yan, yniu@csust.edu.cn

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	FENG Kangkang
	REN Yanjie
	LV Yunlei
	ZHOU Mengni
	CHEN Jian
	NIU Yan

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.037 OR https://www.jcscp.org/EN/Y2024/V44/I1/100

Table 1 Nominal and ICP-OES determined compositions of Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, %) alloys

Fig.1 Linear (a, c) and parabolic (b, d) plots of oxidation kinetic curves of Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, %) alloys in 1atm O₂ at 900^oC for 24 h

Table 2 Parabolic rate constants of the oxidation kinetics of Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, %) alloys in 1 atm O₂ at 900^oC for 24 h (g²·cm^-4·s^-1)

Fig.2 General (a) and enlarged (b) SEM/BEI views of the cross section of Fe-20Ni-20Cr oxidized in 1 atm O₂ at 900℃ for 24 h, XRD pattern (c) and EDS maps in the selected area in Fig.2b (d)

Fig.3 SEM micrograph of the cross section of Fe-20Ni-20Cr-1Si oxidized in 1 atm O₂ at 900^oC for 24 h (a), and corresponding EDS elemental maps of the selected area in Fig.3a (b)

Fig.4 SEM micrograph of the cross section of Fe-20Ni-20Cr-3Si oxidized in 1 atm O₂ at 900^oC for 24 h (a) and EDS elemental scannings of the selected area in Fig.4a (b)

Fig.5 Micrographs of the cross section of Fe-20Ni-20Cr-5Si alloy oxidized in 1 atm O₂ at 900^oC for 24 h: (a) general view, (b) enlarged view of the selected area in Fig.5a

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