Oxidation Kinetics of 9Ni Steel Billet at High Temperature

doi:10.11902/1005.4537.2022.261

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (4): 882-889 DOI: 10.11902/1005.4537.2022.261

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Oxidation Kinetics of 9Ni Steel Billet at High Temperature

GUO Tao, HUANG Feng(

), HU Qian, LIU Jing

State Key Laboratory of Refractories and Metallurgy, Hubei Engineering Technology Research Center of Marine Materials and Service Safety, Wuhan University of Science and Technology, Wuhan 430081, China

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Abstract

The oxidation behavior of 9Ni steel slab at 900~1250 ℃ were investigated by employing a combined thermal analysis and mass spectrometer system, field emission scanning electron microscopy (FE-SEM), field emission electron probe microscopy (FE-EPMA), X-ray diffractometer (XRD) and soft wear FactSage10.0. The results show that the constant temperature oxidation of 9Ni steel at 900-1250 ℃ mainly follows the parabolic law, and the oxidation rate is controlled by the diffusion of metallic ions in the oxide layer, Ni exists in the oxide layer in the form of FeNi₃ and NiFe₂O₄ in the inner layer, and elemental Ni enriched at the boundary of the inner/outer layers of the formed oxide scale, and intertangled with Fe-oxides, The high temperature corrosion at grain boundaries of 9Ni steel billet should be attributed to Fe₂SiO₄ (ferrosilicon olivine) which come from the combining of SiO₂ generated by Si oxidation and FeO of the product of iron oxidation, When the temperature is higher than the eutectic temperature (about 1170 ℃), ferrosilicon olivine will be irregularly permeated into austenite grain boundaries in the matrix as liquid.

Key words: 9Ni steel billet oxide sheet structure network structure high temperature grain boundary corrosion

Received: 22 August 2022 32134.14.1005.4537.2022.261

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(U21A20113)

Corresponding Authors: HUANG Feng, E-mail: huangfeng@wust.edu.cn

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Cite this article:

GUO Tao, HUANG Feng, HU Qian, LIU Jing. Oxidation Kinetics of 9Ni Steel Billet at High Temperature. Journal of Chinese Society for Corrosion and protection, 2023, 43(4): 882-889.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.261 OR https://www.jcscp.org/EN/Y2023/V43/I4/882

Fig.1 Structure of 9Ni steel billet

Fig.2 Isothermal ternary phase diagrams of FeO-SiO₂-NiO (a) and Fe₂O₃-SiO₂-NiO (b) (1250 ℃, 10⁵ Pa)

Fig.3 Oxidation kinetics curves of 9Ni steel billet at different temperatures

Fig.4 Cross-sectional morphologies and corresponding element mappings of the oxide scales formed on 9Ni steel billet after oxidation for 2 h at 900 ℃ (a), 1000 ℃ (b), 1100 ℃ (c), 1150 ℃ (d), 1200 ℃ (e) and 1250 ℃ (f)

Fig.5 Cross-sectional morphologies of the inner oxide layers of 9Ni steel billet after oxidation for 2 h at 900 ℃ (a), 1000 ℃ (b), 1100 ℃ (c), 1150 ℃ (d), 1200 ℃ (e) and 1250 ℃ (f)

Fig.6 EPMA element mappings of the cross section of the inner oxide layer of 9Ni steel billet after oxidation at 1250 ℃ for 2 h

Fig.7 Secondary electron image (a) and EDS analysis results of element contents in the marked points in Fig.7a (b-f) of the inner oxide layer of 9Ni steel billet after oxidation at 1250 ℃ for 2 h

Fig.8 XRD patterns of 9Ni steel billet oxidized for 2 h at 900-1100 ℃ (a) and 1150-1250 ℃ (b)

Fig.9 Square diagram of oxidized mass gain of 9Ni steel billet at different temperatures

Fig.10 Oxidation activation energy of 9Ni steel billet in air at 900-1250 ^oC

Fig.11 High temperature oxidation mechanism of 9Ni steel billet

Fig.12 Schematic diagram of high temperature intergranular corrosion

1	Bai J B, Dong H Q, Zhu H B, et al. Development status of 9Ni steel and welding materials [J]. Electr. Weld. Mach., 2021, 51 (4): 57
	白建斌, 董海青, 朱海滨等. 9Ni钢及其焊材发展现状 [J]. 电焊机, 2021, 51(4)： 57
2	Chen S P, Li Z. Analysis and discussion about 9Ni steel applied in LNG tank [J]. Chem. Equip. Technol., 2009, 30(6)： 40
	陈社鹏, 李臻. 9Ni钢在LNG储罐中的应用分析与探讨 [J]. 化工装备技术, 2009, 30(6): 40
3	Pan T, Zhu J, Yang C F, et al. Kinetics simulation and experimental observation of fine microstructure of 9% Ni cryogenic steel processed by QLT heat treatment [J]. Chin. Sci. Bull., 2014, 59: 1765 doi: 10.1007/s11434-014-0139-3
4	Wu D Y, Han X L, Tian H T, et al. Microstructural characterization and mechanical properties analysis of weld metals with two Ni contents during post-weld heat treatments [J]. Metall. Mater. Trans., 2015, 46A: 1973
5	Li Z H, Fan X F, Gong R Z, et al. Effect of heat treatment on low temperature toughness of 9Ni steel [J]. Mech. Eng., 2018, (3): 86
	李志海, 樊湘芳, 龚仁政等. 热处理对9Ni钢低温韧性的影响 [J]. 机械工程师, 2018, (3)： 86
6	Geng D D, Yan C Y, Na X Y, et al. Analysis on 9Ni steel used for LNG store tank and its weldability [J]. Welded Pipe Tube, 2015, (5): 5
	耿都都, 严春妍, 纳学洋等. LNG储罐用9Ni钢及其焊接性分析 [J]. 焊管, 2015, (5): 5
7	Li F. Sensitivity analysis of welding cold crack in 9%Ni steel [J]. Locomot. Roll. Stock Technol., 2010, (2): 13
	李福. 9%Ni钢的焊接冷裂纹敏感性分析 [J]. 机车车辆工艺, 2010, (2): 13
8	Otsuka N, Fujikawa H. Scaling of austenitic stainless steels and nickel-base alloys in high-temperature steam at 973 K [J]. Corrosion, 1991, 47: 240 doi: 10.5006/1.3585251
9	Fukagawa T, Okada H, Maehara Y. Mechanism of red scale defect formation in Si-added hot-rolled steel sheets [J]. ISIJ Int., 1994, 34: 906 doi: 10.2355/isijinternational.34.906
10	Cao G M, Gao X Y, Shan W C, et al. High temperature oxidation behavior of Ni-based low temperature steel [J]. J. Northeastern Univ. (Nat. Sci.), 2020, 41: 792
	曹光明, 高欣宇, 单文超等. Ni系低温钢的高温氧化行为研究 [J]. 东北大学学报 (自然科学版), 2020, 41: 792
11	Liu Y Z, Yang C F, Chai F, et al. High temperature oxidation resistance of 9Ni steel [J]. J. Iron Steel Res. Int., 2014, 21: 956 doi: 10.1016/S1006-706X(14)60168-0
12	Zhang H. Study on the microstructures and formation mechanism of oxide film of low alloy steel [D]. Shenyang: Northeastern University, 2010
	张欢. 低合金钢表面氧化膜的形成及显微结构的研究 [D]. 沈阳: 东北大学, 2010
13	Zhu G J. An Example of an Application of the Transmission Principle [M]. Beijing: Metallurgical Industry Press, 2017
	朱光俊. 传输原理应用实例 [M]. 北京: 冶金工业出版社, 2017
14	Hu Y B. Analysis on the relationship between oxidation kinetics and oxide film structure evolution of the nickel-based superalloy [D]. Dalian: Dalian University of Technology, 2019
	胡叶兵. 镍基高温合金氧化动力学与氧化膜结构的演化规律关系研究 [D]. 大连: 大连理工大学, 2019
15	Zhang Q, Liang T S, Wang W, et al. Oxidation kinetics and microstructure evolution of nanocrystalline Ni-12Cr alloy at 800 ℃ [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 733
	张勤, 梁涛沙, 王文等. 纳米晶Ni-12Cr合金800 ℃高温氧化动力学和氧化膜结构演化 [J]. 中国腐蚀与防护学报, 2022, 42: 733
16	Song Z Q, Li Z Q, Zheng X D, et al. Oxidation kinetics and interfacial bonding properties of Ni-Co based superalloys [J]. J. Cent. South Univ. (Sci. Technol.), 2019, 50: 1537
	宋正奇, 李志强, 郑绪东等. 镍钴基高温合金的氧化动力学与界面结合性能 [J]. 中南大学学报 (自然科学版)， 2019, 50: 1537
17	Zhang K, Wu H B, Tang D. High temperature deformation behavior of Fe-9Ni-C alloy [J]. J. Iron Steel Res. Int., 2012, 19: 58 doi: 10.1016/S1006-706X(12)60100-9
18	Xie L P, Chen M H, Wang J L, et al. High temperature oxidation behavior of ultrafine grained ODS nickel-based superalloy prepared by spark plasma sintering [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 709
	解磊鹏, 陈明辉, 王金龙等. 放电等离子烧结超细晶ODS镍基合金的高温氧化行为研究 [J]. 中国腐蚀与防护学报, 2022, 42: 709 doi: 10.11902/1005.4537.2021.237
19	Zhang Y D, Jin S B, Jiang C L, et al. Formation of high-temperature inner oxide scale on low alloy steels: Segregation, partitioning and transformation reactions [J]. Corros. Sci., 2022, 195: 109980 doi: 10.1016/j.corsci.2021.109980
20	Li D H, Chen J X, Etim I P, et al. High temperature oxidation behavior of Ni-based superalloy Nimonic95 and the effect of pre-oxidation treatment [J]. Vacuum, 2021, 194: 110582 doi: 10.1016/j.vacuum.2021.110582
21	Li T F. The role of metallic grain boundary in high temperature oxidation [J]. J. Chin. Soc. Corros. Prot., 2002, 22: 180
	李铁藩. 金属晶界在高温氧化中的作用 [J]. 中国腐蚀与防护学报, 2002, 22: 180
22	Yuan Q. Research on the high-temperature oxidation behavior of low carbon silicon-containing steels and the formation mechanism of net-like Fe₂SiO₄/FeO [D]. Wuhan: Wuhan University of Science and Technology, 2019
	袁清. 低碳含Si钢高温氧化行为及网格状Fe₂SiO₄/FeO形成机理研究 [D]. 武汉: 武汉科技大学, 2019

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