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MICRO-DROPLETS PHENOMENON AND ATMOSPHERIC CORROSION—— Ⅲ. Spreading behaviors of micro-droplets under cyclic wet-dry conditions |
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广东海洋大学海洋资源与环境监测中心 |
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Abstract In this paper, the spreading behaviors of micro-droplets with and without the electrochemical polarization were investigated under the cyclic wet-dry conditions of 50% RH and 90% RH at 25℃. The results indicated that there was unobvious influence of the wet-dry cycles on the formation and spreading of micro-droplets in a condition without the electrochemical polarization. Under the external polarization, with the advance of the wet-dry cycles, the areas covered with micro-droplets alternately expanded and dwindled, and the polarization current Ip and polarization resistance Rp changed impulsively. The maximum of Ip in each cycle increased gradually with the increase of the wet-dry cycles and the corresponding maximum of Rp followed a reverse changing rule. Under cyclic wet-dry conditions, it showed a closed relation between the spreading of micro-droplets and corrosion current. They were influenced and promoted with each other.
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Received: 26 September 2006
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[1]Evans U R.Trans.by Hua B D.Corrosion and Oxidation of Metals[M].Beijing:China Machine Press,1976,401-430(Evans U R著.华保定译.金属的腐蚀与氧化[M].北京:机械工业出版社,1976,401-430) [2]Yadav A P,Nishikata A,Tsuru T.Electrochemical impedance study on galvanized steel corrosion under cyclic wet-dry condi-tions-influence of time of wetness[J].Corros.Sci.,2004,46:169-181 [3]Corvo F,Mendoza A R,Autie M,et al.Role of water adsorption and salt content in atmospheric corrosion products of steel[J].Corros.Sci.,1997,39:815-820 [4]Wang J.Role of salt particle deposition in the initiation and prop-agation of atmospheric corrosion[J].J.Chin.Soc.Corros.Prot.,2004,24(3):155-158.(王佳.无机盐微粒沉积和大气腐蚀的发生和发展[J].中国腐蚀与防腐学报,2004,24(3):155-158) [5]Thiel P A,Madey T E.The interaction of water with solid sur-faces:fundamental aspects[J].Surf.Sci.Rep.,1987,7:211-385 [6]Stratmann M,Streeckel H.On the atmospheric corrosion of metalswhich are covered with thin electrolyte layers[J].Corros.Sci.,1990,30:681-714 [7]Wang J,Tsuru T.Potential distribution and micro-droplets forma-tion on the metal with salt particle deposition[A].The 204th Meeting of the Electrochemical Society[C].Orlando 2003,472 [8]Tsuru T,Tamiya K I,Nishikata A.Formation and growth of mi-cro-droplets during the initial stage of atmospheric corrosion[J].Electrochim.Acta,2004,49:2709-2715 [9]Zhang J B,Wang Y H,Jiang Y L,et al.Micro-droplets phe-nomenon and atmospheric corrosion-Ⅰ.Formation and spreadingof micro-droplets[J].J.Chin.Soc.Corros.Prot.,2006,26(4):207-210(张际标,王燕华,姜应律等.微液滴现象与大气腐蚀-Ⅰ.微液滴的形成与扩展[J].中国腐蚀与防护学报,2006,26(4):207-210) [10]Zhang J B,Wang Y H,Jiang Y L,et al.Micro-droplets phe-nomenon and atmospheric corrosion-Ⅱ.Electrochemical charac-teristics of the micro-droplets phenomenon[J].J.Chin.Soc.Cor-ros.Prot.,2006,26(5):282-285(张际标,王燕华,姜应律等.微液滴现象与大气腐蚀-Ⅱ.微液滴的电化学表征[J].中国腐蚀与防护学报,2006,26(5):282-285) |
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