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INHIBITION OF PROPARGYL ALCOHOL ON IRON CORROSION IN h2s-CONTAINING SULFURIC ACID SOLUTIONS |
Lijing Yan;; |
中科院金属腐蚀与防护研究所 电化学室 |
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Abstract The inhibition of propargyl alcohol (PA) on iron corrosion in H2S-containing sulfuric acid solutions has been studied using electrochemical potentiodynamic polarization method and impedance measurements.The results showed that PA could greatly retard the corrosion of iron in sulfuric acid containing H2S, which was attributed mainly to the inhibition effect of PA on the anodic dissolution reaction of iron.It wa also found that PA performed its function effectively when the temperature of solution wa between 30℃ to 65℃.However,the ingibition effect of PA decreased enormously ofr the temperature higher than 65℃.In addition,a polymer film of PA could gradually form on iron surface,and its protective ability was related with the surface state of corroded iron.H2S could influence the polymerization of PA and damage the comeatibility and integrity of the polymer.
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Received: 13 October 1998
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Corresponding Authors:
Lijing Yan
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1 RoselliME ,SanchezMA ,MacciEM ,PodestaJJ.Corros.Sci.,1 990 ,3 0 :1 59 2 YangB ,SmartNG ,BockrisJO′M .Electrochim .Acta .,1 992 ,3 7:3 1 7 3 FiaudC ,HarchA ,MallouhD ,TzinmannM .Corros.Sci.,1 993 ,3 5:1 43 7 4 AramakiK ,FujiokaE .Corrosion ,1 996,52 :83 5 KutejP ,VostaJ,PancirandJ ,HackermanN .J.Electrochem .Soc.,1 995,1 42 :1 84 7 6 PauscherA ,KutsanG ,LukacsZ .Corros.Sci.,1 993 ,3 5:1 42 5 7 曹楚南 .腐蚀科学与防护技术 ,1 990 ,2 :1 8 曹楚南 .腐蚀电化学 ,化学工业出版社 ,1 994 .p .1 3 0 9 BockrisJO′M ,YangB .J.Electrochem .Soc .,1 991 ,1 3 8:2 2 3 7 1 0 BartosM ,HackermanN .J.Electrochem .Soc.,1 992 ,1 3 9:3 42 8 1 1 闫丽静 ,牛 林 ,林海潮 ,吴维 .化学学报 ,1 998,56:1 0 55 |
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