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Journal of Chinese Society for Corrosion and protection  2025, Vol. 45 Issue (1): 103-114    DOI: 10.11902/1005.4537.2024.153
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Effect of Hydrostatic Pressure on Corrosion Behavior of Cr/GLC Laminated Coating
MA Hongyu1,2, LIU Rui1, CUI Yu2(), KE Peiling3, LIU Li1, WANG Fuhui1
1 Corrosion and Protection Center, Northeastern University, Shenyang 110819, China
2 Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 Public Technology Center, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
Cite this article: 

MA Hongyu, LIU Rui, CUI Yu, KE Peiling, LIU Li, WANG Fuhui. Effect of Hydrostatic Pressure on Corrosion Behavior of Cr/GLC Laminated Coating. Journal of Chinese Society for Corrosion and protection, 2025, 45(1): 103-114.

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Abstract  

The corrosion behavior of laminated coating chromium/graphite-like amorphous carbon (Cr/GLC) on 431 stainless steel in 3.5%NaCl solution by applied hydrostatic pressures ranging 0.1 MPa to 15 MPa was investigated by in-situ electrochemical measurements, scanning electron microscopy (SEM) and secondary ion mass spectrometry (SIMS). The results showed that high hydrostatic pressure may accelerate the corrosion failure of laminated coating Cr/GLC. Hydrostatic pressure significantly increases the corrosion current density of laminated coating Cr/GLC, promotes Cl- adsorption on the coating surface and inward to the coating/metal substrate interface, thereby decreases the interface bonding strength of coating/metal substrate.
Key words:  Cr/GLC laminated coating      hydrostatic pressure      electrochemical measurement      corrosion     
Received:  16 May 2024      32134.14.1005.4537.2024.153
ZTFLH:  TG174  
Fund: A-class pilot of Chinese Academy of Sciences(XDA22010303)
Corresponding Authors:  CUI Yu, E-mail: ycui@imr.ac.cn
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MA Hongyu
LIU Rui
CUI Yu
KE Peiling
LIU Li
WANG Fuhui

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.153     OR     https://www.jcscp.org/EN/Y2025/V45/I1/103

Fig.1  Simulated deep-sea environment system[30]
Fig.2  Surface (a) and cross-sectional (b) morphologies of Cr/GLC laminated coating, and the growth of nodules on the coating surface (c) and EDS elemental line scanning (d)
Fig.3  Surface morphologies of multilayer Cr/GLC laminated coating after immersion for 48 h (a, b) and 168 h (c, d) at 0.1 MPa (a, c) and 15 MPa (b, d)
Fig.4  Cross-sectional morphologies of Cr/GLC laminated coating after immersion for 48 h (a, b) and 168 h (c, d) at 0.1 MPa (a, c) and 15 MPa (b, d)
Fig.5  Bode plots of Cr/GLC laminated coating after immersion for different time at 0.1 MPa (a-c) and 15 MPa (d-f)
Time / hRs / Ω·cm2Rf / Ω·cm2nfQf / F·cm-2Rdl / Ω·cm2ndlQdl / F·cm-2
0.514.175.32 × 1050.934.36 × 10-64.59 × 1060.929.28 × 10-7
413.975.52 × 1050.944.46 × 10-64.86 × 1060.919.38 × 10-7
813.637.37 × 1050.944.03 × 10-67.67 × 1060.929.54 × 10-7
1214.159.55 × 1050.944.08 × 10-61.05 × 1070.898.52 × 10-7
2414.731.18 × 1060.944.04 × 10-61.09 × 1070.906.71 × 10-7
3614.81.06 × 1060.954.27 × 10-66.51 × 1060.887.09 × 10-7
4812.568.64 × 1050.954.16 × 10-68.66 × 1060.866.73 × 10-7
7211.688.72 × 1050.954.25 × 10-69.13 × 1060.883.21 × 10-7
12010.497.99 × 1050.944.29 × 10-67.96 × 1060.786.42 × 10-7
15611.116.19 × 1050.924.55 × 10-66.37 × 1060.821.09 × 10-6
22813.315.46 × 1050.925.12 × 10-64.83 × 1060.811.19 × 10-6
27612.723.41 × 1050.925.60 × 10-61.22 × 1060.781.33 × 10-6
34810.925.51 × 1050.934.95 × 10-65.83 × 1060.846.98 × 10-7
48013.582.61 × 1050.925.60 × 10-61.08 × 1060.781.10 × 10-6
57612.25.37 × 1050.925.35 × 10-62.47 × 1060.731.04 × 10-6
61212.41.71 × 1050.925.75 × 10-61.01 × 1060.805.56 × 10-7
64813.311.38 × 1050.925.75 × 10-63.93 × 1050.731.09 × 10-6
72012.521.14 × 1050.915.82 × 10-63.60 × 1050.821.09 × 10-6
Table 1  Fitting parameters of EIS of Cr/GLC laminated coating immersed in 3.5%NaCl solution for different time at 0.1 MPa
Time / hRs / Ω·cm2Rf / Ω·cm2nfQf / F·cm-2Rdl / Ω·cm2ndlQdl / F·cm-2
29.485.29 × 1040.932.04×10-51.63 × 1050.838.29 × 10-6
69.405.21 × 1040.922.20×10-51.59 × 1050.778.09 × 10-6
810.495.35 × 1040.931.32×10-51.81 × 1050.783.84 × 10-6
109.415.28 × 1040.922.18×10-51.62 × 1050.811.28 × 10-5
248.504.54 × 1040.901.72×10-59.01 × 1040.752.81 × 10-5
309.425.00 × 1040.922.25×10-51.46 × 1050.812.58 × 10-5
489.344.07 × 1040.902.44×10-55.48 × 1040.788.09 × 10-6
969.273.94 × 1040.902.81×10-54.71 × 1040.793.36 × 10-5
1209.234.02 × 1040.892.95×10-55.42 × 1040.844.93 × 10-5
1329.078.85 × 1030.836.88×10-56.65 × 1040.931.49 × 10-4
1688.976.93 × 1020.781.65×10-48.47 × 1030.723.08 × 10-4
2408.986.11 × 1020.761.99×10-47.68 × 1030.732.93 × 10-4
3609.195.00 × 1020.772.02×10-45.58 × 1030.723.15 × 10-4
Table 2  Fitting parameters of EIS of Cr/GLC laminated coating immersed in 3.5%NaCl solution for different time at 15 MPa
Fig.6  Potentiostatic polarization curves of Cr/GLC laminated coating and 431 stainless steel in 3.5% NaCl solution at 0.1 MPa and 15 MPa
Fig.7  Depth profiles of various elements of Cr/GLC laminated coating immersed at 0.1 MPa (a) and 15 MPa (b), and distribution comparisons of O (c), Cl (d), Cr (e) and Fe (f)
Fig.8  Peak intensity ratios of Cr0.1 MPa and Cr15 MPa within Cr/GLC laminated coating immersed at 0.1 and 15 MPa
Fig.9  Scratch morphologies (a1-d1) and friction curves (a2-d2) of Cr/GLC laminated coating immersed at 0.1 MPa for 0 h (a), 48 h (b), 96 (c), and 168 h (d)
Fig.10  Scratch morphologies (a1-c1) and friction curv-es (a2-c2) of Cr/GLC laminated coating immer-sed at 15 MPa for 48 h (a), 96 h (b) and 168 h (c)
Fig.11  Variations of adhesion of Cr/GLC laminated coating immersed at 0.1 MPa and 15 MPa with immersion time
Fig.12  Schematic illustration of corrosion failure mechanism of Cr/GLC laminated coating
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