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Journal of Chinese Society for Corrosion and protection  2024, Vol. 44 Issue (4): 823-834    DOI: 10.11902/1005.4537.2023.294
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Research Progress on Hydrophobic Modification of Polyurethane Coatings
WANG Ting, GAO Kun, ZHONG Sainan, ZHANG Zhao()
Department of Chemistry, Zhejiang University, Hangzhou 310027, China
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WANG Ting, GAO Kun, ZHONG Sainan, ZHANG Zhao. Research Progress on Hydrophobic Modification of Polyurethane Coatings. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 823-834.

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Abstract  

Polymer coatings are of particular importance in corrosion and fouling protection of metallic materials in transport and infrastructure industries due to their advantages of low cost, easy preparation, convenient operation and rich variety. Among various polymer coatings, polyurethane (PU) coatings are widely used as surface protection materials for metallic facility because of their excellent mechanical property and strong resistance to abrasion, heat and corrosion. However, the presence of hydrophilic components in the formulation of PU coatings leads to a decrease in hydrophobicity, which seriously restricts their industrial application in humid environment. Therefore, many efforts have been made to develop new modification strategies for PU coatings in order to obtain stable hydrophobic coatings. The review aims to provide insight into the recent advances in hydrophobic PU coatings, and methods that have used to modify and design hydrophobic PU coatings are summarized. Also, the challenges and outlook of hydrophobic PU coatings are discussed.
Key words:  polyurethane      hydrophobicity      coating      corrosion protection     
Received:  15 September 2023      32134.14.1005.4537.2023.294
ZTFLH:  TG172  
Fund: National Natural Science Foundation of China(51771173)
Corresponding Authors:  ZHANG Zhao, E-mail: eaglezzy@zju.edu.cm
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WANG Ting
GAO Kun
ZHONG Sainan
ZHANG Zhao

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.294     OR     https://www.jcscp.org/EN/Y2024/V44/I4/823

Fig.1  Schematic illustration of the preparation of SiO2-FPEAU hydrophobic coatings[35]
Fig.2  Panel depicting representative images of the shapes of water droplets on Si-PUT films (a) and visible light transmittance and showcasing of the optical transparency of Si-PUTs films on glass slides (b)[45]
Fig.3  Water drops on the hybrid films and schematic representations of the effect of m-POSS content on the water wettability of the hybrid films[53]
Fig.4  Surface morphologies of nanocomposite films with 0% (a), 5% (b), 10% (c), 15% (d) and 20% (e) TMES modified nano SiO2[59]
Fig.5  Low (a, d) and high (b, e) magnification SEM images of the surface (a, b) and cross section (d, e) of ZnO@PUA，optical image of a static water droplet (5 µL) on ZnO@PUA (c), and schematic diagram of existing of ZnO nanoparticles in ZnO@PUA (f)[95]
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