Research Progress on Application of Functional Superhydrophobic Coatings for Anti-icing in Polar Regions

doi:10.11902/1005.4537.2023.046

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 1-14 DOI: 10.11902/1005.4537.2023.046

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Research Progress on Application of Functional Superhydrophobic Coatings for Anti-icing in Polar Regions

JIANG Bochen¹^,², LEI Yanhua¹(

), ZHANG Yuliang¹, LI Xiaofeng¹, LIU Tao¹(

), DONG Lihua¹

^1.College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
^2.School of Intelligent Manufacturing and Information, Jiangsu Shipping College, Nantong 226000, China

Cite this article:

JIANG Bochen, LEI Yanhua, ZHANG Yuliang, LI Xiaofeng, LIU Tao, DONG Lihua. Research Progress on Application of Functional Superhydrophobic Coatings for Anti-icing in Polar Regions. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 1-14.

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Abstract

With the development and utilization of polar routes and rich resources in polar regions, the ice covering of hull and all kinds of equipment of navigation ships brings serious safety risks to the safe navigation of polar ships. Thus, research of anti-icing coatings for polar ships and offshore equipment gradually becomes a hot research topic nowadays. Superhydrophobic coatings have excellent ice-resistance properties. However, its practical application is limited to some extent. This paper presents a review on the icing theory, the theoretical models of superhydrophobicicity, and the anti-icing properties of superhydrophobic interfaces. Then the application of superhydrophobic coatings with different preparation methods in the field of anti-icing is discussed and summarized. Finally, aiming at the shortcomings of superhydrophobic coating in deicing, the strategy of superhydrophobic coating with photothermal and electrothermal functions was proposed, and the current research status was comprehensively introduced.

Key words: anti-icing coating superhydrophobicity photothermal de-icing electrothermal de-icing polar region

Received: 24 February 2023 32134.14.1005.4537.2023.046

ZTFLH:

TG178

Fund: National Natural Science Foundation of China(41976039);Foundation of Shanghai Engineering Technology Research Centre of Deep Offshore Material(19DZ2253100)

Corresponding Authors: LEI Yanhua, E-mail: yhlei@shmtu.edu.cn
LIU Tao, E-mail: liutao@shmtu.eud.cn

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	JIANG Bochen
	LEI Yanhua
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	DONG Lihua

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.046 OR https://www.jcscp.org/EN/Y2024/V44/I1/1

Fig.1 Contact angle hysteresis on an inclined plane (a) and wetting theory model: (b) Young model, (c) Wenzel model, (d) Cassie-Baster model

Fig.2 Comparison of breakthrough energy barriers for uniform nucleation and non-uniform nucleation^[30]

Fig.3 Schematic diagram of the impact process of a water droplet (initial diameter D₀ = 2 mm, impact velocity V₀ = 1 m·s^-1) on a superhydrophobic surface^[39]

Fig.4 Optical images of ice formation process on smooth, nanostructured and micro-nanostructured metal surfaces^[42]

Table 1 Summary of preparation methods and performance characterization of superhydrophobic anti-ice coatings

Fig.5 Schematic diagram of the light-emitting thermogenic process of photothermal materials

Fig.6 ATP, PPY/ATP and PPY/ATP@hexadecylPOS coatings (a), their surface temperature changes with irradiation time under 1 sun (b) and the corresponding infrared images of the ATP (c), PPY (d), PPY/ATP (e)and PPY/ATP@hexadecylPOS (f) coatings at certain time intervals^[64]

Preparation method

Photothermal materials /

substrate

Delayed freezing time

Adhesion of ice

Photothermal performance

Citation

Heating temperature

under light

Ice melting time

under light

Other

performance

Laser etching and PFTS modification

Moth eye structure/Aluminum plate

1085 s vs 300 s

at -15^oC

The temperature rises to 80^oC in 300 s/ by 1 sun (0.1 W/cm²)

Melt the 10 mm ×

10 mm ice in 240 s

/by one sun

20 icing / deicing cycles, High durability and wear resistance

[65]

Electron beam vapor deposition

TiN,PTFE/Q234

78 s vs

20 s

at -10^oC

The temperature rises to 85^oC in 600 s/ by NIR irradiation,

808 nm, 0.1 mW/cm²

Melt the 25 mm ×

25 mm × 3 mm ice

in 50 s/ by NIR irradiation, 0.1 W/cm²

High temperature thermal stability, excellent corrosion resistance

[66]

Spraying method

SiC, SiO₂/

copper mesh

82 s vs

43 s

at -30^oC

1.66 kPa vs

5.87 kPa

The temperature rises to 48.3^oC in 60 s

/by NIR irradiation,

808 nm, 2.5 W/cm²

Melt the ice in

300 s/by NIR irradiation

(2.5 W/cm²)

High heat conversion efficiency, high flexibility and wear resistance

[67]

Spraying method

Melanin nanoparticles/glass

144 s vs

63 s

at -20^oC

25.65 kPa vs

104.13 kPa

The temperature rises to 68.5^oC in 600 s

/by 1 sun

(0.1 W/cm²)

Melt the 3 mm thick ice in 600 s/by one sun (0.1 W/cm²)

10 icing /

deicing cycles

[68]

Spraying method

FMWCNTs/Aluminum plate

364 s vs

23 s

at -10^oC

The temperature rises to 55.7^oC in 600 s

/by 1 sun (0.1 W/cm²)

Melt the 2 mm thick ice in 900 s/by one sun (0.1 W/cm²)

Photothermal self - healing performance, high heat conversion efficiency

[69]

Spraying method

SiO₂/SiC/

EVA Plate

152 s vs

29 s

at -30^oC

4.42 kPa vs

52.17 kPa

The temperature rises to 315^oC in 10 s /by NIR

(808 nm)

Melt the 25 mm ×

35 mm × 3 mm ice

in 180 s /by NIR

(808 nm)

5 icing /

deicing cycles

[70]

Spraying method

SiC/CNTs/

EVA Plate

66 s vs

15 s

at -30^oC

2.65 kPa

25.65 kPa

The temperature rises to 172.6^oC in 60 s /by NIR (808 nm)

Melt the 25 mm ×

45 mm × 30 mm ice in 250 s/by NIR

(808 nm)

high heat conversion efficiency

[71]

Spraying method

Fe₃O₄ /

glass

2878 s vs 50 s

at -15^oC

213.7 kPa vs

399.9 kPa

The temperature rises to 38^oC in 300 s

/by fluorescent lamp

(75 W)

Melt the ice in

232 s/by fluorescent lamp (75 W)

10 icing /

deicing cycles

[72]

Table 2 Summary of performance characterization of photothermal superhydrophobic anti-icing coatings

Fig.7 Schematic diagram of Joule heat transfer

Fig.8 Schematic diagram of electrothermal deicing for FSGF-T200 film (a), Joule heating profile of the FSGF-T200 under different applied voltages (b), infrared images (c), defrosting (d) and deicing (e) process of the FSGF-T200 after applying a DC voltage of 15 V^[86]

Fig.9 Photothermal, electro-thermogenic, photo- & electro-thermal process (a) and magnetothermal process (b) of coatings

Fig.10 Light heating curves of the PESC coating at different applied light intensities (a), Joule heating profile at different applied voltages (b), heat generation curve under different light intensity applied at 9.0 V voltage (c), infrared images at different voltages and light intensities (d), water droplet icing process and infrared diagram at different applied voltages and light intensity^[88]

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