Application of Electrochemical Frequency Modulation for Study of Q235 Steel Corrosion in NaCl Solution

doi:10.11902/1005.4537.2014.009

Journal of Chinese Society for Corrosion and protection

2014, Vol. 34

Issue (5): 445-450 DOI: 10.11902/1005.4537.2014.009

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Application of Electrochemical Frequency Modulation for Study of Q235 Steel Corrosion in NaCl Solution

ZHOU Nianguang, ZHA Fanglin(

), FENG Bing, HE Tiexiang

Hunan Electric Power Corporation Research Institute, Changsha 410007, China

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Abstract

The influence of main parameters on the measurement results of electrochemical frequency modulation (EFM) and the deviation of causality factors from their theoretical values were analyzed. Then the accuracy of corrosion rate measured by EFM for Q235 steel in NaCl solution was comparatively checked by means of measurements with EIS, linear-potentiodynamic technique and weight-loss method. The results show that great error will be introduced when the base frequency is too high; 0.01 Hz is a proper base frequency for Q235 steel in NaCl solution. Causality factor CF2 is much reliable than CF3 for checking the accuracy of EFM measurement. R_p value measured by EFM is much accurate than that by linear-potentiodynamic technique; in comparison with weight-loss method, EFM is a rapid and accurate method for measuring corrosion rate.

Key words: EFM base frequency causality factor corrosion rate polarization resistance

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Cite this article:

ZHOU Nianguang, ZHA Fanglin, FENG Bing, HE Tiexiang. Application of Electrochemical Frequency Modulation for Study of Q235 Steel Corrosion in NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2014, 34(5): 445-450.

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https://www.jcscp.org/EN/10.11902/1005.4537.2014.009 OR https://www.jcscp.org/EN/Y2014/V34/I5/445

Fig.1 EFM spectrograms of Q235 steel in 0.5 mol/L NaCl solution at 0.01 and 0.1 Hz base frequency

Fig 2 Bode (a) and Nyquist (b) diagrams of Q235 steel in 0.5 mol/L NaCl solution

Fig.3 Equivalent circuit of Q235 in 0.5mol/L NaCl solution

Table 1 Main impedance parameters of Q235 steel in 0.5 mol/L Nacl solution

Fig.4 Linear polarization curves of Q235 steel at different corrosion time

Fig.5 Comparison of R_p curves measured by EIS, LPD and EMF

Fig.6 EFM spectrograms of Q235 steel corroded for 17 h (a), 163 h (b) and 353 h (c)

Table 2 EFM results of Q235 steel corroded for different time

Fig.7 Linear fitting of corrosion rate curve measured by EFM

Fig.8 Linear fitting of corrosion rate curves measured by EIS and LPD

Fig.9 Comparison of Q235 steel's corrosion rate measured by EFM, weight-loss method, EIS and LPD

[1]	Bosch R W, Bogaerts W F. Instantaneous corrosion rate measurement with small-amplitude potential intermediation techniques[J]. Corrosion, 1996, 52: 204-211
[2]	Bosch R W, Hubrecht J, Bogaerts W F, et al. Electrochemical frequency modulation: a new electrochemical technique for online corrosion monitoring[J]. Corrosion, 2001, 57: 60-70
[3]	Abdel-Rehim S S, Khaled K F, Abd-Elshafi N S. Electrochemical frequency modulation as a new technique for monitoring corrosion inhibition of iron in acid media by new thiourea derivation[J]. Electrochim. Acta, 2006, 51: 3269-3277
[4]	Mansfeld F. The use of electrochemical techniques for the investigation and monitoring of microbiologically influenced corrosion and its inhibition-a review[J]. Mater. Corros., 2003, 54: 489-495
[5]	Al-Mobarak N A, Khaled K F, Hamed M N H, et al.Employing electrochemical frequency modulation for studying corrosion and corrosion inhibitor of copper in sodium chloride solutions[J]. Arabian J.Chem., 2011, 4: 185-193
[6]	Javaherdashti R.Impact of sulphate-reducing bacteria on the performance of engineering materials[J]. Appl. Microbiol. Biotechnol., 2011, 91: 1507-1513
[7]	Rauf A, Bogaerts W F. Employing electrochemical frequency modulation for pitting corrosion[J]. Corros. Sci., 2010, 52: 2773-2784
[8]	Rauf A, Bogaerts W F, Mahdi E. Implementation of electrochemical frequency modulation to analyze stress corrosion cracking[J]. Corrosion, 2012, 68: 352-363
[9]	Khaled K F.Evaluation of electrochemical frequency modulation as a new technique for monitoring corrosion and corrosion inhibitor of carbon steel in perchloric acid using hydrazine carbodithioic acid deriwatives[J]. J. Appl. Electrochem., 2009, 39: 429-438
[10]	Kus E, Mansfeld F. An evaluation of the electrochemical frequency modulation (EFM) technique[J]. Corros. Sci., 2006, 48: 965-979
[11]	Beese P, Venzlaff H, Srinivasan J, et al. Monitoring of anaerobic microbially influenced corrosion via electrochemical frequency modulation[J]. Elctrochim. Acta, 2013, 105: 239-247
[12]	Rauf A, Bogaerts W F. Monitoring of crevice corrosion with the electrochemical frequency modulation technique[J]. Electrochim.Acta, 2009, 54: 7357-7363
[13]	Zhao X D, Duan J Z, Wu S R, et al. Formation and transformation of surface corrosion products of Q235 steel influenced by sulfate-reducing bacteria in seawater[J]. J. Chin. Soc. Corros. Prot., 2008, 28(5): 299-302
	(赵晓栋, 段继周, 武素茹等.海水中硫酸盐还原菌作用下Q235钢表面腐蚀产物的形成和转化[J]. 中国腐蚀与防护学报, 2008, 28(5): 299-302)

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