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Corrosion Behavior of Steels Used in Making Crude Oil Distillation Unit in High Temperature Crude Oil Fractions |
HUANG Bensheng1, YIN Wenfeng2, WANG Xiaohong1, SHI Yijun1 |
1. College of Materials Science and Engineering, Southwest Petroleum University, Chengdu 610500, China; 2. Engineering Training Center, Southwest Petroleum University, Chengdu 610500, China |
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Abstract The corrosion behavior of four steels used in making crude oil distillation unit in high temperature crude oil fractions was studied in an autoclave to simulate the corrosive environment in atmospheric and vacuum distillation unit. The mass loss of the samples was measured and then the corrosion morphology was characterized by scanning electron microscopy. The result showed that the higher acid value, sulfur content and salt content of the crude oil resulted in much serious corrosiveness on 20 steel and the corrosiveness of the substances could be ranked as the desalted crude oil > the second atmospheric side-cut fraction > the first atmospheric side-cut fraction. Alloying elements Cr, Ni and Mo could help to improve the corrosion resistance of steels,and the corrosion resistance of the test steels could be ranked as 316 stainless steel > 304 stainless steel > 1Cr5Mo > 20 steel. The overall corrosion rate usually increased with increasing temperature, however, which could reach extreme value in certain range of temperature.
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Cite this article:
HUANG Bensheng,YIN Wenfeng,WANG Xiaohong,SHI Yijun. Corrosion Behavior of Steels Used in Making Crude Oil Distillation Unit in High Temperature Crude Oil Fractions. Journal of Chinese Society for Corrosion and protection, 2013, 33(5): 377-382.
URL:
https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2013/V33/I5/377
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[1] Su Y L. Progress in the application of process corrosion protection in atmospheric and vacuum distillation unit [J]. Chem. Ind. Eng. Prog., 2011, 30(S1): 1-6 (苏亚兰. 常减压蒸馏装置工艺防腐应用及进展 [J]. 化工进展,2011, 30(S1): 1-6) [2] Jing H M, Zheng Y G, Yao Z M, et al. Corrosion of naphthenic acid and control [J]. Petrochem. Corros. Prot., 1999, 16(1): 1-7 (敬和民, 郑玉贵, 姚志铭等. 环烷酸腐蚀及其控制 [J]. 石油化工腐蚀与防护, 1999, 16(1): 1-7) [3] Qu D R, Zheng Y G. High temperature naphthenic acid corrosion and sulphidic corrosion of Q235 and 5Cr1/2Mo steels in synthetic refining media [J]. Corros. Sci., 2006, 48(8): 1960-1985 [4] Messer B, Beaton M C, Tarleton B, et al. New theory for naphthenic acid corrosivity of athabasca oilsands crudes [A]. NACE Conference Corrosion/2004 [C]. New Orleans: 2004: 634-641 [5] Huang B S, Sang D H, Jiang Z Y, et al. Coupled erosive behavior of naphthenic acid and sulfur at high temperatures [J]. J. Mater. Eng., 2011, 9(9): 39-49 (黄本生, 桑东恒, 江仲英等. 高温下环烷酸与硫耦合腐蚀实验研究 [J]. 材料工程, 2011, 9(9): 39-49) [6] Kane R D, Cayard M S. A comprehensive study on naphthenic acid corrosion [A]. NACE Conference Corrosion/2002 [C]. Denver,2002: 555-560 [7] Omar Y. Influence of different sulfur compounds on corrosion due to naphthenicacid [J]. Fuel, 2005, 56(1): 97-104 [8] Craig H L. Naphthenic acid corrosion in the refinery [A]. NACE Conference Corrosion/95 [C]. Houston: 1995: 333-339 [9] Joerg G. Effect of organic chloride contamination of crude oil on refinery corrosion [A]. NACE Conference Corrosion/2000 [C]. Orlando: 2000: 694-670 [10] Magdy A M, Rehim S S, Hamza M M. Corrosion behavior of some austenitic stainless steels in chloride environments [J]. Mater. Chem. Phys., 2009, 40(1): 80-85 [11] Yao J S. Corrosion of chloride in continuous catalytic reformer and protection [J]. Petrochem. Corros. Prot., 2002, 19(1): 16-18 (姚金森. 催化重整装置氯腐蚀及防治 [J]. 石油化工腐蚀与防护, 2002, 19(1): 16-18) [12] Ren S K, Seng G, Shao P C, et al. Analysis of corrosive environment in crude oil refine processing containing sour [J]. Corros. Prot., 2006, 27(6): 306-307 (任世科, 盛刚, 邵鹏程等. 含硫原油加工过程腐蚀环境分析 [J]. 腐蚀与防护, 2006, 27(6): 306-307) [13] Hu Y, Cheng X Q, Zhou J L. Corrosion behavior of carbon steel and 321 stainless steel in naphthenic acid at high temperature [J]. Corros. Prot., 2010, 31(10): 775-777 (胡洋, 程学群, 周建龙等. 20碳钢和321不锈钢在高温环烷酸中的腐蚀行为 [J]. 腐蚀与防护, 2010, 31(10): 775-777) [14] Jing H M, Wu X Q, Zheng Y G, et al. Effect of mo content on the corrosion and erosion-corrosion of stainless steel in oil containing naphthenic acid [J]. Acta Metall. Sin., 2002, 38(10): 1067-1073 (敬和民, 吴欣强, 郑玉贵等. Mo含量对不锈钢在环烷酸介质中腐蚀与冲蚀的影响 [J]. 金属学报, 2002, 38(10): 1067-1073) [15] Zhai Y H, Dong Z H, Mu J Y, et al. Corrosion behavior of mild steel and stainless steel in heavy oil at high temperature [J]. Corros. Prot., 2006, 39(3): 52-74 (翟云皓, 董泽华, 母建益等. 碳钢和不锈钢在高温重质油中的腐蚀行为 [J]. 材料保护, 2006, 39(3): 52-74) [16] Dong Z H, He J B, Guo X P, et al. High temperature interactive corrosion of naphthenic acid and organic sulphide on Cr5Mo steel in synthetic refining mixture [J]. J. Chin. Soc. Corros. Prot., 2011, 31(3): 219-224 (董泽华, 何金杯, 郭兴蓬等. 环烷酸与有机硫对Cr5Mo钢高温腐蚀的交互作用研究 [J]. 中国腐蚀与防护学报, 2011, 31(3): 219-224) [17] Lou S S, Zuo Y, Chu X L, et al. Corrosion of several metallic materials in high acidic crude oil [J]. Corros. Sci. Prot. Technol., 2005, 17(3): 201-204 (娄世松, 左禹, 楚喜丽等. 几种材料在高酸值原油中的腐蚀 [J]. 腐蚀科学与防护技术, 2005, 17(3): 201-204) [18] Yu J F, Gan F X, Hao L, et al. High temperature naphthenic acid corrosion of steel in high tan refining media [J]. J. Chin. Soc. Corros. Prot., 2009, 29(6): 481-486 (余建飞, 甘复兴, 郝龙等. 碳钢和不锈钢在高温环烷酸介质中的腐蚀行为 [J]. 中国腐蚀与防护学报, 2009, 29(6): 481-486) [19] Chen B F, Yang Q M. Kinetics analysis of naphthenic acid corrosion to six different alloy steels [J]. Pet. Process. Petrochem., 2006, 37(5): 49-52 (陈碧凤, 杨启明. 六种材料环烷酸腐蚀的动力学分析 [J]. 石油炼制与化工, 2006, 37(5): 49-52) |
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