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EFFECT OF ROLLING TEMPERATURE ON MICROSTRUCTURE AND PERFORMANCES OF Al-Mg-Sn-Bi-Ga-In ALLOY ANODE |
LIANG Shuquan, ZHANG Yong, GUAN Dikai, TAN Xiaoping, TANG Yan, MAO Zhiwei |
School of Materials Science and Engineering,Central South University, Changsha 410083 |
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Abstract Modern testing techniques such as TEM, SEM, EDAX, Tafel curves, E-T curves and hydrogen collection test have been applied to analyze the effect of rolling temperature on the microstructure, electrochemical and anti-corrosion properties of Al-Mg-Sn-Bi-Ga-In alloy anode in alkaline solution (80℃, Na2SnO3+5 mol/L NaOH). The results show that when controlling the pass deformation at 40\%, with the increase of rolling temperature, the microstructure of Al alloy anode undergoes a process from disordered dislocations cell structure, subgrain structure to dynamic recrystallized structure. When the rolling temperature is 420℃, the Al alloy anode has the most negative electrode potential of about -1.48 V(vs•Hg/HgO) and the lowest hydrogen evolution rate of 0.1716 mL•cm-2•min-1 due to the uniform distribution of active elements and decrease of segregation phases in alloy. The optimum comprehensive performance of Al alloy anode has been obtained.
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Received: 23 February 2009
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Corresponding Authors:
zhiwei M AO
E-mail: cw04zhangyong@126.com
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