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ANTISEPSIS OF X70 STEEL IN WEAK ACIDIC SOLUTION WITH H2S |
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山东理工大学 |
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Abstract Antisepsis of cathodic protection with Zn as sacrifice anode to X70 steel in weak acidic solution with H2S was studied by means of static weight loss method and scanning electron microscope. And inhibitive effect of 4-hydroxy-2-mercapto-6-methyl-primidine(HMMP) to the corrosion of X70 steel under the same condition was investigated by means of electrochemical impedance spectroscopy and potentiodynamic polarization curves. The results show that the antiseptic result with Zn as sacriice anode to X70 steel in weak acidic solution with H2S is excellent. HMMP belongs to mixed inhibitors that mainly restrain the anodic process, the inhibition increases gradually with the increasing of its concentration within the range of concentration studied.
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Received: 02 September 2005
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[1]Li Y T,Du Z Y,Tao Y Y,et al.Sulfide stress cracking of X70pipeline steels[J].Transactions of the China Welding Institution,2003,24(3):75-78(李云涛,杜则裕,陶勇寅等.X70管线钢硫化氢应力腐蚀[J].焊接学报,2003,24(3):75-78) [2]Hu P F,Wen J B,Li Q A.Researchstatus and progress of anti cor-rosion of oil and gas pipes at home and abroad[J].Journal of HenanUniversity of Science and Technology(Natural Science),2003,24(2):100-104(胡鹏飞,文九巴,李全安.国内外油气管道腐蚀及防护技术研究现状及进展[J].河南科技大学学报(自然科学版),2003,24(2):100-104) [3]Antin olo A,Carrillo-Hermosilla F,Fernandez-Baeza J,et al.Synthesis and characterization of thiolate,amido and oxy hetero-cyclic containing niobocene complexes:X-ray moleculars tudies ofNb(h5-C5H4Si Me3)2(h2-N,S-S(C6H7N2))](3)[J].Inor-ganica Chi mica Acta,2000,300-302:131-137 [4]Chen WB,Chen Peter,Chen HY,et al.Development of Al-con-taining zinc-rich paints for corrosion resistances[J].Appl.Surf.Sci.,2002,187:154-164 [5]Panossian Z,Mariaca L,Morcillo M,et al.Steel cathodic protectionafforded by zinc,aluminium and zinc/aluminium alloy coatings inthe atmosphere[J].Surf.Coat.Technol.,2005,190:244-248 [6]Wang Y,Han T,Zhao W M.Influence of the second thermal cycleon coarse-grained zone toughness of X70 steel[J].Acta Metall.Sin.,1999,12(5):831 [7]Yang H Y,Chen J J,Cao C N,et al.Study on corrosion in H2Saqueous solutions[J].J.Chin.Soc.Corros.Prot.,2000,20(1):1-7(杨怀玉,陈家坚,曹楚南等.H2S水溶液中的腐蚀与缓蚀作用机理的研究[J].中国腐蚀与防护学报,2000,20(1):1-7) [8]Yang Y Q.Applied Electrochemistry[M].Guangzhou:ZhongshanUiversity Press,2001,151(杨倚琴.应用电化学[M].广州:中山大学出版社,2001,151 [9]Wang J,Cao C N.Anodic desorption of inhibitorsⅡ.Effects of in-hibitor desorption on electrode[J].J.Chin.Soc.Corros.Prot.,1995,15(4):247-253(王佳,曹楚南.缓蚀剂阳极脱附现象的研究Ⅱ[J].中国腐蚀与防护学报,1995,15(4):247-253) [10]Cao C N,Zhang J Q.Electrochemical I mpedance SpectroscopyTheory[M].Beijing:Science Press,2002,53(曹楚南,张鉴清.电化学阻抗谱导论[M].北京:科学出版社,2002,53) |
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