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J Chin Soc Corr Pro  2003, Vol. 23 Issue (6): 335-339     DOI:
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HIGH TEMPERATURE OXIDATION BEHAVIOR OF PURE NiAND ITS SPUTTERED NANOCRYSTALLINE COATING
Shujiang Geng;Shenglong Zhu;Fuhui Wang
中科院金属所;金属腐蚀与防护国家重点实验室
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Abstract  A nanocrystalline coating with the same compositio n as pure Ni was deposited on the pure Ni substrate by means of magnetron sputte ring.The oxidation behavior of pure Ni and its sputtered nanocrystalline coatin g in air at 700℃~900℃ was studied.The samples were examined by scanning tunne l microscopy(STM),scanning electron microscopy(SEM)with energy dispersive X-ray (EDX)and X-ray diffraction(XRD).The results indicated that the mass gain of t he nanocrystalline pure Ni was higher than that of normal grain-sized pure Ni at the same temperature.Nanocrystallization accelerated the oxidation of pure Ni,e specially at the very early stage.It is proposed that nanocrystallization may al so lead to an increase of oxidation rate at the very early stage for oxidation o f any multi-element alloy,and it is by this mechanism that nanocrystallization p romotes the selective oxidation of alloys.
Key words:  pure Ni      sputtering      nanocrystalline      oxidation      
Received:  13 May 2002     
ZTFLH:  TG174.4  
Corresponding Authors:  Shujiang Geng   

Cite this article: 

Shujiang Geng; Shenglong Zhu; Fuhui Wang. HIGH TEMPERATURE OXIDATION BEHAVIOR OF PURE NiAND ITS SPUTTERED NANOCRYSTALLINE COATING. J Chin Soc Corr Pro, 2003, 23(6): 335-339 .

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https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2003/V23/I6/335

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