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INHIBITION EFFECT OF NaNO3 FOR 316L STAINLESS STEEL IN Cl- CONTAINING ITACONIC ACID SOLUTIONS |
Jinming Long;; |
昆明理工大学材料系 |
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Abstract By weight loss and electrochemical measurements and XPS analysis,the inhibition effect of NaNO3 for 316L stainless steel in Cl- containing itaconic acid media was investigated.The results showed that the pitting corrosion of the steel in the media could be prevented effectively in the presence of some amounts of NaNO3,which could raise the critical pitting potential up to the transpassive potential so as to result in a superior pitting resistance.The competitive adsorption between NO3- and Cl- on the steels surface might be a main mechanism for inhibition.In view of the dual functions of NaNO3 as an inhibitor and as a nitrogenous source necessary for the fermentation process,it is feasible for NaNO3 to be recommended for use in the production of itaconic acid by fermentation
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Received: 21 July 2005
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Corresponding Authors:
Jinming Long
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1Kolotyrkin JA M.Corrosion,1963,19(8):261t 2许淳淳等。中国腐蚀与防护学报, 1991, 11(3): 225 3金其荣等。有机酸发酵工艺学,北京:轻工业出版社, 1995. 499 4Schwenk W. Corrosion,1964, 20(4): 129t 5杨武等。金属的局部腐蚀,北京:化学工业出版社、 1995.106 |
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