Please wait a minute...
中国腐蚀与防护学报  2010, Vol. 30 Issue (3): 181-186    
  研究报告 本期目录 | 过刊浏览 |
恒流脉冲技术检测混凝土中钢筋的腐蚀
徐晶,姚武
同济大学 先进土木工程材料教育部重点实验室 上海 200092
CORROSION DETECTION OF STEEL IN CONCRETE BY USE OF GALVANOSTATIC PULSE TECHNIQUE
XU Jing, YAO Wu
Key Labratory of Advance Civil Engineering Materials of the Ministry of Education, Tongji University, Shanghai 200092
全文: PDF(773 KB)  
摘要: 

采用恒流脉冲法研究了混凝土结构中的钢筋在不同Cl-含量下的腐蚀行为。运用两种数据处理手段分别分析了脉冲响应曲线,计算得到的腐蚀速率值与传统线性极化法进行了对比。结果表明,扰动信号强度的选择强烈依赖于钢筋的腐蚀状况,过低会造成背景噪声干扰,而过高则会引起钢筋强烈极化,两者均不利于后期数据处理。阳极电流换算法能快速有效地分析脉冲信号曲线,但在过大的脉冲电流情况下有其局限性。

关键词 钢筋混凝土腐蚀速率恒流脉冲    
Abstract

Corrosion behavior of steel in concrete with different chloride ion concentration was studied by means of galvanostatic pulse, which is introduced as a new type of non-destructive technique nowadays. Potential transient technique galvanostatically induced is used to determine the corrosion rate with two data analysis methods, followed by comparing to that of the traditional linear polarization method. It is shown that the choice of perturbation magnitude of signal to be applied depends strongly on the corrosion state of steel. Too small current makes it difficult to separate the potential signal from background noise, whereas higher current results in intensive polarization. Thus, neither of two is beneficial for the data processing. Anodic current conversion method is fast and efficient in analyzing the galvanostatic pulse curves; however, this approach has some limitations in case of large applied current.

Key wordssteel reinforced concrete    corrosion rate    galvanostatic pulse
收稿日期: 2008-06-27     
ZTFLH: 

TU201

 
基金资助:

国家教育部博士点基金项目20070247063资助

通讯作者: 徐晶     E-mail: 0420060017@smail.tongji.edu.cn
Corresponding author: XU Jing     E-mail: 0420060017@smail.tongji.edu.cn
作者简介: 徐晶,男,1984年生,博士生,研究方向为钢筋混凝土腐蚀与防护

引用本文:

徐晶,姚武. 恒流脉冲技术检测混凝土中钢筋的腐蚀[J]. 中国腐蚀与防护学报, 2010, 30(3): 181-186.
XU Jing, YAO Wu. CORROSION DETECTION OF STEEL IN CONCRETE BY USE OF GALVANOSTATIC PULSE TECHNIQUE. J Chin Soc Corr Pro, 2010, 30(3): 181-186.

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2010/V30/I3/181

[1] Feliu S,Gonzalez J A,Miranda J M,et al. Possibilities and problems of in situ techniques for measuring steel corrosion rates in large reinforced concrete structures [J]. Corros. Sci, 2005, 47(1):217-238
[2] Broomfield J P,Davies K,Hladky K. The use of permanent corrosion monitoring in new and existing reinforced concrete structures [J]. Cem. Concr. Comp, 2002, 24(1):27-34
[3] Hong D H.Corrosion and Protection of Rebar in Concrete [M].Beijing:China Railway Press,1998.
[4] (洪定海.混凝土中钢筋的腐蚀与保护 [M].北京:中国铁道出版社,1998)
[5] Lu Z L.Corrosion behavior and mechanism of reinforced steel in acidic environment [J].J. Chin. Soc. Corros.Prot.,2007,27(2):119-123
[6] 鲁照玲. 酸性气氛下钢筋混凝土结构腐蚀行为及其机理 [J]. 中国腐蚀与防护学报, 2007, 27(2):119-123浏览
[7] Chen L T,Zhang S P,Zou G J,et al.Technology for corrosion monitoring of reinforcing steel bars in concrete and the application [J].J. Mater.Prot.,2007,40(5):52-55
  (陈澜涛,张三平,邹国军等.钢筋混凝土腐蚀监测技术及其应用 [J].材料保护,2007,40(5):52-55)
[8] Hu J F,Li G X,Deng K,et al.Study on non-uniform corrosion of rebar embedded in concrete by wire-beam electrode [J].J. Chin. Soc. Corros. Prot.,2005,25(2):88-92
[9] 胡金丰,李国希,邓恺等. 用丝束电极研究混凝土中钢筋腐蚀的不均匀性 [J]. 中国腐蚀与防护学报, 2005, 25(2):88-92浏览
[10] Li H,Wu J H,Qi G T.Electrochemical performance of RuTiSnMn/Ti anode [J].J. Chin.Soc. Corros. Prot.,2004,24(5):280-283
[11] 李辉. 吴建华.齐公台RuTiSnMn/Ti阳极的电化学性能 [J]. 中国腐蚀与防护学报, 2004, 24(5):280-283浏览
[12] Hu R G,Du R G,Shao M H,et al.In situ STM study on dynamic behavior of corrosion and inhibition of rebar steel in different simulated concrete pore solution [J].J. Chin. Soc.Corros. Prot.,2003,23(6):321-325
[13] 胡融刚,杜荣归,绍敏华等. 原位STM研究钢筋在模拟混凝土孔溶液中腐蚀和缓蚀动态行为 [J]. 中国腐蚀与防护学报, 2003, 23(6):321-325浏览
[14] Wu J H,Zhao Y T.Corrosion monitoring/detecting of rebar in concrete[J].Corros. Prot., 2003,24(10):421-431.
  (吴建华,赵永韬.钢筋混凝土的腐蚀监测/检测 [J].腐蚀与防护,2003,24(10):421-431)
[15] Zou G J,Chen L T,Zhen Q F,et al.Corrosion behavior of reinforcing steel bars of reinforced concrete in water environment studied by resistance probe [J].J. Mater. Prot.,2007,40(4):11-13
  (邹国军,陈澜涛,郑弃非等.用电阻探针法研究水环境中钢筋混凝土的腐蚀行为 [J].材料保护,2007,40(4):11-13)
[16] Geng O,Li G,Yuan Y S.Application of electrochemical detection techniques in concrete reinforcement corrosion [J].Concrete,2005,184(2):20-23
  (耿欧,李果,袁迎曙.电化学检测技术在混凝土内钢筋腐蚀研究中的应用现状与展望 [J].混凝土,2005,184(2):20-23)
[17] Ding Y L,Dong Z H,Zhou H L,et al.Field corrosion monitoring of rebars in concrete by guard ring electrode method [J].J. Chin. Soc. Corros.Prot.,2006,26(5):257-262
[18] 丁元力,董泽华,周华林等. 基于护环技术的混凝土中钢筋腐蚀监测研究 [J]. 中国腐蚀与防护学报, 2006, 26(5):257-262浏览
[19] Andrade C,Keddam M,Novoa X R,et al. Electrochemical behaviour of steel rebars in concrete: influence of environmental factors and cement chemistry [J]. Electrochim. Acta, 2001, 46(24/25):3905-3912
[20] Stern M,Geary A L. Electrochemical polarisation:ⅠA theoretical analysis of the shape of polarization curves [J]. J. Electrochem.Soc, 1957, 104(1):56-63
[21] Gonzclez J A,Molina A,Escudero M L,et al. Errors in the electrochemical evaluation of very small corrosion rates-I:polarization resistance method applied to corrosion of steel in concrete [J]. Corros.Sci, 1985, 25(10):917-930
[22] Glass G K,Page C L,Short N R,et al. An investigation of galvanostatic transient methods used to monitor the corrosion of rate of steel in concrete [J]. Corros.Sci, 1993, 35(5-8):1585-1592
[23] Mietz J,Isecke B. Monitoring of concrete structures with respect to rebar corrosion [J]. Constr. Build. Mater, 1996, 10(5):367-373
[24] Holloway M,Sykes J M. Studies of the corrosion of mild steel in alkali-activated slag cement mortars with sodium chloride admixtures by a galvanostatic pulse method [J]. Corros. Sci, 2005, 47(12):3097-3110
[25] Birbilis N,Nairn K M,Forsyth M. On the electrochemical response and interfacial properties of steel-Ca(OH)2 and the steel-concrete system measured using galvanostatic pulses [J]. Electrochim. Acta, 2004, 49(25):4331-4339
[26] Birbilis N,Nairn K M,Forsyth M. Transient response analysis of steel in concrete [J]. Corros. Sci, 2003, 45(9):1895-1902
[27] Newton C J,Sykes J M. A galvanostatic pulse technique for investigation of steel corrosion in concrete [J]. Corros.Sci, 1988, 28(11):1051-1074
[28] Gonzalez J A,Cobo A,Gonzalez M N,et al. On-site determination of corrosion rate in reinforced concrete structures by use of galvanostatic pulses [J]. Corros. Sci, 2001, 43(4):611-625
[29] Glass G K,Page C L,Short N R,et al. The analysis of potentiostatic transients applied to the corrosion of steel in concrete [J]. Corros.Sci, 1997, 39(9):1657-1663
[30] Sathiyanarayanan S,Natarajan P,Saravanan K,et al. Corrosion monitoring of steel in concrete by galvanostatic pulse technique [J]. Cem. Concr.Comp, 2006, 28(7):630-637
[31] Cao C N.Principle ofCorrosion Electrochemistry [M]. Beijing:Chemical Industry Press,2004
[32] (曹楚南.腐蚀电化学原理 [M].北京:化学工业出版社,2004)
[33] Gonzalez J A,Miranda J M,Feliu S. Considerations on reproducibility of potential and corrosion rate measurements in reinforced concrete [J]. Corros. Sci, 2004, 46(10):2467-2485
[34] Glass G K,Hassanein A M,Buenfeld N R. Cathodic protection afforded by an intermittent current applied to reinforced concrete [J]. Corros. Sci, 2001, 43(6):1111-1131
[1] 贾世超, 高佳祺, 郭浩, 王超, 陈杨杨, 李旗, 田一梅. 再生水水质因素对铸铁管道的腐蚀研究[J]. 中国腐蚀与防护学报, 2020, 40(6): 569-576.
[2] 赵国仙,黄静,薛艳. 某油田地面集输管道用材腐蚀行为研究[J]. 中国腐蚀与防护学报, 2019, 39(6): 557-562.
[3] 孙永伟,钟玉平,王灵水,范芳雄,陈亚涛. 低合金高强度钢的耐模拟工业大气腐蚀行为研究[J]. 中国腐蚀与防护学报, 2019, 39(3): 274-280.
[4] 刘丽,于思荣. 添加Gd对AM60镁合金耐腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2019, 39(2): 185-191.
[5] 李洋, 李承媛, 陈旭, 杨佳星, 王欣彤, 明男希, 韩镇泽. 超级13Cr不锈钢在海洋油气田环境中腐蚀行为灰关联分析[J]. 中国腐蚀与防护学报, 2018, 38(5): 471-477.
[6] 宋丰轩,赵启忠,李飞龙,任月路,黄奎,张新明. 不同时效态7050铝合金板材腐蚀速率测量[J]. 中国腐蚀与防护学报, 2017, 37(3): 287-292.
[7] 朱明,余勇,张慧慧. L245钢在不同温度下的油气田模拟水中的腐蚀行为研究[J]. 中国腐蚀与防护学报, 2017, 37(3): 300-304.
[8] 张子阳,王善林,章恒瑜,柯黎明. AZ31镁合金搅拌摩擦焊接头腐蚀行为[J]. 中国腐蚀与防护学报, 2017, 37(2): 117-125.
[9] 白强,邹妍,孔祥峰,高杨,刘岩,董胜. 奥氏体焊条水下湿法焊接CCSE40钢在海水中的腐蚀电化学行为研究[J]. 中国腐蚀与防护学报, 2016, 36(5): 427-432.
[10] 王春霞,陈敬平,张晓红,王赪胤. 溴化N-辛烷异喹啉在盐酸溶液中对Q235碳钢的缓蚀行为[J]. 中国腐蚀与防护学报, 2016, 36(3): 245-252.
[11] 张玉成,鞠新华,庞晓露,高克玮. O2浓度对钢在超临界CO2中腐蚀速率的影响[J]. 中国腐蚀与防护学报, 2015, 35(3): 220-226.
[12] 程旭东, 孙连方, 曹志烽, 朱兴吉, 赵立新. 沿海钢筋混凝土结构Cl-侵蚀数值模拟方法研究[J]. 中国腐蚀与防护学报, 2015, 35(2): 144-150.
[13] 周年光, 查方林, 冯兵, 何铁祥. 电化学频率调制技术在Q235钢/NaCl腐蚀体系中的应用[J]. 中国腐蚀与防护学报, 2014, 34(5): 445-450.
[14] 刘智勇, 贾静焕, 杜翠薇, 李晓刚, 王丽颖. X80和X52钢在模拟海水环境中的腐蚀行为与规律[J]. 中国腐蚀与防护学报, 2014, 34(4): 327-332.
[15] 朱敏, 杜翠薇, 李晓刚, 刘智勇, 王丽叶. 交流电频率对X80管线钢在酸性土壤模拟溶液中腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2014, 34(3): 225-230.