Bi2S3/TiO2 纳米复合材料的制备及其对304不锈钢的光生阴极保护性能研究

doi:10.11902/1005.4537.2023.270

中国腐蚀与防护学报

2024, Vol. 44

Issue (4): 901-908 CSTR: 32134.14.1005.4537.2023.270 DOI: 10.11902/1005.4537.2023.270

研究报告

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Bi₂S₃/TiO₂ 纳米复合材料的制备及其对304不锈钢的光生阴极保护性能研究

于佳汇, 王彤彤, 高云, 高荣杰(

)

中国海洋大学材料科学与工程学院青岛 266100

Fabrication and Photocathodic Protection Performance of Bi₂S₃/TiO₂ Nanocomposites for 304 Stainless Steel

YU Jiahui, WANG Tongtong, GAO Yun, GAO Rongjie(

)

School of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China

引用本文:

于佳汇, 王彤彤, 高云, 高荣杰. Bi₂S₃/TiO₂ 纳米复合材料的制备及其对304不锈钢的光生阴极保护性能研究[J]. 中国腐蚀与防护学报, 2024, 44(4): 901-908.
Jiahui YU, Tongtong WANG, Yun GAO, Rongjie GAO. Fabrication and Photocathodic Protection Performance of Bi₂S₃/TiO₂ Nanocomposites for 304 Stainless Steel[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 901-908.

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摘要:

通过连续离子层吸附法(SILAR)在TiO₂纳米管上负载Bi₂S₃，通过XRD、SEM、XPS等手段对Bi₂S₃/TiO₂纳米复合材料的形貌、结构、元素组成和价态进行表征。同时在模拟太阳光条件下进行光电化学性能测试。Bi₂S₃改性后复合材料的带隙减小，光生载流子复合率大幅下降，当Bi₂S₃循环5次时，TiO₂纳米复合材料的光电化学性能最好。带隙减小到2.9 eV，光电流密度由改性前的200 μA·cm^-2提升至550 μA·cm^-2，是改性前的2.75倍；将其与304不锈钢耦合后，电位降至-1.0 V，比改性前的耦合电位低80 mV，可以进一步提升对304不锈钢的光生阴极保护效果。

关键词 ：光生阴极保护, 改性, Bi₂S₃/TiO₂, 304不锈钢

Abstract：

TiO₂ nanotube arrays are decorated with Bi₂S₃ by a successive ionic layer adsorption and reaction (SILAR) method, aiming to enhance the photoelectric conversion ability of TiO₂ and photogenerated cathodic protection performance of TiO₂ nanotube arrays for 304 stainless steel. B-(x)/TiO₂ nanotubes (x = 1,3,5,7) were prepared by changing the number of deposition cycles of Bi₂S₃. The morphology, structure, light response ability and photogenerated carrier separation efficiency of Bi₂S₃/TiO₂ nanocomposites were examined by means of XRD, SEM and XPS. At the same time, the photoelectrochemical properties of Bi₂S₃/TiO₂ nanocomposites were tested under simulated sunlight. In addition, the effect of the number of deposition cycles of Bi₂S₃ on the photocathodic protection performance of TiO₂ nanocomposites was also studied. After Bi₂S₃ modification, the band gap of the composites decreases, and the recombination rate of photogenerated carriers decreases greatly. When a 5 cyclic deposition of Bi₂S₃ is adopted, the photoelectrochemical properties of the prepared nanocomposites are the best. Of which the band gap is reduced to 2.9 eV, and the photocurrent density is increased from 200 μA·cm^-2 to 550 μA·cm^-2 under the condition of turning on light, which is 2.75 times that of the bare TiO₂ nanotube arrays. After coupling the modified nanocomposite with 304 stainless steel, the coupling potential can be reduced to -1.0 V under simulated sunlight, which is about 80 mV lower than the coupling potential before modification, which can further improve the photogenerated cathodic protection effect on 304 stainless steel.

Key words： photogenerated cathodic protection modification Bi₂S₃/TiO₂ 304 stainless steel

收稿日期: 2023-08-31 32134.14.1005.4537.2023.270

ZTFLH:

TG174

基金资助:国家自然科学基金-山东省联合基金(U1706221)

通讯作者: 高荣杰，E-mail: dmh206@ouc.edu.cn，研究方向为阴极保护设计与检测

Corresponding author: GAO Rongjie, E-mail: dmh206@ouc.edu.cn

作者简介: 于佳汇，女，1999年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2023.270 或 https://www.jcscp.org/CN/Y2024/V44/I4/901

图1 TiO2纳米管的制备过程示意图

图2 Bi2S3 /TiO2纳米复合材料的制备过程示意图

图3 电化学测试装置示意图

图4 TiO2纳米管及Bi2S3/TiO2纳米复合材料的XRD谱

图5 TiO2纳米管，B-1/TiO2，B-3/TiO2，B-5/TiO2，B-7/TiO2纳米复合材料的SEM形貌图和B-5/TiO2纳米复合材料的EDS分析结果

图6 B-5/TiO2纳米复合材料的元素分布图

图7 B-5/TiO2纳米复合材料的XPS谱

图8 TiO2纳米管及B-5/TiO2纳米复合材料的紫外-可见漫反射谱的Tauc曲线图

图9 TiO2纳米管及B-x/TiO2纳米复合材料的光致发光光谱

图10 TiO2纳米复合材料在间歇可见光下的光生电流密度-时间曲线

图11 TiO2纳米复合材料耦合304不锈钢电极在间歇可见光下的电位变化

图12 模拟太阳光下TiO2纳米复合材料的Nyquist图及等效电路图

表1 EIS拟合参数

图13 Bi2S3和TiO2半导体的能带结构示意图

[1]	Zhang Y, Yin X Y, Yan F Y. Effect of halide concentration on tribocorrosion behaviour of 304SS in artificial seawater [J]. Corros. Sci., 2015, 99: 272
[2]	Zhang Y, Yin X Y, Yan Y F, et al. Tribocorrosion behaviors of 304SS: effect of solution pH [J]. RSC Adv., 2015, 5: 17676
[3]	Jiang J H, Zhang X Y, Jin Z Q. Research progress in photochemical cathodic protection technology [J]. Mar. Sci., 2021, 45(12): 150
[3]	蒋继宏, 张小影, 金祖权. 光电化学阴极保护技术研究进展 [J]. 海洋科学, 2021, 45(12): 150
[4]	Chen F W, Liu B, Jian D H, et al. Research progress and existing problems of photocathodic protection technology [J]. J. Mater. Eng., 2021, 49(12): 83
[4]	陈凡伟, 刘斌, 蹇冬辉等. 光生阴极保护技术的研究进展及其存在的问题 [J]. 材料工程, 2021, 49(12): 83 doi: 10.11868/j.issn.1001-4381.2021.000469
[5]	Subasri R, Shinohara T. Application of the photoeffect in TiO₂ for cathodic protection of copper [J]. Electrochemistry, 2004, 72: 880
[6]	Kumar S G, Devi L G. Review on modified TiO₂ photocatalysis under UV/Visible light: selected results and related mechanisms on interfacial charge carrier transfer dynamics [J]. J. Phys. Chem., 2011, 115A: 13211
[7]	Guo H X, Li L L, Su C, et al. Effective photocathodic protection for 304 stainless steel by PbS quantum dots modified TiO₂ nanotubes [J]. Mater. Chem. Phys., 2021, 258: 123914
[8]	Zheng L X, Teng F, Ye X Y, et al. Photo/electrochemical applications of metal sulfide/TiO₂ heterostructures [J]. Adv. Energy Mater., 2020, 10: 1902355
[9]	Luo J H, Wei H Y, Huang Q L, et al. Highly efficient core-shell CuInS₂-Mn doped CdS quantum dot sensitized solar cells [J]. Chem. Commun., 2013, 49: 3881
[10]	Yang L, Ma Y P, Liu J H, et al. Improving the performance of solid-state quantum dot-sensitized solar cells based on TiO₂/CuInS₂ photoelectrodes with annealing treatment [J]. RSC Adv., 2016, 6: 92869
[11]	Yang Y Y, Zhang W W, Xu Y, et al. Ag₂S decorated TiO₂ nanosheets grown on carbon fibers for photoelectrochemical protection of 304 stainless steel [J]. Appl. Surf. Sci., 2019, 494: 841
[12]	Cheng L Y, Ding H M, Chen C H, et al. Ag₂S/Bi₂S₃ co-sensitized TiO₂ nanorod arrays prepared on conductive glass as a photoanode for solar cells [J]. J. Mater. Sci., 2016, 27: 3234
[13]	Hu J, Guan Z C, Liang Y, et al. Bi₂S₃ modified single crystalline rutile TiO₂ nanorod array films for photoelectrochemical cathodic protection [J]. Corros. Sci., 2017, 125: 59
[14]	Li H, Wang X T, Wei Q Y, et al. Photocathodic protection of 304 stainless steel by Bi₂S₃/TiO₂ nanotube films under visible light [J]. Nanoscale Res. Lett., 2017, 12: 80
[15]	Li X L, Yang M, Zhu D, et al. Preparation of TiO₂/Bi₂S₃ composite photo-anode through ultrasound-assisted successive ionic layer adsorption and reaction method for improving the photoelectric performance [J]. J. Electron. Mater., 2020, 49: 3242
[16]	Zumeta-Dubé I, Ruiz-Ruiz V F, Díaz D, et al. TiO₂ sensitization with Bi₂S₃ quantum dots: the inconvenience of sodium ions in the deposition procedure [J]. J. Phys. Chem., 2014, 118C: 11495
[17]	Wang Q Y, Liu Z Y, Jin R C, et al. SILAR preparation of Bi₂S₃ nanoparticles sensitized TiO₂ nanotube arrays for efficient solar cells and photocatalysts [J]. Sep. Purif. Technol., 2019, 210: 798
[18]	Zhou M J, Zeng Z O, Zhong L. Photogenerated cathode protection properties of nano-sized TiO₂/WO₃ coating [J]. Corros. Sci., 2009, 51: 1386
[19]	Kubo T, Nakahira A. Local structure of TiO₂-derived nanotubes prepared by the hydrothermal process [J]. J. Phys. Chem., 2008, 112C: 1658
[20]	Antony R P, Mathews T, Dash S, et al. X-ray photoelectron spectroscopic studies of anodically synthesized self aligned TiO₂ nanotube arrays and the effect of electrochemical parameters on tube morphology [J]. Mater. Chem. Phys., 2012, 132: 957
[21]	He H C, Berglund S P, Xiao P, et al. Nanostructured Bi₂S₃/WO₃ heterojunction films exhibiting enhanced photoelectrochemical performance [J]. J. Mater. Chem., 2013, 1A: 12826
[22]	Weng B, Zhang X, Zhang N, et al. Two-dimensional MoS₂ nanosheet-coated Bi₂S₃ discoids: synthesis, formation mechanism, and photocatalytic application [J]. Langmuir, 2015, 31: 4314 doi: 10.1021/la504549y pmid: 25625414
[23]	Chen L, He J, Yuan Q, et al. CuS-Bi₂S₃ hierarchical architectures: controlled synthesis and enhanced visible-light photocatalytic performance for dye degradation [J]. RSC Adv., 2015, 5: 33747
[24]	Lin Z Q, Lai Y K, Hu R G, et al. A highly efficient ZnS/CdS@TiO₂ photoelectrode for photogenerated cathodic protection of metals [J]. Electrochim. Acta, 2010, 55: 8717
[25]	Li X L, Wang X Y, Liu J L, et al. Bismuth sulfide decorated TiO₂ arrays heterojunction assembly for enhanced photoelectrochemical performance [J]. Optik, 2022, 252: 168522
[26]	Su N, Ye M Y, Li J M, et al. Fabrication of ZIF-8/TiO₂ composite film and its photogeneration cathodic protection performance [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 267
[26]	苏娜, 叶梦颖, 李建民等. ZIF-8/TiO₂纳米复合材料的制备及光生阴极保护性能 [J]. 中国腐蚀与防护学报, 2022, 42: 267
[27]	Wang W C, Wang X T, Wang N, et al. Bi₂Se₃ sensitized TiO₂ nanotube films for photogenerated cathodic protection of 304 stainless steel under visible light [J]. Nanoscale Res. Lett., 2018, 13: 295
[28]	Jiao Z B, Zhang Y, Chen T, et al. TiO₂ nanotube arrays modified with Cr-Doped SrTiO₃ nanocubes for highly efficient hydrogen evolution under visible light [J]. Chem. Eur. J., 2014, 20: 2654
[29]	Bao C Y, Li J M, Ye M Y, et al. Preparation of TiO₂ nanotube arrays in composite electrolytes and their photogenerated cathodic protection performance [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 759
[29]	鲍晨宇, 李建民, 叶梦颖等. 复合电解液中TiO₂纳米管阵列的制备及光生阴极保护性能 [J]. 中国腐蚀与防护学报, 2022, 42: 759 doi: 10.11902/1005.4537.2021.255
[30]	Cai F G. Fabrication and photoelectrochemical properties study of Bi₂S₃/PbS-sensitized TiO₂nanotube arrays [D]. Chengdu: Southwest Jiaotong University, 2013
[30]	蔡芳共. Bi₂S₃、PbS敏化TiO₂纳米管阵列的制备及其光电性能研究 [D]. 成都: 西南交通大学, 2013
[31]	Wang B, Cao J T, Dong Y X, et al. An in situ electron donor consumption strategy for photoelectrochemical biosensing of proteins based on ternary Bi₂S₃/Ag₂S/TiO₂NT arrays [J]. Chem. Commun., 2018, 54: 806

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