高温高压水溶液用Ag/AgCl参比电极研究现状及发展趋势

中国腐蚀与防护学报

2003, Vol. 23

Issue (6): 370-374

综述

本期目录 | 过刊浏览

高温高压水溶液用Ag/AgCl参比电极研究现状及发展趋势

田斌;胡明;李春福

田斌天津大学电子信息工程学院天津300072

STATE OF THE ART AND FUTURE TRENDS OFAg/AgCl REFERENCE ELECTRODES FOR HIGHTEMPERATURE AND HIGH PRESSURE AQUEOUS SYSTEMS

Bin Tian;Ming Hu;Chunfu Li

田斌天津大学电子信息工程学院天津300072

全文: PDF(187 KB)

摘要: 对目前国内外高温高压水溶液用Ag/AgCl参比电极的研究现状进行了回顾和总结，主要针对内置式参比电极和外置式参比电极的结构和存在的问题进行了讨论.两种电极在结构上的发展都是从复杂到简单实用，大量新材料和新技术的应用使参比电极的性能有了很大的提高.相比来说，内置式参比电极由于结构简单，电位稳定，比较适合用于热力学方面的研究；而外置式参比电极的结构比较复杂，适合于动力学方面的研究 .并对参比电极的发展趋势进行了展望.

关键词 ：高温高压水溶液, 参比电极, Ag/AgCl, 结构, 新

Abstract：The developments of the Ag/AgCl reference electrode s for high temperature and high pressure aqueous systems are reviewed.Particular attention is paid to the designs and the problems of the internal and external reference electrodes.The development in structure is from complexity to simplene ss.The qualities of the electrodes are improved mostly because of the use of lot s of new materials and technologies.In contrast,internal reference electrodes ar e adapt to be used in thermodynamics because of simple structures and stable p otentials,external reference electrodes in kinetics because of the complex struc ture.A forecast is given for their future trends.

Key words： high temperature and high pressure aqueous system ref erence electrode Ag/AgCl structure new materia

收稿日期: 2002-10-14

ZTFLH:

TG172.82

通讯作者: 田斌

Corresponding author: Bin Tian

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	田斌
	胡明
	李春福
44.8K

引用本文:

田斌; 胡明; 李春福 . 高温高压水溶液用Ag/AgCl参比电极研究现状及发展趋势[J]. 中国腐蚀与防护学报, 2003, 23(6): 370-374 .
Bin Tian, Ming Hu, Chunfu Li. STATE OF THE ART AND FUTURE TRENDS OFAg/AgCl REFERENCE ELECTRODES FOR HIGHTEMPERATURE AND HIGH PRESSURE AQUEOUS SYSTEMS. J Chin Soc Corr Pro, 2003, 23(6): 370-374 .

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2003/V23/I6/370

[1]DobsonJV ,FirmanRE ,ThirskHR .Thebehaviourofcellsusingsilver/silverchlorideandskin-calomelelectrodesattemperaturefrom25℃to200℃and1barto2kbarpressure[J].Electrochem.Acta,1971,16:793-809
[2]ZhouWeifang.ElectrochemicalMeasurement[M ].Shanghai:ShanghaiScienceandTechnologyPress,1985(周伟舫.电化学测量[M].上海:上海科学技术出版社,1985)
[3]IvesDJG ,JanzGJ .ReferenceElectrodes-TheoryandPractice[M ].NewYorkandLondon:AcademicPress,1961
[4]MacDonaldDD .Referenceelectrodesforhightemperatureaqueoussystems-areviewandassessment[J].Corrosion,1978,34(3):75-84
[5]KatsuhisaSugimoto.Referenceelectrodesforhightemperaturehighpressureaqueoussolutionsandtheirapplicationtocorrosionstudies[J].BoshokuGijutsu,1980,29:521-533
[6]Referenceelectrodeforuseathightemperaturesandpressures[P].USP 4116798,1978
[7]Referenceelectrodeassemblyofasilver/silverchlorideconstruction[P].USP 5034113,1989
[8]MagarIJ,MorrisPE .Theconstructionandperformanceofasil ver/silverchloridereferenceelectrodeforhightemperatureaqueousenvironments[J].Corrosion,1976,32:374-377
[9]LuJianshu,ZhangJiuyuan,YuXiaoming,etal.Asilver-silverchloridereferenceelectrode[J].JournalofZhejiangInstituteofTechnology,1991,51(2):80-83(卢建树,张九渊,俞小明等.Ag/AgCl参比电极的研制[J].浙江工学院学报,1991,51(2):80-83)
[10]WildeBE .Aassemblyforelectrochemicalcorrosionstudiesinaqueousenvironmentsathightemperatureandpressure[J].Corro sion,1967,23:331-334
[11]Sinteredceramicarticlewithporousregion[P].USP 4500413,1985
[12]KatsuhisaSugimoto,SaikoSoma.AnewdesignedAg-AgClinter nalreferenceelectrodeanditsapplicationtomeasurementsofanod icpolarizationcurvesfortype304Lstainlesssteelinhightempera tureaqueoussolutions[J].BoshokuGijutsu,1982,31:574-581
[13]Referenceelectrodeprobeforuseinaqueousenvironmentsofhightemperature[P].USP 5262038,1991
[14]HuangS ,DaehlingK ,CarlesonTE .Constructionandcalibrationoaninternalsilver/silverchloridereferenceelectrodeforsupercriticalfluidstudies[J].Corrosion,1991,47(3):185-188
[15]AgrawalAK ,StaehleRW .Asilver-silverchloridereferenceelectrodeforthehightemperatureandhighpressureelectro chemistry[J].Corrosion,1977,33(11):418-420
[16]IndigME ,McilreeAR .Hightemperatureelectrochemicalstudiesofthestresscorrosionoftype304stainlesssteel[J].Corrosion,1979,35:288-292
[17]Ruggedelectrodeforelectrochemicalmeasurementsathightem peraturesandpressures[P].USP 5516413,1993
[18]Referenceelectrodewithannularjunction[P].USP 5234570,1991
[19]DanielsonMJ.TheconstructionandthermodynamicperformanceofanAg-AgClreferenceelectrodeforuseinhightemperatureaqueousenvironmentscontainingH2 andH2S[J].Corrosion,1979,35:200-204
[20]MacDonaldDD ,ScottAC ,WentrcekP .Externalreferenceelec trodesforuseinhightemperatureaqueoussystem[J].J.Elec trochem.Soc.,1979,126:908-911
[21]KatsumiKushiya,KatsuhisaSugimoto,TatsuhikoEjima.Electro chemicalpolarizationbehaviorofsensitizedSUS 304stainlesssteelinhightemperaturewater[J].NihonKinzokuGakkaishi,1978,42:1109-1112
[22]Longlifereferenceelectrode[P].USP 4818366,1987
[23]KojiTachibana.Anewpressure-balancedouterreferenceelec trodewithoxidizedzircaloytubecontainerforcorrosionstudiesinhigh-temperature-high-pressureaqueoussolutionanditsappli cationtoobtainingpolarizationcurves[J].BoshokuGijutsu,1985,34:125-131

[1]	于浩冉, 张文丽, 崔中雨. 4种镁合金在Cl^--NH₄⁺-NO₃^-溶液体系中的腐蚀行为差异研究[J]. 中国腐蚀与防护学报, 2020, 40(6): 553-559.
[2]	李聪玮, 杜双明, 曾志琳, 刘二勇, 王飞虎, 马付良. 电流密度对Ni-Co-B镀层微观结构及磨蚀性能的影响[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[3]	闻洋, 熊林, 陈伟, 薛刚, 宋文学. 干湿循环下聚乙烯醇纤维混凝土抗Cl^-渗透性能研究[J]. 中国腐蚀与防护学报, 2020, 40(4): 381-388.
[4]	姜冬雪,付颖,张峻巍,张伟,辛丽,朱圣龙,王福会. 钛合金表面Al₂O₃陶瓷膜制备及性能研究[J]. 中国腐蚀与防护学报, 2019, 39(6): 469-476.
[5]	潘成成,马超,夏大海. EBSD技术研究金属材料晶体取向对大气腐蚀萌生的影响机理[J]. 中国腐蚀与防护学报, 2019, 39(6): 495-503.
[6]	王泽臣, 林君, 杨国卿, 梁尚清. 全氟磺酸膜对海洋电场电极抗腐蚀与电场响应性能影响的研究[J]. 中国腐蚀与防护学报, 2019, 39(6): 581-587.
[7]	魏欣欣,张波,马秀良. FeCr₁₅Ni₁₅单晶600 ℃下热生长氧化膜的TEM观察[J]. 中国腐蚀与防护学报, 2019, 39(5): 417-422.
[8]	于美,魏新帝,范世洋,刘建华,李松梅,钟锦岩. 应力作用下2297铝锂合金腐蚀行为研究[J]. 中国腐蚀与防护学报, 2019, 39(5): 439-445.
[9]	史昆玉,张进中,张毅,万毅. Nb₂N涂层制备及其耐腐蚀性能研究[J]. 中国腐蚀与防护学报, 2019, 39(4): 313-318.
[10]	黄博博,刘平,刘新宽,梅品修,陈小红. 新型HSn70-1铜网衣两年期海水腐蚀行为研究[J]. 中国腐蚀与防护学报, 2018, 38(6): 594-600.
[11]	蒋斌, 曾利兰, 梁涛, 潘浩波, 乔岩欣, 张竞, 赵颖. 316L不锈钢表面超疏水微纳镍镀层定向电沉积工艺优化研究[J]. 中国腐蚀与防护学报, 2018, 38(5): 438-446.
[12]	樊志民, 于锦, 宋影伟, 单大勇, 韩恩厚. 镁合金点蚀的研究进展[J]. 中国腐蚀与防护学报, 2018, 38(4): 317-325.
[13]	李越, 王剑, 张勇, 白晋钢, 胡亚迪, 乔永锋, 张彩丽, 韩培德. 2205双相不锈钢密闭容器中高温初始氧化过程分析[J]. 中国腐蚀与防护学报, 2018, 38(3): 296-302.
[14]	陈菊娜,吴佳佳,王鹏,张盾. 脱硫弧菌和溶藻弧菌对船体结构材料907钢海水腐蚀行为的影响研究[J]. 中国腐蚀与防护学报, 2017, 37(5): 402-410.
[15]	耿振伟,肖代红. Zn对挤压态Mg-13Gd-2Cu合金的显微组织及腐蚀性能影响[J]. 中国腐蚀与防护学报, 2016, 36(6): 595-603.

Viewed

Full text

Abstract

Cited

Shared

Discussed