一种组合添加剂在碱性无氰镀锌中的作用

中国腐蚀与防护学报

2012, Vol. 32

Issue (3): 251-255

研究报告

本期目录 | 过刊浏览

一种组合添加剂在碱性无氰镀锌中的作用

杜楠¹,舒伟发²,王春霞¹,王帅星¹,陈庆龙²

1. 南昌航空大学轻合金加工科学与技术国防重点学科实验室南昌 330063
2. 南京机电液压工程研究中心南京 211106

FUNCTION OF A COMBINATORIAL ADDITIVE ON ALKALINE NON-CYANIDE ZINC PLATING

DU Nan¹, SHU Weifa², WANG Chunxia¹, WANG Shuaixing¹, CHEN Qinglong²

1.National Defence Key Discipline Laboratory of Light Alloy Processing Science and Technology Institute,Nanchang Hangkong University, Nanchang 330063
2. Nanjing Engineering Center of Aircraft Systems, Nanjing 211106

全文: PDF(1534 KB)

摘要: 通过在碱性无氰镀锌溶液中添加一种组合添加剂获得了晶粒尺寸在60nm以内的纳米晶镀锌层，并通过对比有无添加剂时Zn的析出电位、镀锌层微观形貌及晶粒度的差异，分析了组合添加剂中两种组分的作用。结果表明，两种添加剂分别起到细化晶粒和整平作用，二者一起使用有很强的协调作用。

关键词 ：纳米镀锌, 添加剂, 形貌, 协同作用

Abstract：The nanocrystalline zinc coating which the grain size was within 60 nm was obtained when a combinatorial additive was added to alkaline non-cyanide bath. Besides, the role of two components of combinatorial additive was analyzed through comparing the differences with deposition potential、morphology and grain size of zinc coatings which were obtained in the bath contained additives or not. The results showed that the additive A played a role of grain refinement, the additive B played a role of leveling, and a strong synergistic effect was existed when both A and B was used.

Key words： nano-zinc electroplating additive morphology synergistic effect

收稿日期: 2011-03-31

ZTFLH:

TG174.45

基金资助:

江西省教育厅2011年度重点科技项目(GJJ11023)资助

通讯作者: 杜楠 E-mail: d_unan@sina.com

Corresponding author: DU Nan E-mail: d_unan@sina.com

作者简介: 杜楠，男，1956年生，教授，研究方向为材料物理与化学

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引用本文:

杜楠,舒伟发,王春霞,王帅星,陈庆龙. 一种组合添加剂在碱性无氰镀锌中的作用[J]. 中国腐蚀与防护学报, 2012, 32(3): 251-255.
DU Nan, YU Wei-Fa. FUNCTION OF A COMBINATORIAL ADDITIVE ON ALKALINE NON-CYANIDE ZINC PLATING. J Chin Soc Corr Pro, 2012, 32(3): 251-255.

链接本文:

https://www.jcscp.org/CN/ 或 https://www.jcscp.org/CN/Y2012/V32/I3/251

[1] Yan X C, Wen H, Yu N, et al. Corrosion and inhibition mechanism of zinc nanocrystalline electrodeposition in sulfuric acid solution[J]. J. Wuhan Univ. (Nat. Sci.), 2005, 41(6): 683-686

    (颜肖慈, 文汉, 余娜等. 纳米锌镀层在硫酸中的腐蚀和缓蚀机理[J].武汉大学学报(理学版), 2005, 41(6): 683-686)

[2] Wu X F. Study on technics of high efficient alkaline non-cyanide zinc plating[J]. Electroplat. Finish., 2005, 11(24):43-45

    (吴旭峰. 高效碱性无情镀锌工艺研究[J]. 电镀与涂饰, 2005, 11(24):43-45)

[3] Kavitha B, Santhosh P, Renukaelevi M, et al. Role of organic additives on zinc plating[J]. J.Power Sour., 1995, 55: 53-62

[4] Shivkumar R, Kalaignan G P, Vasudevan T. Effect of additives on zinc electrodes in alkaline battery systems[J]. Surf.Coat. Technol, 2006, 210: 3428-3442

[5] Ravindran V, Muralidharan V S. Cathodic process on zinc in alkaline zincate soluion[J]. J. Power Sour., 1995, 55: 237-241

[6] Ghavanmi R K, Rafiei Z. Performance improvements of alkaline batteries by studying kinds of surfactant and different derivatives of benzene on the electrochemical properties of electrolytic zinc[J]. J. Power Sour., 2006, 162: 893-899

[7] Mouanga M, Ricq L, Douglade J, et al. Effects of some additives on the corrosion behaviour and preferred orientations of zinc obtained by continuous current deposition[J]. J.Appl.Electrochem., 2007, 37: 283-289

[8] Sekar R, Eagammai C, Jayakrishnan S. Effect of additives on electrodeposition of tin and its structural and corrosion behaviour[J]. J.Appl. Electrochem, 2010, 40: 49-57

[9] Li M C, Jiang L L, Wen Q Z, et al. Electrochemical corrosion behavior of nanocrystalline zinc coatings in 3.5% NaCl solutions[J]. Solid State Electrochem., 2007, 11: 1319-1325

[10] Wu Y Q, Li M C, Xin S S, et al. Effect of three additives on electrodeposition behavior and structure of nanocrystalline zinc coatings [J]. Acta Chim. Sin., 2010, 68(6): 531-534

     (伍玉琴,李谋成, 辛森森等. 三种添加剂对纳米晶锌镀层电沉积行为及结构的影响[J].化学学报, 2010, 68(6): 531-534)

[11] Yang F Z, Huang L, Xu S K, et al. Leveling ability of additives and their effects on structure of Cu electrodeposits [J].J. Xiamen Univ. (Nat. Sci), 2003, 42(1): 56-59

     (杨防祖, 黄令,许书凯等. 添加剂的整平能力及其对Cu电沉积层结构的影响[J].厦门大学学报(自然科学版), 2003, 42(1): 56-59)

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